Chemistry Unit 7 Practice Test The Mole Concept No work shown = no credit. Please write legibly. Numerical answers must be rounded to the appropriate number of significant figures or decimal points and must contain the appropriate unit. 1. Calculate the number of representative particles in each of the following quantities. Round all answers to three significant figures. Each item is worth 4 points (12 points). (A) 2.35 mol N2 2.35 mol N2 x 6.022x10 23 molecules N2 = 1.42x1024 molecules N2 1mol N2 (B) 0.993 mol CH2Cl2 0.993 mol CH2Cl2 x 6.022x10 23 molecules CH 2 Cl 2 = 5.98x1023 molecules CH2Cl2 1mol CH 2 Cl 2 (C) 38.4 mol Ag 38.4 mol Ag x 6.022x10 23 atoms Ag = 2.31x1025 atoms Ag 1mol Ag 2. Calculate the mass of each of the following quantities. Round all answers to three significant figures. Each item is worth 4 points (12 points). (A) 0.00144 mol Hg Molar mass of Hg = 200.59 g/mol 0.00144 mol Hg x 200.59 g Hg = 0.289 g Hg 1mol Hg (B) 5.00 mol H2O Molar mass of H2O = 18.0153 g/mol 5.00 mol H2O x 18.0153 g H 2 O = 90.1 g H2O 1mol H 2 O (C) 9.15x104 mol NaNO3 Molar mass of NaNO3 = 84.9947 g/mol 9.15x104 mol NaNO3 x 84.9947 g NaNO 3 = 7.78x106 g NaNO3 1mol NaNO 3 3. Calculate the number of moles in each of the following quantities. Round all answers to three signficant figures. Each item is worth 4 points (24 points). (A) 4.11x1026 molecules of glucose 4.11x1026 molecules of glucose x 1 mol glucose 6.022x10 23 glucose molecules = 682 mol glucose (B) 0.500 grams of CH3COOH Molar mass of CH3COOH = 60.0522 g/mol 0.500 g CH3COOH x 1mol CH 3 COOH = 0.00833 mol CH3COOH 60.0522 g CH 3 COOH (C) 2.95x1024 atoms of carbon 2.95x1024 C atoms x 1mol C = 4.90 mol C 6.022x10 23 C atoms (D) 12.3 grams of water Molar mass of H2O = 18.0153 g/mol 12.3 g H2O x 1mol H 2 O = 0.683 mol H2O 18.0153 g H 2 O (E) 6.39x1022 molecules of hydrazine 6.39x1022 hydrazine molecules x 1 mol hydrazine 6.022x10 23 hydrazine molecules = 0.106 mol hydrazine (F) 330. grams of lithium fluoride 1 mol LiF = 12.7 mol LiF 25.9396 g LiF 4. Calculate the percentage composition of the following compounds. If the compound is a hydrate, treat water as an element with a molar mass of 18.0153 g/mol. Each item is worth 10 points (30 points). Molar mass of LiF = 25.9396 g/mol 330. g LiF x (A) CaCO3 Molar mass of CaCO3: 1 x Ca = 40.078 1 x C = 12.011 3 x O = 47.9982 Total = 100.087 g/mol %Ca = %O = 40.078 g x 100% = 40.043% Ca 100.087 g 47.9982 g x 100% = 47.9565% O 100.087 g %C = 12.011 g x 100% = 12.001% C 100.087 g (B) BrF3 Molar mass of BrF3: 1 x Br = 79.904 3 x F = 56.995209 Total = 136.899 g/mol %Br = 79.904 g x 100% = 58.367% Br 136.899 g %F = 56.995209 g x 100% = 41.6330% F 136.899 g %Cl = 70.906 g x 100% = 34.877% Cl 203.303 g (C) MgCl2●6H2O Molar mass of MgCl2●6H2O: 1 x Mg = 24.305 2 x Cl = 70.906 6 x H2O = 108.092 Total = 203.303 g/mol 24.305 g x 100% = 11.955% Mg 203.303 g %Mg = %H2O = 108.092 g x 100% = 53.1679% H2O 203.303 g 5. How many grams of iron could be obtained from 445 grams of Fe(NO 3)3●9H2O? (5 points) Molar mass of Fe(NO3)3●9H2O: 1 x Fe = 55.847 3 x N = 42.0201 9 x O = 143.995 9 x H2O = 162.138 Total = 404.000 g/mol %Fe = 55.847 g x 100% = 13.823% 404.000 g 13.823% of 445 g = 0.13823 x 445 g = 61.5 grams of Fe 6. How many grams of water are in 310. grams of CuSO4●5H2O? (5 points) Molar mass of CuSO4●5H2O: 1 x Cu = 63.55 1 x S = 32.07 4 x O = 64.00 5 x H2O = 90.10 Total = 249.72 g/mol %H2O = 90.10 g x 100% = 36.08% 249.72 g 36.08% of 310. g = 0.3608 x 310. g = 112 grams of H2O 7. Chloroform was once used as an anaesthetic until its toxic properties were discovered. The percentage compositon of chloroform is: 10.061% carbon 0.84436% hydrogen 89.094% chlorine What is the empirical formula of chloroform? (7 points) 10.061 g C x 1 mol C = 0.83764 mol C 12.011 g C 0.84436 g H x 1 mol H = 0.83771 mol H 1.00794 g H 89.094 g Cl x 1mol Cl = 2.5130 mol Cl 35.453 g Cl C0.83764H0.83771Cl2.5130 CHCl3 8. Glyceraldehyde is a molecule produced during cellular respiration. Its empirical formula is CH 2O and it has a molar mass of 90.09 g/mol. What is the molecular formula of glyceraldehyde? (5 points) Formula mass of CH2O: 1 x C = 12.011 2 x H = 2.01599 1 x O = 15.9994 Total = 30.026 g/mol 90.09 g/mol Molar mass = ≈3 Formula mass 30.026 g/mol Molecular formula: (CH2O)3 = C3H6O3