N Dangerous For The Environment

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Bros – Ziarno na myszy i szczury
Bros – mouse and rat killer grain
Material Safety Data Sheet
MSDS Creation Date: 29.05.2008
MSDS update: 03.08.2009
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Trade name: Bros – Ziarno na myszy i szczury
Bros – mouse and rat killer grain
Product name: Bros - Ziarno na myszy i szczury
Bros – mouse and rat killer grain
Appearance: grain
Use of preparation: product is destined to control mice, rats and other rodents.
Manufacturer:
BROS Sp.j.
ul. Karpia 24; 61-619 PoznaƄ
telephone: (0-61) 82-62-512
fax: (0-61) 82-00-841
e-mail: biuro@bros.pl
(information about material safety data sheet)
Emergency telephone number:
telephone: +48 (0-61) 82-62-512
The Office of the Toxicological Information
in Warsaw, available: 8.00am -16.00pm
telephone: +48 (0-22) 619 08 97
telephone: +48 (0-22) 619 66 54
2. HAZARDS IDENTIFICATION
Classification:
Product is not classified as hazardous.
Product contains denatonium benzoate – bitter substance which prevent the accidental consumption by
human (especially children) and animals.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components:
NAME
Bromadiolon (active
substances)
CONCENTRATION
0.005%
NUMBER
28772-56-7
249-205-9
--T+; R26/27/28
CLASSIFICATION
Xn; R48, N; R50
CAS No.
CE No.
INDEX No.
4. FIRST AID MEASURES
Inhalation: Inhalation is unlikely with regard to the form of the product. Bring the person out to fresh air. If
victim has breathing difficulty consult a physician.
Skin contact: After contact with skin, wash immediately with plenty of water and soap.
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Bros – Ziarno na myszy i szczury
Bros – mouse and rat killer grain
Eye contact: In the case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Contact a physician immediately.
Ingestion: If victim is conscious give a water to rinse the mouth. Never give anything by mouth to an
unconscious person. Contact a physician immediately and show the label of the product.
Advice for physician: Bromadiolone is an indirect anticoagulant. Phytomenadione, Vitamin K1, is
antidotal. Determine prothrombin times not less than eighteen hours after consumption. If elevated,
administer Vitamin K1 and continue until prothrombin time normalises. Continue determination of
prothrombin time for two weeks after withdrawal of antidote and resume treatment if elevation occurs
in that time.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: Use standard fire extinguishing procedures. Use: foam, carbon dioxide,
dry powder and water spray.
Specific hazards during fire fighting: Irritating and/or toxic gases/fumes may be generated during a fire.
Special protective equipment for fire-fighters: protective clothing, glovs, self-contained breathing
apparatus. Use standard fire extinguishing procedures.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Use personal protective equipment: gloves. Avoid contact with eyes and skin.
Environmental precautions: there are no special requirements.
Methods for cleaning up: collect spilled product to the suitable container for disposal. Do not flush into
surface water or sanitary sewer system.
7. HANDLING AND STORAGE
Handling: Before the use read the label. Avoid contact with eyes, mouth and skin. When using do not
eat, drink and smoke. Wash hands and face before breaks and immediately after handling
the product. Keep out of the reach of children and animals.
Storage: Keep in a dry and cool place. Store in orginal container. Keep container tightly closed when
product is not use. Keep away from food, drink and animal feedingstuffs. Keep out of the
reach of children and animals.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Special requirements:
There are no special requirements. Keep out of the reach of children and animals.
Personal protective equipment:
Wear protective clothing, gloves. When using do not eat, drink and smoke. Wash hands before breaks
and immediately after handling the product. Avoid contact with skin and eyes.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and chemical properties
Physical state
grain
Odour
faint odour
Colour
pink
Water solubility
insoluble
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Bros – Ziarno na myszy i szczury
Bros – mouse and rat killer grain
10. STABILITY AND REACTIVITY
Chemical stability: stable under normal conditions of use.
Conditions to avoid: contact with strong oxidizers.
Hazardous products of decomposition, hazardous reactions and hazardous polimerizations: irritating
and/or toxic gases/fumes may be generated during a fire.
11. TOXICOLOGICAL INFORMATION
For the product:
Acute oral toxicity: may be harmful if swallowed.
Acute dermal toxicity: may irritate eyes and skin.
Acute inhalation toxicity: it should not irritate.
Acute dermal toxicity for eyes: may irritate the eyes.
Toxicological information:
LD50 (rat - oral)
45 [mg/kg]
LD50 (rat - dermal)
84 [mg/kg]
Bromadiolon / 28772-56-7
12. ECOLOGICAL INFORMATION
Product may be harmful for farm animals and domestic fowl. Taking into consideration the contents of
the dangerous substances, product is not classified as hazardous. Product is not harmful for natural
environment if it is used in accordance with instruction.
Ecological information:
LC50 96 h (Rainbow trout)
1,4 mg/dm3
Bromadiolon / 28772-56-7
LC50 96 h (various fish species)
1,4 - 3,0 mg/dm3
13. DISPOSAL CONSIDERATIONS
To dispose the large amount of waste contact with waste disposal services. W aste disposal carry out in
accordance with adequate regulations. Empty package treat like a community waste.
14. TRANSPORT INFORMATION
RID/ADR: not regulated
IATA: not regulated
IMO: not regulated
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Bros – Ziarno na myszy i szczury
Bros – mouse and rat killer grain
15. REGULATORY INFORMATION
Classification: point 2
Marking:
S2 Keep out of the reach of children
S13 Keep away from food, drink and animal feedingstuffs
S37 Wear suitable gloves
S46 If swallowed, seek medical advice immediately and show this container or label.
16. OTHER INFORMATION
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.
T+
Very toxic
Xn Harmful
N
Dangerous For The Environment
R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed
R48
Danger of serious damage to health by prolonged exposure
R50 Very toxic to aquatic organisms
S2 Keep out of the reach of children
S13 Keep away from food, drink and animal feedingstuffs
S37 Wear suitable gloves
S46 If swallowed, seek medical advice immediately and show this container or label.
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