MATERIAL SAFETY DATA SHEET Metalaxyl 25% WP 1. IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY PRODUCT NAME: Metalaxyl 25% WP SYNONYMS: None CHEMICAL NAME: Methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)-DL-aalaninate CHEMICAL FORMULA: C15H21NO4 MOLECULAR WEIGHT: 279.34 MANUFACTURER & ADDRESS: China 2. COMPOSITION/INFORMATION ON INGREDIENT TYPE OF PRODUCT AND USE: Fungicide COMPOSITION: Metalaxyl – 25.0%, Inerts – 75.0% CAS RN: [57837-19-1] 3. HAZARD IDENTIFICATION Risk advice to man and the environment Dangers for the environment: toxic to fish and bees 4. FIRST AID MEASURES Skin: wash thoroughly with soap and water. Eyes: flush with plenty of water for at least 15 minutes. See medical attention if irritation develops or persists. Inhalation: move to fresh air. Ingestion: if oral contamination, drink 1-2 glasses of water and milk. Call physician/poison control center immediately. 5. FIRE FIGHTING MEASURES Extinguishing media: To be used: dry chemical, foam, carbon dioxide. Measures of personal protection: safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants. Environmental cautions EX: prevent the contamination of the floor and of beds of water. 6. ACCIDENTAL RELEASE MEASURES Personal cautions: safety glasses or goggles, rubber gloves, shoes plus socks, long-sleeved shirt, and long pants. Cleaning methods EX: pick up for sweeping or asplation avoiding the powder formation. Transfer to a properly labeled deposit that will be closed and sealed until the recovery of climination of the product. 7. HANDLING AND STORAGE Handling: do not apply to humans, their clothing, or beding. Do not contaminate food or use on household tanks. Storage: Technical protective measures: store in original container only in cool, dry, wellventilated, secure area at minimum storage temperatures and out of reach of children and animals. Fire and explosion protection: the area must be far from fire and flammable materials Enviromental cautions EX: prevent the contamination of the floor and of beds of water. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection: approved respirator Protective gloves: rubber gloves Eye protection: goggles Industrial hygiene: appropriate protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance:White powder pH:5.0-8.0 Suspensibility: ≥90.0 Melting point: 63.5-72.3℃ Boiling point: 295.9℃ 10. STABILITY AND REACTIVITY Conditions to avoid: fire, feed, food and beds of water Products to avoid: strong oxidizing agents, alkalis and acids. Thermal decomposition: not applicable Hazardous decomposition products: oxides of carbon and nitrogen and other toxic nitrogen compounds on combustion. 11. TOXICOLOGICAL INFORMATION Acute Oral Toxicity LD50 (female rat) 1750 mg/kg Acute Dermal Toxicity LD50 (rabbit) >5000 mg/kg Acute Inhalation Toxicity LC50 (rabbit, 4-hr) : >2.02 mg/l(low toxicity) Eye Irritation (Rabbit): Mildly irritating Skin Irritation (Rabbit): Non-irritating Sensitization: Not a dermal sensitizer (guinea pig) Carcinogenicity: Metalaxyl was found not to be carcinogenic in studies with rats and mice. Reproductive toxicity: Metalaxyl is not developmentally toxic, and does not affect reproductive performance in rats. Teratogenicity: Metalaxyl was not teratogenic in a study with rats. 12. ECOLOGICAL INFORMATION Ecological Information 96-hour LC50 Bluegill: 139mg/L 96-hour LC50 Rainbow Trout: 132mg/L 48-hour EC50 Daphnia: 29mg/L 13. DISPOSAL CONSIDERATIONS Wastes resulting from the use of this product that cannot be used or chemically reprocessed should be disposed of in a landfill approved for pesticide disposal or in accordance with applicable Federal, states, or local procedures. Dispose of empty container in a sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways. 14. TRANSPORT INFORMATION UN-Number: 2588 Label class: 9 Packing group: III 15. REGULATORY INFORMATION No Data 16. OTHER INFORMATION STATEMENT NOTICE The information and recommendations contained herein is believed to be reliable and are presented in good faith by the supplier. The information is supplied upon the condition that users and handlers of the product will make their own determination as to its suitability for their purpose prior to use. In no event will the supplier be responsible for damages of any nature concerning the handling and use of this product. Handlers and users of the product assume all risks and liabilities arising from its handling, use or application.