Honors Chemistry I Mole Concept / Molarity / Empirical & Molecular Formulas Practice Test Make sure to use the proper number of sig. figs and include the proper units with all answers. 1.____5.664 x 10-23 g _______________________ What is the mass, in grams, of a single molecule of hydrosulfuric acid? 1 molec. H2S x (1 mol/6.022 x 1023) x (34.0808 g/1 mol) = 2.____107 g_____________ A 30.0-liter sample of dinitrogen pentoxide contains how many grams of oxygen? 30.0 L x (1 mol/22.4 L) x (5 mol O/1 mol N2O5) x (15.9998 g /1 mol) = 3.____5.09 x 1020 molecules _____________ How many molecules of water are present in 80.0 milligrams of ferric chlorate tetrahydrate? .0800 g x (1 mol/378.2542 g) x (4 mol water/1 mol ferric chlorate tetrahydrate) x (6.022 x 1023/1 mol) = 4._____68.3%____________ What is the percentage of metal in a 2.000-gram sample of barium dichromate? (241.32/353.32) x 100 = 5._____16.87 g____________ What is the mass of exactly 13.50 liters of carbon monoxide gas at STP conditions? 13.50 x (1 mol/22.41 L) x (28.010 g/1 mol)= 6.___6.40 x 1023 atoms ______________ What is the number of hydrogen atoms in 34.7 grams of phosphoric acid? 34.7 g x (1 mol/97.9937 g) x (3 mol H/1 mol phosphoric acid) x (6.022 x 1023/1 mol) = -27.___13.5 mol oxygen_____________ If you had 3.00 moles of auric carbonate, how many moles of pure oxygen gas could you get from this sample? [Hint: remember that oxygen gas is diatomic!] 3.00 mol auric carbonate x (9 mol oxygen/1 mol auric carbonate) x (1 mol O2/2 mol O) = 8.____3.891 x 1019 atoms _______________ sodium tetraborate? How many total atoms are in exactly 1.000 milligram of .001000 g x (1 mol/201.217 g) x (13 mol atoms/1 mol sodium tetraborate) x (6.022 x 1023/1 mol) 9.___.892 mol _______________ How many moles of perchloric acid do you need in order to release 10.0 liters of hydrogen gas (H2) at STP? 10.0 L x (1 mol/22.41L) x (2 mol perchloric acid/1 mol hyrdrogen) 10.___2.79 x1023 ions__________________ If a compound of stannic chloride contains 45.53% tin by weight, how many chloride ions are there in 30.0 grams of this compound? 54.47% chloride .5447 x 30.0 = 16.341 g Cl x (1 mol/35.453 g) x (6.022 x 1023/1 mol) = 11._____7.53 x 1023 ions ____________________ How many ions (total of both cations and anions) are there in 0.0250 moles of chromium(III) oxalate? .0250 mol Cr(III)ox x (5 mol ions/1 mol cmp) x (6.022 x 1023/1 mol) = 12._____1.01 mol___ How many moles of metal can be recovered from 125 grams of strontium molybdate? SrMoO4 125 g x (1 mol/247.556 g) x (2 mol Metal/1 mol cmp) = -313.____904 mL_____________ If 300.0 milliliters of a 6.15 M solution of nitric acid is diluted until the new concentration is only 2.04 M, what will be the final volume of this diluted solution? (6.15)(300.0) = (2.04)(V) 14.___Ca3(PO4)2 ___________ What is the empirical formula of a substance that is analyzed and found to contain 38.77% calcium, 19.98% phosphorus, and 41.25% oxygen? 38.77 g Ca x (1 mol/40.078) = 0.9674/.6451 = 1.500 x 2 = 3 19.98 g P x (1 mol/30.974) = 0.6451/.6451 = 1 x 2 = 2 41.25 g O x (1 mol/15.999) = 2.578/.6451 =3.996 x 2 = 8 Ca3P2O8 15.__119 mL_______________ How much water must be added to 45.0 ml of a 2.00 M solution of phosphoric acid to produce a 0.550 M solution of this acid? (2.00)(45.0) = (0.550)(V) V = 164 mL (new solution volume) 164-45.0 = 119 mL water to be added 16.___N4O8 ______________ 4.72 grams of a gas at STP conditions occupies 575 ml. This gas is known to contain 30.435% nitrogen and 69.565% oxygen. What is the true, or molecular formula? .575 L x (1 mol/22.41 L) = 0.0257 mol MM = 4.72 g/0.0257 mol = 184 g/mol 30.435 g N x (1 mol/14.007 g) = 2.1728 mol/2.1728 = 1 69.565 g O x (1 mol/15.999 g) = 4.3481 mol/2.1728 = 2.0011 NO2 = 46 g/mol 184/46 = 4 17.____2.43 g_____________ How many grams of barium hydroxide need to be added to 750.0 ml of water in order to produce a 0.0189 M solution of this base? 0.0189 M = x mol/.7500 x = 0.0142 mol x (171.3438 g/1 mol) = 18.____Ba(NO3)2·7H2O ________________When 44.466 grams of a hydrate of barium nitrate is heated, 30.000 grams of the anhydrous residue remains. What is the correct formula of this hydrate? 30.000 g Ba(NO3)2 x (1 mol/261.338 g) = .11479 mol/.11479 = 1 14.466 g H2O x (1 mol/18.0148 g) = .80301 mol/.11479 = 6.9954 -419.___0.726 M____________ What is the molarity of a solution if 1.35 grams of lithium chlorite is added to enough water to make 25.0 ml of solution? 1.35 g x (1 mol/74.392) = 0.0181 mol M = 0.0181/.0250 20.____6.45 L____________ How many liters of water must be added to 4.75 liters of a 10.25 M solution of potassium chloride in order to end up with 11.20 liters of a 4.347 M solution? 11.20-4.75 = 21.__7.50 M__________________ What is the [S-2] if 2.00 moles of ferric sulfide is added to enough water to produce 800.0 ml of solution? Fe2S3 M = 2.00/.8000 = 2.50 M = [Fe2S3] 2.50 x 3 = 22.___Mn2O3 ________________ Oxygen gas is passed over a 5.000-gram sample of solid manganese and allow to react with this metal. If 7.186 grams of an oxide form of manganese is produced, what is the empirical formula of this compound? 5.000 g Mn x (1 mol/54.938 g) = 0.09101mol/.09101 = 1x 2 = 2 2.186 g O x (1 mol/15.999 g) = 0.1366 mol/.09101 = 1.501 x 2 = 3 23.____C20H27O6________________ An organic compound is known to contain 48.00 grams of carbon, 24 3.25 x 10 atoms of hydrogen, and 1.20 moles of oxygen atoms. If 4.000 grams of this compound is known to be 0.01102 moles, what its true molecular formula? 48.00 g x (1 mol/12.011 g) = 3.996 mol/1.20 = 3.33 x 6 = 20 3.25 x 1024 atoms x (1 mol/6.022 x 1023) = 5.40 mol/1.20 = 4.5 x 6 = 27 1.20 mol O/1.20 = 1.00 x 6 = 6 C20H27O6 = 363.4273 MM = 4.000/0.01102 = 363.0