Vita: Edward Allen Boyle July 29, 2013 ADDRESS: Department of Earth, Atmospheric, and Planetary Sciences TELEPHONE: 617-253-3388 Massachusetts Institute of Technology FAX: 617-253-8630 Cambridge MA 02139 EMAIL: eaboyle@mit.edu BIRTHDATE: May 1, 1949 EDUCATION: CITIZENSHIP: U.S.A. B.A. 1971 (Chemistry), University of California, San Diego (1971) Highest Honors Ph.D. 1976 (Oceanography), Massachusetts Institute of Technology/ Woods Hole Oceanographic Institution EMPLOYMENT Postdoctoral Fellow, University of Edinburgh (1976-1977) Assistant Professor, Massachusetts Institute of Technology (1977-1981) Associate Professor, Massachusetts Institute of Technology (1981-1990) Professor, Massachusetts Institute of Technology (1990-present) HONORS: National Science Foundation Graduate Fellow, 1971-1975 NATO Postdoctoral Fellow, 1976-1777 Guggenheim Fellow, 1991-1992 Fellow, American Geophysical Union (1994) Huntsman Award, Bedford Institute of Oceanography (1994) Geochemistry Fellow, Geochemical Society and European Association for Geochemistry (1998) Patterson Medal, Geochemical Society (2000) Honorary Fellow, European Geosciences Union (2003) Member, National Academy of Sciences (2008) PROFESSIONAL ORGANIZATIONS: American Geophysical Union Geochemical Society Oceanography Society American Association for the Advancement of Science American Chemical Society INTERNATIONAL SCIENTIFIC COMMITTEES: GEOTRACES International Science Steering Committee, Co-Chair (2011-present) Scientific Advisory Board, IFM-GEOMAR (1990-2011) EDITORIAL AFFILIATIONS: Editor, EARTH AND PLANETARY SCIENCE LETTERS (1999-2005) Associate Editor, MARINE CHEMISTRY Seagoing Experience (* = Chief Scientist or Co-Chief Scientist) Period April 1972 July1972 June1974 April 1975 June1976 Oct.1978 Nov.1979 April 1981 Sept. 1981 April 1982 June1982 June1983 Sept. 1983 Nov. 1983 Jan.1984 April 1984 June1984 Sept. 1984 Dec.1984 Jan.1986 Sept. 1987 March 1987 April 1987 ?Jun. 1987 Jan.1988 April 1988 June1988 Aug.1988 Oct.1988 Oct.1989 Jan.1990 May 1990 Oct. 1993 Jun. 1995 Aug. 1995 Aug. 1996 May 1997 Jul. 1997 July 1998 Nov. 1998 May 1998 Sept. 1999 Ship Ports R/V Knorr R/V Chain R/V Chain R/V Chain R/V Alpha Helix R/V Oceanus USNS DeSteiguer USNS Lynch R/V Gillis R/V Gyre USNS Bartlett *R/V Weatherbird *R/V Weatherbird *R/V Endeavor *R/V Weatherbird *R/V Weatherbird *R/V Weatherbird *R/V Endeavor *R/V Weatherbird R/V Oceanus R/V Endeavor *R/V Endeavor R/V Oceanus *R/V Weatherbird *R/V Weatherbird *R/V Knorr *R/V Weatherbird *R/V Knorr *R/V Weatherbird *R/V Atlantis II *R/V WeatherbirdII *R/V WeatherbirdII *R/V WeatherbirdII R/V Marion Dufresne R/V WeatherbirdII R/V WeatherbirdII R/V WeatherbirdII R/V WeatherbirdII R/V Oceanus R/V Moana Wave R/V Moana Wave *R/V Endeavor San Juan - San Juan St. Johns - Lisbon - Cork Fortaleza - Barbados Alexandria - Alexandria Balboa - Belem - Iquitos Lisbon - Dakar - Recife Balboa - Acapulco Ft. Lauderdale - Gulfport Miami - Miami St. Petersburg - Pilottown LA Cadiz - Rota St. George St. George Narragansett - Panama St. George St. George St. George Narragansett - St. George St. George St. George - Woods Hole Narragansett - St. George Narragansett - Portland ME Cadiz - Cadiz St. George St. George Cadiz - Izmir St. George Cagliari - Cadiz St. George Woods Hole - Punta del Gada St. George St. George St. George Brest - Punta del Gada St. George St. George St. George St. George Woods Hole - Woods Hole Honolulu - Honolulu Honolulu - Honolulu Narragansett-Punta del Gada Approx. Days at Sea 14 49 21 20 50 19 22 14 13 15 10 1 1 10 1 1 1 10 1 8 7 15 3 1 2 14 1 4 1 22 1 2 2 37 1 1 2 2 17 2 5 26 Jan. 2001 R/V Seward Johnson Mar. 2002 *R/V Endeavor Sept. 2002 R/V Kilo Moana Oct. 2004 R/V Melville July 2005 *R/V Endeavor Mar. 2007 R/V Kilo Moana June 2008 R/V Knorr Aug. 2008 R/V Oceanus Oct. 2010 *R/V Knorr March 2010 Bahith-II January 2012 Bahith-II NovDec2011 *R/V Knorr Ft. Pierce-Barbados Barbados-Rio de Janeiro Honolulu-Honolulu Honolulu-San Diego Narragansett-Barbados Australia-Fiji Norfolk-St. George Barbados-Cape Verde Islands Lisbon-Cape Verde Islands Northern Persian Gulf Northern Persian Gulf Woods Hole-Cape Verde Islands 20 21 13 25 19 38 18 29 21 3 2 37 ____ 695 * Chief or co-chief scientist Forthcoming: PUBLICATIONS 1. Jolly, W.L. and E.A. Boyle, Coulometric potentiometric titrations of weak acids in liquid ammonia, Analytical Chemistry, 43, 514-518, 1971. 2. Jolly, W.L. and E.A. Boyle, The use of indicators in acid-base titrations in liquid ammonia, J. Inorg. Nucl. Chem., 33, 783-789, 1971. 3. Boyle, E.A., R. Collier, A.T. Dengler, J.M. Edmond, A.C. Ng, and R.F. Stallard, On the geochemical mass balance in estuaries, Geochim. Cosmochim. Acta, 38, 1719-1728, 1974. 4. Boyle, E.A. and J.M. Edmond, Determination of trace metals in aqueous solution by APDC chelate coprecipitation, in: Analytical Methods in Oceanography (ed. T.R.P. Gibb, Jr.), Advances in Chemistry series, No. 147, American Chemical Society, 44-45, 1975. 5. Milliman, J.D. and E.A. Boyle, Biological uptake of dissolved silica in the Amazon River Estuary, Science, 189, 995-997, 1975. 6. Boyle, E.A. and J.M. Edmond (1975) Copper in surface waters south of New Zealand, Nature 253:107-109. 7. Sclater, F.R., E.A. Boyle, and J.M. Edmond, On the marine geochemistry of nickel, Earth and Planet. Sci. Lett., 31, 119-128, 1976. 8. Boyle, E.A., F.R. Sclater, and J.M. Edmond, On the marine geochemistry of cadmium, Nature,263, 42-44, 1976. 9. Boyle, E.A., F.R. Sclater, and J.M. Edmond, Determination of copper, nickel, and cadmium in seawater by APDC chelate coprecipitation and flameless atomic absorption spectrometry, Anal. Chim. Acta, 91, 189-197, 1977. 10.Boyle, E.A. and J.M. Edmond, On the carbonate saturation-dissolution rate relationship, in: The Fate of Fossil Fuel CO2 in the Oceans, (eds. N.R. Anderson and A. Malahoff), Plenum Press, N.Y., 261-268, 1977. 11. Boyle, E.A., F.R. Sclater, and J.M. Edmond, The distribution of dissolved copper in the Pacific, Earth and Planet. Sci. Lett., 37, 38-54, 1977. 12. Boyle, E.A., J.M. Edmond, and E.R. Sholkovitz, The mechanism or iron removal in estuaries, Geochim. Cosmochim. Acta, 41, 1313-1324, 1977. 13. Edmond, J.M., E.A. Boyle, D. Drummond, B. Grant, T. Mislick, Desorption of barium in the plume of the Zaire (Congo) River, in the Netherlands Journal of Sea Research, 12(3/4):324328,1978. 14. Sholkovitz E. R., Boyle E. A., and Price N. B. (1978) The removal of dissolved humic acids and iron during estuarine mixing. Earth and Planet. Sc. Lett. 40, 130-136. 15. Boyle, E.A., Copper in natural waters, in: Copper in the Environment, Part 1, 1979. 16. Sclater, F.R., E.A. Boyle, and J.M. Edmond, A quantitative analysis of some factors affecting carbonate sedimentation in the oceans, in Deep Drilling Results in the Atlantic Ocean: Continental Margins and Paleoenvironment, (eds. Talwani, Hay and Ryan), AGU, Maurice Ewing Series No. 3, 1979. 17. Boyle, E.A., Cadmium, zinc, copper and barium in foraminifera tests, Earth and Planet. Sci. Lett., 53, 11-35, 1981. 18. Boyle, E.A., S.S. Huested, and S.P. Jones, On the distribution of copper, nickel, and cadmium in the surface waters of the North Atlantic and North Pacific Ocean, J. Geophys. Res., 86, C9, 8048-8066, 1981. 19. Edmond, J.M., E.A. Boyle, B. Grant, and R.F. Stallard, The Chemical Mass Balance in the Amazon Plume I: The Nutrients, Deep Sea Research, 28A, 11, 1339-1374, 1981. 20. Boyle, E.A., S.S. Huested, and B.C. Grant (1982) Chemical mass balance in the Amazon Plume II: copper, nickel and cadmium, Deep Sea Research: 29:1355-1364. 21. Boyle, E.A. and L.D. Keigwin, Deep Circulation of the North Atlantic over the last 200,000 years: Geochemical Evidence (1982) Science, 218:784-787. 22. Hester, K. and E.A. Boyle (1982) Water chemistry control of the cadmium content of some recent benthic foraminifera, Nature, 298:260-262. 23. Spivack, A.J., S.S. Huested, and E.A. Boyle (1983) Copper, Nickel and Cadmium in the surface waters of the Mediterranean, NATO, Advanced Study Institute on Trace Metals in Seawater, eds. C.S. Wong et al., Plenum, N.Y. 24. Delaney, M.L. and E.A. Boyle (1983) Uranium and Thorium isotope concentrations in foraminiferal calcite, Earth Planet. Sci. Lett., 62:258-262. 25. Boyle, E.A. (1983) Chemical variability and sediment accumulation rate variations under the Peru current during the past 130,000 years, J. Geophys. Res., 88:7667-7680. 26. Boyle, E.A. (1983) Manganese carbonate overgrowths on foraminifera tests, Geochim. Cosmochim. Acta, 47:1815-1819. 27. Boyle, E.A. (1984) Cadmium in Benthic Foraminifera and Abyssal hydrography: Evidence for a 41 kyr. Obliquity cycle, in: Climate Processes and Climate Sensitivity, (eds. T. Takahashi and J. Hansen), American Geophysical Uniion Maurice Ewing Series No. 5,, Geophysical Monograph, 29:360-368. 28. Boyle, E.A., D.F. Reid, S.S. Huested and J. Hering (1984) Trace metals and radium in the Gulf of Mexico: an evaluation of river and continental shelf sources, Earth Planet. Sci. Lett., 69:69-87. 29. Boyle, E.A., Sampling statistic limitations on benthic foraminifera chemical and isotopic data (1984) Marine Geology, 58:213-224. 30. Keigwin, L.D. and E.A. Boyle (1985) Carbon isotopes in deep-sea benthic foraminifera: precession and changes in low-latitude biomass, in: The carbon cycle and atmospheric CO2: Natural Variations Archean to Present (eds. E.T. Sundquist and W.F. Broecker), American Geophysical Union Monograph 32:319-328. 31. Shiller, A.M., and E.A. Boyle (1985) Dissolved zinc in rivers, Nature 317:49-52. 32. Boyle, E.A., S.D. Chapnick, X.X. Bai, A. Spivack and S.S. Huested (1985) Trace metal enrichments in the Mediterranean Sea, Earth Planet. Sci. Lett., 74:405-419. 33. Delaney, M.L., A.W.H. Be, and E.A. Boyle (1985) Li, Sr, Mg, and Na in foraminiferal calcite shells from laboratory culture, sediment traps, and sediment cores, Geochim Cosmochim. Acta 49:1327-1341. 34. Boyle, E.A. and L.D. Keigwin (1985/6) A Comparison of Paleochemical Records from the North Atlantic and North Pacific Ocean: Changes in Deep Ocean Circulation and Chemical Inventories, Earth Planet. Sci. Lett., 76:135-150. 35. Boyle, E.A. (1986) Paired Cd and 13C data from benthic foraminifera: implications for ocean circulation, phosphorus, and atmospheric CO2, Geochim. Cosmochim. Acta., 50:265276. 36. Boyle, E.A., S.D. Chapnick, G.T. Shen and M.P. Bacon (1986) Temporal Variability of Lead in the Western North Atlantic Ocean, J. Geophys. Res. 91:8573-8593. 37. Delaney, M.L. and E.A. Boyle (1986) Lithium in foraminiferal shells: implications for hightemperature hydrothermal circulation fluxes and oceanic crustal generation rates during the last 116 m.y., Earth. Planet. Sci. Lett. 80:91-105. 38. Boyle, E.A. (1986) Deep-ocean circulation, preformed nutrients, and atmospheric carbon dioxide: theories and evidence from oceanic sediments, in: Mesozoic and Cenozoic Oceans (ed. K.J. Hsu), American Geophysical Union, Geodynamics Series 15:49-59. 39. Shen, G.T. and E.A. Boyle (1987) Lead in corals: reconstruction of historical industrial fluxes to the surface ocean, Earth Planet. Sci. Lett. 82:289-304. 40. Boyle, E.A., B. Handy, and A. van Geen (1987) Cobalt determination in natural waters using cation-exchange liquid chromatography with luminol chemiluminescence detection, Anal. Chem. 59:1499-1503. 41. Shen, G.T., E.A. Boyle, and D.W. Lea (1987) Cadmium in corals: chronicles of historical upwelling and industrial fallout, Nature 328:794-796. 42. Boyle, E.A. and L.D. Keigwin (1987) North Atlantic thermohaline circulation during the last 20,000 years: link to high latitude surface temperature, Nature 330:35-40. 43. Delaney, M. and E.A. Boyle (1987) Cd/Ca in Late Miocene benthic foraminifera and changes in the global organic carbon budget, Nature 330:156-159. 44. Shiller, A.M. and E.A. Boyle (1987) Trace metal variability in the Mississippi River, Geochim. Cosmochim. Acta 51:3273-3277. 45. Shiller, A.M. and E.A. Boyle (1987) Dissolved vanadium in rivers and estuaries, Earth Planet. Sci. Lett. 86:214-224. 46. Boyle, E.A. (1988) Vertical oceanic nutrient fractionation and glacial/interglacial CO2 cycles, Nature 331:55-56. 47. van Geen, L., P. Rosener, and E.A. Boyle (1988) Entrainment of trace metal enriched Atlantic shelf water in the inflow to the Mediterranean Sea, Nature 331:422-426. 48. Shen, G.T. and E.A. Boyle (1988) Determination of lead, cadmium, and other trace metals in annually-banded corals, Chem. Geol. 67:47-62. 49. Delaney, M.L. and E.A. Boyle (1988) Tertiary paleoceanic chemical variability: unintended consequences of simple geochemical models, Paleoceanography 3: 137-156.47. 50. Boyle, E.A. (1988) Cadmium: chemical tracer of deep-water paleoceanography, Paleoceanography 3:471-490.48. 51. Sherrell, R. and E.A. Boyle (1988) Zinc, chromium, vanadium, and iron in the Mediterranean Sea, Deep-Sea Res. 35:1319-1334. 52. Boyle, E.A. (1988) The role of vertical chemical fractionation in controlling late Quaternary atmospheric carbon dioxide, J.Geophys.Res.93:15701-15714. 53. Shen, G.T. and E.A. Boyle (1988) Thermocline ventilation of anthropogenic lead in the western North Atlantic, J. Geophys. Res. 93:15715-15732. 54. Lea, D. and E.A. Boyle (1989) Barium content of benthic foraminifera controlled by bottom water composition, Nature 338:751-753. 55. Lea, D.W., G.T. Shen, and E.A. Boyle (1989) Coralline barium records temporal variability in Equatorial Pacific upwelling, Nature 340:373-375. 56. Keigwin, L.D. and E.A. Boyle (1989) Late Quaternary paleochemistry of high-latitude surface waters, Paleoclimatol. Paleogeog. Paleoecol. 73:85-106. 57. Shackleton, N.J., T.H. van Andel, E.A. Boyle, E. Jansen, L. Labeyrie, M. Leinen, J. McKenzie, L. Mayer, and E. Sundquist (1990) Contributions from the oceanic record to the study of global change on three time scales - Report of Working Group 1, Interlaken Workshop for Past Global Changes, Paleoclimatol. Paleogeog. Paleoecol. (Global and Planetary Change) 82:5-37. 58. van Geen, A. and E.A. Boyle (1990) Automated pre-concentration of trace metals from seawater and freshwater, Anal. Chem. 62:1705-1709. 59. Boyle, E.A. (1990) Quaternary deep water paleoceanography, Science 249:863-870. 60. Lea, D.W., and E.A. Boyle (1990) 200,000 year record of Barium in the deep western North Atlantic, Nature 347:269-272. 61. Boyle, E.A. and P. Rosener (1990) Further evidence for a link between Late Pleistocene North Atlantic surface temperatures and North Atlantic Deep Water Production, Paleoclimatol. Paleogeog. Paleoecol. (Global and Planetary Change) 89: 113-124. 62. van Geen, A. and E.A. Boyle (1990) Variability of trace metal fluxes through the Straits of Gibraltar, Paleoclimatol. Paleogeog. Paleoecol. (Global and Planetary Change) 89: 65-80. 63. Orians, K.J., E.A. Boyle, and K.W. Bruland (1990) Dissolved Titanium in the Open Ocean, Nature 348:322-325. 64. Lea, D.W. and E.A. Boyle (1990) Foraminiferal reconstruction of barium distributions in water masses of the glacial oceans, Paleoceanogr. 5: 719-742. 65. Boyle, E.A. (1991) Quaternary Ocean Paleochemistry, Rev. Geophysics Suppl. 634-638. 66. van Geen, L., E.A. Boyle, and W.S. Moore (1991) Trace metal enrichments in the Gulf of Cadiz, Geochim. Cosmochim. Acta 55: 2173-2192. 67. Keigwin, L.D., G.A. Jones, S.J. Lehman, and E.A. Boyle (1991) Deglacial meltwater discharge, North Atlantic deep circulation, and abrupt climate change, J. Geophys. Res. 96: 16811-16826. 68. Lea, D.W., and E.A. Boyle (1991) Barium in planktonic foraminifera and corals, Geochim. Cosmochim. Acta 55:3321-3333. 69. Shiller, A.M. and E.A. Boyle (1991) Trace elements in the Mississippi River Delta outflow region: behavior at high discharge, Geochim. Cosmochim. Acta. 55:3241-3251. 70. Boyle, E.A. (1992) Cadmium and 13C paleochemical ocean distributions during the stage 2 glacial maximum, Ann. Rev. Earth Planet. Sci. 20:245-287. 71. Sherrell, R.M., E.A. Boyle, and B. Hamelin (1992) Isotopic equilibration between dissolved and suspended particulate lead in the Atlantic Ocean: evidence from Pb-210 and stable Pb isotopes, J. Geophys. Res. 97:11257-11268. 72. Sherrell, R.M. and E.A. Boyle (1992) The trace metal composition of suspended particles in the oceanic water column near Bermuda, Earth Planet. Sci. Lett. 111:155-174. 73. Colodner, D.C., E.A. Boyle, J.M. Edmond, and J. Thomson (1992) Post-depositional mobility of platinum, iridium, and rhenium in marine sediments, Nature 358:402-404. 74. Imbrie, J., E.A. Boyle, S.C. Clemens, A. Duffy, W.R. Howard, G. Kukla, J. Kutzbach, D.G. Martinson, A. McIntyre, A.C. Mix, B. Molfino, J.J. Morley, L.C. Peterson, N.G. Pisias, W.L. Prell, M.E. Raymo, N.J. Shackleton, and J.R. Toggweiler (1992), On the structure and origin of major glaciation cycles 1. Linear responses to Milankovitch forcing, Paleoceanogr. 7:701738. 75. Rosenthal, Y. and E. Boyle (1993) Factors controlling the fluoride content of planktonic foraminifera: an evaluation of its paleoceanographic applicability, Geochim. Cosmochim. Acta.57:335-346. 76. D.W. Lea and E.A. Boyle (1993) Reply to the comment by N.E. Pingitore Jr. on "Barium in planktonic foraminifera", Geochim. Cosmochim. Acta 57:471-473. 77. Lea, D.W., and E.A. Boyle (1993) Barium determination in foraminifera and corals by isotope dilution plasma mass spectrometry, Chem.Geol.103:73-84. 78. Colodner, D.C, E.A. Boyle, and J.M. Edmond (1993) Determination of rhenium and platinum in natural waters and sediments, and iridium in sediments by flow injection isotope dilution inductively coupled plasma mass spectrometry, Anal. Chem.65:1419-1425. 79. Colodner, D.C., G. Ravizza, J. Sachs, K. Turekian, J. Edmond, E. Boyle (1993) The geochemical cycle of rhenium: a reconnaissance, Earth. Planet. Sci. Lett. 117:205-221. 80. Orians, K.J. and E.A. Boyle (1993) The determination of picomolar concentrations of titanium, gallium, and indium in seawater by inductively coupled plasma mass spectrometry (ICPMS) following an 8-hydroxyquinoline chelating resin preconcentration, Anal. Chim. Acta. 282:63-74. 81. Imbrie, J., A. Berger, E.A. Boyle, S.C. Clemens, A. Duffy, W.R. Howard, G. Kukla, J. Kutzbach, D.G. Martinson, A. McIntyre, A.C. Mix, B. Molfino, J.J. Morley, L.C. Peterson, N.G. Pisias, W.L. Prell, M.E. Raymo, N.J. Shackleton, and J.R. Toggweiler (1993), On the structure and origin of major glaciation cycles 2. The 100,000-year cycle, Paleoceanogr. 8: 699-735. 82. Boyle, E.A. (1994) A comparison of carbon isotopes and cadmium in the modern and glacial maximum ocean: can we account for the discrepancies?, in Carbon Cycling in the Glacial Ocean: Constraints on the Ocean's Role in Global Change (eds. R. Zahn, T.F. Pedersen, M.A. Kaminski, and L. Labeyrie), NATO ASI Series, Vol. 17, Springer-Verlag, Berlin, p. 167-194. 83. Boyle, E.A., R. A. Sherrell, and M.P. Bacon (1994) Lead variability in the western North Atlantic and Central Greenland: implications for the search for decadal trends in anthropogenic emissions, Geochim. Cosmochim. Acta 58:3227-3238 84. Boyle, E.A. (1995) Limits on Benthic Foraminiferal Chemical Analyses as Precise Measures of Environmental Properties, J. Foram. Res.25:4-13. 85. Rosenthal, Y., E.A. Boyle, L. Labeyrie, and D. Oppo (1995) Glacial enrichments of authigenic Cd and U in sub-Antarctic sediments: a climatic control on the elements' oceanic budget?, Paleoceanogr. 10:395-413. 86. Boyle, E.A., L. Labeyrie, J.-C. Duplessy (1995), Calcitic foraminiferal data confirmed by cadmium in aragonitic Hoeglundina: application to the the last glacial maximum northern Indian Ocean, Paleoceanogr. 10:881-900. 87. Colodner, D., J. Edmond, and E. Boyle (1995) Rhenium in the Black Sea: comparison with molybdenum and uranium, Earth Planet. Sci. Lett. 131:1-15 88. Rosenthal, Y., P. Lam, E.A. Boyle and J. Thomson (1995) Authigenic cadmium enrichments in reducing sediments: precipitation and post-depositional mobility, Earth Planet. Sci. Lett. 132:99-111 89. Boyle, E.A. (1995) Last glacial maximum North Atlantic deep water: on, off, or somewhere in-between?, Phil. Trans. R. Soc. Lond. B 348:243-253. 90. Boyle, E. A. and Y. Rosenthal (1996) Chemical hydrography of the South Atlantic during the last glacial maximum: 13C vs. Cd, Berlin., Springer-Verlag, in: The South Atlantic: Present and Past Circulation, eds. G. Wefer, W. H. Berger, G. Siedler and D. Webb, Berlin., Springer-Verlag, 423-443. 91. Boyle, E.A. (1997) Cool tropical temperatures shift the global 18O-T relationship: an explanation for the Ice Core 18O / borehole thermometry conflict?, Geophys. Res. Lett. 24:273-276. 92. van Geen, A., J.F. Adkins, E.A. Boyle, C.H. Nelson, A. Palanques (1997) A 120 year record of metal contamination on an unprecedented scale from mining of the Iberian Pyrite Belt, Geology 25:291-294. 93. Dickey, T.D., D. Frye, H.W. Jannasch, E. Boyle, A.H. Knap (1997) Bermuda Sensor System Testbed, Sea Technology, April, p. 81-86. 94. Adkins, J.F. and E.A. Boyle (1997) Changing atmospheric 14C and the record of deep water paleo-ventilation ages, Paleoceanogr. 12:337-344. 95. Wu, J. and E.A. Boyle (1997) Low blank preconcentration technique for the determination of lead, copper and cadmium in small-volume seawater samples by isotope dilution ICPMS, Anal. Chem. 69:2464-2470. 96. Boyle, E.A. (1997) Characteristics of the deep ocean carbon system during the past 150, 000 years: CO2 distributions, deep water flow patterns, and abrupt climate change, Proc. Nat. Acad. Sci. 94:8300-8307. 97. Wu, J.F. and E.A. Boyle (1997) Lead in the western North Alantic Ocean: completed response to leaded gasoline phaseout, Geochim. Cosmochim. Acta 61:3279-3283. 98. Rosenthal, Y., E.A. Boyle, N. Slowey (1997) Temperature control on the incorporation of Mg, Sr, F and Cd into benthic foraminiferal shells from Little Bahama Bank: prospects for thermocline paleoceanography, Geochim. Cosmochim. Acta. 61:3633-3643. 99. Adkins, J.F., E.A. Boyle, L. Keigwin, and E. Cortijo (1997) Variability of the North Atlantic thermohaline circulation during the last interglacial period, Nature 390: 154-156. 100. Rosenthal, Y., E.A. Boyle, and L. Labeyrie (1997) Last glacial maximum paleochemistry and deep water circulation in the Southern Ocean: Evidence from foraminiferal cadmium, Paleoceanography 12:787-796. 101. Boyle, E.A. (1997) What controls dissolved iron concentrations in the world ocean? - a comment, Mar. Chem. 57:163-167. 102. Wu, J. and E.A. Boyle (1998) Determination of iron in seawater by high-resolution isotope dilution by high-resolution inductively coupled plasma mass spectrometry after Mg(OH)2 coprecipitation, Analytica Chimica Acta 367:183-191. 103. Adkins, J., H. Cheng, E.A. Boyle, E.R.M. Druffel and R.L. Edwards (1998) Deep-Sea Coral Evidence for Rapid Change in Ventilation of the Deep North Atlantic at 15.4 ka, Science 280:725-728. 104. Dickey, T., D. Frye, H., Jannash, E. Boyle, D. Manov, D. Sigurdson, J. McNeil, M. Stramska, A. Michaels, N. Nelson, D. Siegel, G. Chang, J. Wu, A. Knap (1998) Preliminary results from the Bermuda Testbed Mooring Program, Deep-Sea Res. I 45:771-794. 105. Keigwin, L.D. and E.A. Boyle (1999) Surface and deep ocean variability in the Northern Sargasso Sea during marine isotope stage 3, Paleoceanography 14:164-170. 106. Adkins, J.F. and E.A. Boyle (1999), Age screening of deep-sea corals and the record of deep North Atlantic circulation change at 15.4 ka, in: Reconstructing Ocean History: A Window into the Future, eds. F. Abrantes and A. Mix, Kluwer/Plenum, New York, pp. 103120. 107. Cheng, H., J. Adkins, R.L. Edwards, and E.A. Boyle (2000) U-Th dating of deep-sea corals, Geochim. Cosmochim. Acta 64: 2401-2416. 108. Boyle E. A. (2000) Is Ocean Thermohaline Circulation Linked to Abrupt Stadial/Interstadial Transitions? Quat. Sci. Rev. 19: 255-272. 109. Sherrell, R. M., Boyle E. A., Falkner K. K., and N.R. Harris (2000) Temporal variability of Cd, Pb, and Pb isotope deposition in central Greenland snow. Geochem. Geophys. Geosyst., vol. 1, Paper number 1999GC000007 [13,582 words, 6 figures, 2 tables]. May 30, 2000. 110. Vink S., Boyle E. A., Measures C. I., and Yuan J. (2000) Automated High Resolution Determination of the Trace Elements Iron and Aluminium in the Surface Ocean using a Towed Fish Coupled to Flow Injection Analysis. Deep-Sea Res. I 47:1141-1156 111. Wu, J., W. Sunda, E. Boyle, and D. Karl (2000) Phosphate depletion in the Western North Atlantic Ocean , Science 289:759-762. 112. Sigman, D. and E. Boyle (2000) Glacial/Interglacial variations in atmospheric carbon dioxide, Nature 407:859-869. 113. Keigwin, L.D. and E.A. Boyle (2000) Detecting Holocene changes in thermohaline circulation, Proc. Nat. Acad. Sci. 97:1343-1346. 114. Weiss, D., E.A. Boyle, V. Chavagnac, M. Herwegh, and J. Wu (2000) Determination of lead isotope ratios in seawater by quadrapole inductively coupled plasma mass spectrometry after Mg(OH)2 coprecipitation, Spectrochim. Acta B 55: 363-364. 115. Falkowski, P., R. J. Scholes, E. Boyle, J. Canadell, D. Canfield, J. Elser, N. Gruber, K. Hibbard, P. Högberg, S. Linder, F. T. Mackenzie, B. Moore III, T. Pedersen, Y. Rosenthal, S. Seitzinger, V. Smetacek, W. Steffen (2000) The Global Carbon Cycle: A Test of Our Knowledge of Earth as a System, Science 290:291-296. 116. Wu, J., E. Boyle, L.-S. Wen, and W. Sunda (2001) Occurrence of soluble and colloidal iron in oligotrophic oceans, Science 293:847-849. 117. D. Weiss, W. Shotyk, E.A. Boyle, J. Kramers, P.G. Appleby, and A.K. Cheburkin (2002) Comparative study of the temporal evolution of atmospheric lead deposition in Scotland and eastern Canada using blanket peat bogs, The Science of the Total Environment, 292:7-18. 118. S.J. Lehman, J.P. Sachs, A.M. Crotwell, L.D. Keigwin, E.A. Boyle (2002) Relation of subtropical Atlantic temperature, high latitude ice rafting, deep water formation, and European climate 135,000 – 60,000 years ago, Quat. Sci. Rev. 21:1917-1924. 119. Bell, J., J. Betts, and E. Boyle (2002) MITESS: A Moored In-situ Trace Element Serial Sampler for Deep-Sea Moorings, Deep-Sea Research I: 49:2103-2118. 120. Wu, J. and E. Boyle (2002) Iron in the Sargasso Sea: implications for the processes controlling dissolved Fe distribution in the ocean, Glob. Biogeochem. Cycles. 16:1086 (10.1029/2001GB 001453). 121. Adkins, J.F., Kashgarian, M., Cheng, H., Druffel, E.R.M., Boyle, E.A., Griffin, S., Edwards, L. and Shen, R. (2002) Radiocarbon dating of deep-sea corals, Radiocarbon 44:567-580. 122. Weiss, D., Edward A. Boyle, Jingfeng Wu, Valérie Chavagnac, Anna Michel, Matthew Reuer (2003) Spatial and Temporal Evolution of Lead Isotope Ratios in the North Atlantic Ocean Between 1981 and 1989, J. Geophys. Res. 108 (C10) 3306, doi: 10.1029/2000JC000762. 123. M.K. Reuer, Edward A. Boyle , and Barry C. Grant (2003) Lead isotope analysis of marine carbonates and seawater by multiple collector ICP-MS, Chem. Geol. 200:137-153. 124. Reuer, M.K., Edward A. Boyle, and Julia E. Cole (2003) A Mid-Century Reduction in Tropical Upwelling Inferred from Coralline Trace Element Proxies, Earth Planet. Sci. Lett. 210:437-452. 125. Adkins, J.F., E. A. Boyle, W. B. Curry and A. Lutringer, Stable isotopes in deep-sea corals and a new mechanism for "vital effects", Geochimica et Cosmochimica Acta (2003) 67:11291143 126. Parekh, P., M. Follows, and E. Boyle (2004) Modeling the global iron cycle, Glob. Biogeochem. Cyc. 18, GB1002, doi:10.1029/2003GB002061. 127. T. Ito, M.J. Follows, E.A. Boyle (2004) Is AOU a good measure of respiration in the oceans? Geophys. Res. Lett. 31, L17305, doi:10.1029/2004GL020900 128. Boyle, Edward A., Bridget A. Bergquist, Richard A. Kayser, Natalie Mahowald (2005) Iron, Manganese, and Lead at Hawaii Ocean Time-series Station ALOHA: Temporal Variability and an Intermediate Water Hydrothermal Plume, Geochim. Cosmochim. Acta: 69:933-952 129. Ana Lúcia Lima, Bridget A. Bergquist, Edward A. Boyle, Matthew K. Reuer, F.O. Dudas, Christopher M. Reddy and Timothy I. Eglinton, (2005) High resolution Pb isotope record reveals a stratigraphic marker for the Northeast USA, Geochim. Cosmochim. Acta 69:18131824. 130. P. Parekh, M.J. Follows, and E. Boyle (2005) Decoupling of iron and phosphate in the global ocean, Glob. Biogeochem. Cyc. 19:GB2020, doi:10.1029/2004GB002280. 131. L. D. Keigwin, J. Sachs, Y. Rosenthal, E. A. Boyle (2005) The 8200 year B.P. event in the slope water system, western subpolar North Atlantic, Paleoceanography 20:PA2003, doi:10.1029/2004PA001074. 132. B.A. Bergquist and E.A. Boyle (2006) Dissolved iron in the tropical and subtropical Atlantic Ocean, Glob. Biogeochem. Cycles 20, GB1015, doi:10.1029/2005GB002505. 133. B.A. Bergquist and E.A. Boyle (2006) Iron Isotopes in the Amazon River System: Weathering and Transport Signatures, Earth Planet. Sci. Lett 248:54-68. 134. P.W. Boyd, T. Jickells, C. Law, S. Blain, E.A. Boyle, K.O. Buesseler, K. Coale, J.J. Cullen, H. de Baar, M. Follows, M. Harvey, C. Lancelot, M. Levasseur, R. Pollard, R. Rivkin, J. Sarmiento, V. Schoemann, V. Smetacek, S. Takeda, A. Tsuda, S. Turner, A. Watson (2007) A synthesis of mesoscale iron-enrichment experiments 1993-2005: key findings and implications for ocean biogeochemistry, Science 315:612-617 135. B.A. Bergquist, J. Wu, E.A. Boyle (2007) Variability in oceanic dissolved iron is dominated by the colloidal fraction, Geochim. Cosmochim. Acta 71:2960-2974 136. Johnson, K.S., E. Boyle, K. Bruland, K. Coale, C. Measures, J. Moffett, A. Aguilar-Islas, K. Barbeau, B. Bergquist, A. Bowie, K. Buck, Y. Cai, Z. Chase, J. Cullent, T. Doi, V. Elrod, S. Fitzwater, M. Gordon, A. King, P. Laan, L. Laglera-Baquer, W. Landing, M. Lohan, J. Mendez, A. Milne, H. Obata, L. Ossiander, J. Plant, G. Sarthou, P. Sedwick, G.J. Smith, B. Sohst, S. Tanner, S. Van Den Berg, and J. Wu (2007) Developing Standards for Dissolved Iron in Seawater, EOS Trans. Am. Geophys. Union 88:131-132 137. GEOTRACES SCOR working group, incl. E. Boyle (2007) GEOTRACES – An international study of the global marine biogeochemical cycles of trace elements and their isotopes, Chemie der Erde 67 (2007) 85–131 138. Rashid, H. and Edward A. Boyle (2007) Mixed-Layer Deepening During Heinrich Events: A Multi-Planktonic Foraminiferal δ18O Approach, Science 318:439-441 139. John, S., J. G. Park, Z. Zhang, E.A. Boyle (2007) The isotopic composition of some common forms of anthropogenic zinc, Chem. Geol. 245:61-69 140. S.G. John, R.W. Geis, M.A. Saito, and E.A. Boyle (2007) Zinc isotope fractionation during high-affinity and low-affinity Zn transport in T. oceanica, Limnol. Oceanogr. 52:2710-2714 141. Keigwin, L. D., and E. A. Boyle (2008), Did North Atlantic overturning halt 17,000 years ago? Paleoceanography 23, PA1101, doi:10.1029/2007PA001500 142. Weyer S., Anbar A. D., Gerdes A., Gordon G. W., Algeo T. J., and Boyle E. A. (2008) Natural fractionation of 238U/235U. Geochim. Cosmochim. Acta 72, 345-359 143. S.G. John, O.J. Rouxel, P.R. Craddock, Alison M. Engwall, and E.A. Boyle (2008), Zinc stable isotopes in seafloor hydrothermal vent fluids and chimneys, Earth Planet. Sci. Lett. 269:17-28 144. A. Kavner, S.G. John, S. Sass, E.A. Boyle (2008) Redox-driven stable isotope fractionation in transition metals: Application to Zn electroplating, Geochim. Cosmochim. Acta 72:1731–1741 145. A.E. Kelly, M.K. Reuer, N.F. Goodkin, & E.A. Boyle (2009), Lead Concentrations and Isotopes in Corals and Water near Bermuda, 1780-2000, Earth Planet. Sci. Lett. 283:93-100 146. Jingfeng Wu, Robert Rember, Meibin Jin, Edward A. Boyle and Russ A. Flegal (2010) Isotopic evidence for the source of lead in the North Pacific abyssal water, Geochim. Cosmochim. Acta 75:460-468 147. Seth G. John, Carolina B. Mendez, Li Deng, Bonnie Poulos, Anne Kathryn M. Kauffman, Suzanne Kern, Jennifer Brum, Martin F. Polz, Edward A. Boyle and Matthew B. Sullivan** J. Fuhrman (2010) A simple and efficient method for concentration of ocean viruses by chemical flocculation, Environ. Microbiol. Rep. 3:195-202. 148. Jong-Mi Lee, Edward A. Boyle, Yolanda Echegoyen-Sanz, Jessica N. Fitzsimmons, Ruifeng Zhang, Richard A. Kayser (2011) Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch Nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry, Anal. Chim. Acta 686:93-101. 149. P.H. Moisander, R. Zhang, E.A. Boyle, I. Hewson, J.P. Montoya and J.P. Zehr (2012) Analogous nutrient limitations in unicellular diazotrophs and Prochlorococcus in the South Pacific Ocean, Int. Soc. Microb. Ecol. J. 6:733–744; doi:10.1038/ismej.2011.152 150. Edward A. Boyle, Seth John, Wafa Abouchami, Jess F. Adkins, Yolanda Echegoyen-Sanz, Michael Ellwood, Russ Flegal, Kyrstin Fornace, Celine Gallon, Steve Galer, Melanie GaultRingold, Francois Lacan, Amandine Radic, Mark Rehkamper, Olivier Rouxel, Yoshiki Sohrin, Claudine Stirling, Claire Thompson, Derek Vance, Zichen Xue, Ye Zhao (2012) GEOTRACES IC1 (BATS) Contamination-Prone Trace Element Isotopes Cd, Fe, Pb, Zn, (and Mo) Intercalibration, Limnol. Oceanogr. Methods 10:653-665 151. Jessica N. Fitzsimmons & Edward A. Boyle (2012) An intercalibration between the GEOTRACES GO-Flo and the MITESS/Vanes sampling systems for dissolved iron concentration analyses (and a closer look at adsorption effects), Limnol. Oceanogr. Methods 10:437-450 152. Rene M. Boiteau, Jessica N. Fitzsimmons, Daniel J. Repeta, Edward A. Boyle (2013) Characterization of Organic Iron Ligands in Marine Cyanobacteria Cultures and Seawater by HPLC-ICP-MS, Anal. Chem. 85:4357-4362 153. Fitzsimmons, J.N., R. Zhang, and E.A. Boyle (2013) Dissolved Iron in the tropical North Atlantic, Mar. Chem. 154:87-99 154. Jessica N. Fitzsimmons and Edward A. Boyle (submitted) Assessment and comparison of Anopore and cross flow filtration methods for the determination of dissolved iron size fractionation into soluble/colloidal phases in seawater, Limnology and Oceanography Methods 155. Jessica N. Fitzsimmons and Edward A. Boyle (submitted) Both soluble and colloidal iron phases control dissolved iron variability in the tropical North Atlantic Ocean, Geochimica Cosmochimica Acta.