Bros – Ziarno na myszy i szczury Bros – mouse and rat killer grain Material Safety Data Sheet MSDS Creation Date: 29.05.2008 MSDS update: 03.08.2009 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Trade name: Bros – Ziarno na myszy i szczury Bros – mouse and rat killer grain Product name: Bros - Ziarno na myszy i szczury Bros – mouse and rat killer grain Appearance: grain Use of preparation: product is destined to control mice, rats and other rodents. Manufacturer: BROS Sp.j. ul. Karpia 24; 61-619 PoznaĆ telephone: (0-61) 82-62-512 fax: (0-61) 82-00-841 e-mail: biuro@bros.pl (information about material safety data sheet) Emergency telephone number: telephone: +48 (0-61) 82-62-512 The Office of the Toxicological Information in Warsaw, available: 8.00am -16.00pm telephone: +48 (0-22) 619 08 97 telephone: +48 (0-22) 619 66 54 2. HAZARDS IDENTIFICATION Classification: Product is not classified as hazardous. Product contains denatonium benzoate – bitter substance which prevent the accidental consumption by human (especially children) and animals. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components: NAME Bromadiolon (active substances) CONCENTRATION 0.005% NUMBER 28772-56-7 249-205-9 --T+; R26/27/28 CLASSIFICATION Xn; R48, N; R50 CAS No. CE No. INDEX No. 4. FIRST AID MEASURES Inhalation: Inhalation is unlikely with regard to the form of the product. Bring the person out to fresh air. If victim has breathing difficulty consult a physician. Skin contact: After contact with skin, wash immediately with plenty of water and soap. 1/4 Bros – Ziarno na myszy i szczury Bros – mouse and rat killer grain Eye contact: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Contact a physician immediately. Ingestion: If victim is conscious give a water to rinse the mouth. Never give anything by mouth to an unconscious person. Contact a physician immediately and show the label of the product. Advice for physician: Bromadiolone is an indirect anticoagulant. Phytomenadione, Vitamin K1, is antidotal. Determine prothrombin times not less than eighteen hours after consumption. If elevated, administer Vitamin K1 and continue until prothrombin time normalises. Continue determination of prothrombin time for two weeks after withdrawal of antidote and resume treatment if elevation occurs in that time. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Use standard fire extinguishing procedures. Use: foam, carbon dioxide, dry powder and water spray. Specific hazards during fire fighting: Irritating and/or toxic gases/fumes may be generated during a fire. Special protective equipment for fire-fighters: protective clothing, glovs, self-contained breathing apparatus. Use standard fire extinguishing procedures. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Use personal protective equipment: gloves. Avoid contact with eyes and skin. Environmental precautions: there are no special requirements. Methods for cleaning up: collect spilled product to the suitable container for disposal. Do not flush into surface water or sanitary sewer system. 7. HANDLING AND STORAGE Handling: Before the use read the label. Avoid contact with eyes, mouth and skin. When using do not eat, drink and smoke. Wash hands and face before breaks and immediately after handling the product. Keep out of the reach of children and animals. Storage: Keep in a dry and cool place. Store in orginal container. Keep container tightly closed when product is not use. Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children and animals. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Special requirements: There are no special requirements. Keep out of the reach of children and animals. Personal protective equipment: Wear protective clothing, gloves. When using do not eat, drink and smoke. Wash hands before breaks and immediately after handling the product. Avoid contact with skin and eyes. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and chemical properties Physical state grain Odour faint odour Colour pink Water solubility insoluble 2/4 Bros – Ziarno na myszy i szczury Bros – mouse and rat killer grain 10. STABILITY AND REACTIVITY Chemical stability: stable under normal conditions of use. Conditions to avoid: contact with strong oxidizers. Hazardous products of decomposition, hazardous reactions and hazardous polimerizations: irritating and/or toxic gases/fumes may be generated during a fire. 11. TOXICOLOGICAL INFORMATION For the product: Acute oral toxicity: may be harmful if swallowed. Acute dermal toxicity: may irritate eyes and skin. Acute inhalation toxicity: it should not irritate. Acute dermal toxicity for eyes: may irritate the eyes. Toxicological information: LD50 (rat - oral) 45 [mg/kg] LD50 (rat - dermal) 84 [mg/kg] Bromadiolon / 28772-56-7 12. ECOLOGICAL INFORMATION Product may be harmful for farm animals and domestic fowl. Taking into consideration the contents of the dangerous substances, product is not classified as hazardous. Product is not harmful for natural environment if it is used in accordance with instruction. Ecological information: LC50 96 h (Rainbow trout) 1,4 mg/dm3 Bromadiolon / 28772-56-7 LC50 96 h (various fish species) 1,4 - 3,0 mg/dm3 13. DISPOSAL CONSIDERATIONS To dispose the large amount of waste contact with waste disposal services. W aste disposal carry out in accordance with adequate regulations. Empty package treat like a community waste. 14. TRANSPORT INFORMATION RID/ADR: not regulated IATA: not regulated IMO: not regulated 3/4 Bros – Ziarno na myszy i szczury Bros – mouse and rat killer grain 15. REGULATORY INFORMATION Classification: point 2 Marking: S2 Keep out of the reach of children S13 Keep away from food, drink and animal feedingstuffs S37 Wear suitable gloves S46 If swallowed, seek medical advice immediately and show this container or label. 16. OTHER INFORMATION The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. T+ Very toxic Xn Harmful N Dangerous For The Environment R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed R48 Danger of serious damage to health by prolonged exposure R50 Very toxic to aquatic organisms S2 Keep out of the reach of children S13 Keep away from food, drink and animal feedingstuffs S37 Wear suitable gloves S46 If swallowed, seek medical advice immediately and show this container or label. 4/4