Experiment study on the abrasion and impact performance of cement-based composites using fiber and silica fume Wei-Ting Lin, Der-Chang Suen Department of Architecture, National Jui-Fang Industrial Vocational High School ABSTRACT An experimental program was carried out to evaluate the mechanical properties of cement-based composites. Test variables included water to cementitious ratio, dosage of silica fume and volume fraction of steel fiber and abrasion resistance test and drop weight test were performed. Addition of fibers provided better performance for the cement-based composites, while silica fume in the composites may adjust the fiber dispersion and strength losses caused by fibers, and improve strength and the bond between fiber and matrix with dense calcium-silicate-hydrate gel. The combination of steel fibers and silica fume can increase greatly abrasion and impact resistance of cement-based composites. Keywords: abrasion coefficient, impact number, cement-based composites INTRODUCTION Cement-based composites have long been used for civil structures such as highways, bridges and buildings. However, the unexpected deterioration of reinforced or pre-stressed concrete structures has led to the improvement of durability. Traditionally, the composition of cement-based composites includes cementitious material, water, aggregate and/or admixtures. Fiber has been added in the fiber cement-based composites (FCC) since 1960’s to improve concrete properties, particularly tensile strength, abrasion resistance and energy absorbing capacity [1-3]. The presence of fiber helps to refrain crack growth or propagation and transfer load to the un-cracked part [4-5]. The specimen with fibers has much higher ductility than the specimen without fibers. Fibers by bridging the cracks in the cementitious composites increase the energy absorption or toughness [6]. However, the properties of FCC would be affected by the type, volume fraction and aspect ratio of fiber. Lower fiber volume fraction is usually preferred by considering the material cost and workability [7]. According to the results of previous researches, the volume fraction suggested was around 2 % to achieve effectiveness in cement-based composites [8]. In addition, it was also reported that the combination of silica fume with steel fibers would effectively enhance the compressive strength, splitting tensile strength, 1 abrasion resistance and impact resistance of cement-based composites and be beneficial for fiber dispersion. This study was aimed to evaluate the combined effect of silica fume and steel fiber on the abrasion and impact resistance of cement-based composites using experimental program. EXPERIMENTAL PROGRAM 1. Materials and mix proportions Type I Portland cement conforming to ASTM C150-05 was used in all mixes. Silica fume with specific gravity of 2.20 and specific surface area of 22500 m2/kg was used. The diameter of silica fume particle was about 0.1-0.2μm. The chemical compositions of cement and silica fume are listed in Table 1. Hooked-end steel fiber with an aspect ratio (l/d) of 40 was applied. The average length and tensile strength of steel fiber was 30 mm and 1100 N/mm2, respectively. Table 1 Composition and specific gravity of Portland cement and silica fume Chemical composition SiO2 (%) Al2O3 (%) Fe2O3 (%) CaO (%) MgO (%) SO3 (%) L.O.I.* (%) K2O+Na2O (%) Others (%) Specific gravity Portland cement 21.2 5.4 3.2 63.8 2.0 2.2 0.7 0.8 0.7 3.15 Silica fume 91.5 0.2 0.7 0.4 1.5 0.5 1.4 1.9 1.9 2.20 Table 2 Mix design (kg/m3) Mix no. w/cm* Water A 0.35 189.4 Af1 0.35 189.4 Af2 0.35 189.4 Af3 0.35 189.4 A1 0.35 189.4 A1f1 0.35 189.4 A1f2 0.35 189.4 A1f3 0.35 189.4 A2 0.35 189.4 A2f1 0.35 189.4 A2f2 0.35 189.4 A2f3 0.35 189.4 B 0.55 217.0 Bf1 0.55 217.0 Bf2 0.55 217.0 Bf3 0.55 217.0 B1 0.55 217.0 B1f1 0.55 217.0 B1f2 0.55 217.0 B1f3 0.55 217.0 B2 0.55 217.0 B2f1 0.55 217.0 B2f2 0.55 217.0 B2f3 0.55 217.0 * water/cementitious ratio ** superplasticizer Cement Silica fume 558.0 558.0 558.0 558.0 530.1 530.1 530.1 530.1 502.2 502.2 502.2 502.2 395.0 395.0 395.0 395.0 375.2 375.2 375.2 375.2 355.5 355.5 355.5 355.5 0 0 0 0 27.9 27.9 27.9 27.9 55.8 55.8 55.8 55.8 0 0 0 0 19.8 19.8 19.8 19.8 39.5 39.5 39.5 39.5 2 Fine aggregate 908.0 901.0 894.0 881.0 908.0 901.0 894.0 881.0 908.0 901.0 894.0 881.0 908.0 901.0 894.0 881.0 908.0 901.0 894.0 881.0 908.0 901.0 894.0 881.0 Coarse aggregate 700.0 694.0 687.0 674.0 700.0 694.0 687.0 674.0 700.0 694.0 687.0 674.0 780.0 773.0 767.0 753.0 780.0 773.0 767.0 753.0 780.0 773.0 767.0 753.0 Fiber SP** 0 39.0 78.0 156.0 0 39.0 78.0 156.0 0 39.0 78.0 156.0 0 39.0 78.0 156.0 0 39.0 78.0 156.0 0 39.0 78.0 156.0 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 0 0 0 0 0 0 0 0 0 0 0 0 The water/cementitious ratio was kept at 0.35 and 0.55, respectively. The maximum size of coarse aggregates was 13mm and the fineness modulus of fine aggregates was 2.87. Mixture slump was controlled around 150mm by adjusting proper amount of high-range water-reducing admixture in the mixes. The details of mix proportions of FCC are shown in Table 2. Silica fume with 5% and 10% by the weight of cement was used to replace cement partially. The volume fraction was defined as the steel fiber volume divided by the total concrete volume and the steel fiber content was used to replace aggregate partially. Concrete mixtures with volume fraction of 0.5%, 1.0% and 2.0% steel fiber were designed. 2. Specimens Specimens with a total of 24 different mixes were cast. For each mix, six ψ150×64 mm circular plate for abrasion resistance test and drop weight test were prepared and cured in saturated lime water until testing. Mix number A and B refer to a water/cement ratio of 0.35 and 0.55, mix number 1 and 2 refer to the silica fume content of 5 % and 10 %, and mix number f1, f2 and f3 refer to the steel fiber content of 0.5 %, 1.0 % and 2.0%, respectively. 3. Testing methods An abrasion resistance test was conducted following the specifications of ASTM C418-05. The method covers the determination of abrasion resistance characteristics of FCC by subjecting the specimen to the impingement of air-driven silica sand, and abrasion coefficient was determined accordingly. The abrasion coefficient is an index of abrasion resistance of cement-based composite and obtained from AC V A , where A is the test abraded surface area, V is the abraded volume and AC is the abrasion coefficient. Impact resistance assessment was performed following the recommendations of ACI committee 544. A 63.5 mm-diameter steel ball with 4.54 kg weight dropped from a height of 914 mm and recorded the number of drops until the first visible crack and ultimate failure was found. Ultimate failure is defined as the opening of cracks in the specimen sufficiently so that concrete specimen touches three of the four positioning lugs on the base plate. RESULTS AND DISCUSSION 1. Abrasion resistance test The abrasion coefficient of specimen decreases as the fiber and silica fume content increases as indicated in Fig. 1 at the age of 120 days. The inclusion of 0.5% steel fiber in the composites markedly decreases the abrasion coefficient than that of control. The abrasion coefficient is remained steady though the addition of steel fiber content exceeded in the value of 1%. Another, the abrasion coefficient also 3 decreases with the addition of silica fume increases for each w/cm ratio. The addition of steel fiber in the composites produces a denser and stronger surface, thus resulting in a higher resistance to wear for FCC specimens. The abrasion coefficient of A2f3 and B2f3 specimens is 2.21x10-3 and 3.21x10-3, respectively, which is about 50% lower than that of control specimen. The cement-based composites with 10% silica fume and 2% fiber also exhibit an excellent ability in abrasion resistance. The abrasion coefficient appears to decrease exponentially as compressive strength increases as illustrated in Fig. 2. Clearly, the curve between compressive strength and abrasion coefficient with high w/cm ratio drops significantly faster than that with low w/cm ratio. It indicates that w/cm ratio also plays an important role on abrasion coefficient except silica fume content and steel fiber content. 8 w/cm = 0.35, silica fume = 0 % w/cm = 0.35, silica fume = 5 % w/cm = 0.35, silica fume = 10 % w/cm = 0.55, silica fume = 0 % w/cm = 0.55, silica fume = 5 % w/cm = 0.55, silica fume = 10 % 6 Abrasion coefficient (x10-3) - Abrasion coefficient (x10 3) 8 4 2 6 4 2 w/cm = 0.35, Y=1.40+99.57e-0.06X R2=0.91 w/cm = 0.55, Y=3.00+442527.94e-0.32X R2=0.97 0 0 0 0.5 1 1.5 2 30 Steel fiber content (vol. %) 40 50 60 70 80 Compressive strength (MPa) Fig. 1 - Abrasion coefficient vs. Fiber content Fig. 2 - Abrasion coefficient vs. Compressive strength Table 3 Drop weight test results Mix no. A Af1 Af2 Af3 A1 A1f1 A1f2 A1f3 A2 A2f1 A2f2 A2f3 B Bf1 Bf2 Bf3 B1 B1f1 B1f2 B1f3 B2 B2f1 B2f2 B2f3 Impact number of initial crack, N1 59 54 86 88 4 20 70 115 7 19 70 350 98 110 130 222 30 27 40 71 35 33 35 94 Impact number of ultimate failure, N2 63 70 113 133 19 43 116 175 11 32 128 460 103 129 171 252 33 47 92 135 39 46 53 154 4 Difference between N1 and N2, △N 4 16 27 45 15 23 46 60 4 13 58 110 5 19 41 30 3 20 52 64 4 13 18 60 Impact toughness (KN-m) 2.54 2.82 4.56 5.37 0.77 1.73 4.68 7.06 0.44 1.29 5.16 18.56 4.16 5.20 6.90 10.17 1.33 1.90 3.71 5.45 1.57 1.86 2.14 6.21 2. Drop weight test The impact number at ultimate failure serves as a qualitative estimate of the energy absorbed by the specimens. The impact performance serves as a quantitative index by impact number of initial crack (N1), impact number of ultimate failure (N2), difference between N1 and N2 (△N) and impact toughness (T). Impact toughness is calculated by T=N2mgh, where m, g and h is weight of the ball, acceleration of gravity and height, respectively. The results of drop weight test are summarized in Table 3, which indicates the specimen with higher w/cm ratio has higher increase in the energy-absorbed capacity than the specimen with lower w/cm ratio. As previous discussion, the microstructure of cement-based composites could be densified and become stronger and more brittle by incorporation of silica fume so that the impact number at ultimate failure decreases as the silica fume content increases. However, FCC specimens with proper fiber contents could exhibit ductile property and usually the energy absorbed capacity increases with an increasing fiber content. The key to increasing the performance of cement-based composites under impact is to increase its cracking resistance. Steel fibers in the composites can restrain the extension of the crack, change the direction of crack growth and delay the growth rate of the crack. Besides, incorporating silica fume into the composites can improve further the interfacial characteristics, which is improved by the filler effect and the pozzolanic effect of the silica fume. Mix A specimen with 10% silica fume and 2% fiber having energy absorbed capacity 7.3 times than the control specimen and it presents excellent impact resistance. It indicated that the A2f3 specimen has a great ability to absorb impact energy due to the combined effect of the steel fiber and silica fume. CONCLUSIONS Steel fiber incorporation in cement-based composites results in significant improvement in abrasion and impact resistance. Silica fume incorporation in cement-based composites benefits fiber dispersion and significantly improves the bond between fiber and matrix. 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