August , 2001 BRITT ANN HOLMÉN Department of Civil & Environmental Engineering University of Connecticut Storrs, CT 06269-2037 (860) 486-3941 (860) 486-2298 (FAX) baholmen@engr.uconn.edu EDUCATION Massachusetts Institute of Technology, Cambridge, MA Ph.D., Department of Civil and Environmental Engineering. February, 1995. Thesis title: Polycyclic aromatic hydrocarbon sorption kinetics in three iron oxide-coated aquifer sands. Sorbent texture and PAH transport relationships used to develop a low foc sand particle-scale sorption kinetics model. Thesis Advisor: Philip M. Gschwend. University of Washington, Seattle, WA M.S., Geological Oceanography, 1985. Thesis: Chlorite compositional constraints on hydrothermal fluids. Geochemical analysis and thermodynamic modeling of Fe and Mg distribution in chlorites from hydrothermal basalts and gabbros. Thesis Advisor: John R. Delaney. Colby College, Waterville, ME B.A., Environmental Science/Geology, 1982. PROFESSIONAL EXPERIENCE Aug. 2001 – Present University of Connecticut, Storrs, CT. Civil & Environmental Engineering Assistant Professor. Jul. 1998 – Present University of California, Davis, CA. Civil & Environmental Engineering Assistant Adjunct Professor. Apr. 1997 – Jul. 2001 University of California, Davis, CA. Crocker Nuclear Laboratory Assistant Research Geochemist. Sept. 1994Apr. 1997 University of California, Davis, CA. Land, Air and Water Resources Postdoctoral Associate. Reaction of organic compounds with mineral surfaces under various environmental conditions. Post-doc Mentor: William H. Casey. Jan. 1988Jul. 1989 Cambridge Analytical Associates, Boston, MA Environmental Geochemist. Project management, fieldwork at contaminated groundwater sites, interpretation of chemical and hydrologic data, writing final reports. Dec. 1985Mar. 1988 Smithsonian Astrophysical Observatory, Cambridge, MA Geologist / Electron Microprobe Lab Manager. Geochemical research on meteorites. Jun. 1985Dec. 1985 Harvard University Geology Department, Cambridge, MA Research Technician in isotope geochemistry laboratory. Radioisotopic dating of Archean rocks using solid-source mass spectrometer. BRITT HOLMÉN PAGE 2 PROFESSIONAL AFFILIATIONS American Chemical Society American Geophysical Union HONORS 2000 1999 1994 1982 1981, 1982 Association for Women in Science Air & Waste Management Association UC Davis Academic Federation Excellence in Research Award Nominee, Finalist Advisee (Kristine Kuhna) received AGU Outstanding Student Paper Award, Fall Annual Meeting, San Francisco, CA. American Chemical Society Graduate Student Research Paper Award Graduate cum laude, Colby College Geology Student Prizes, Colby College RESEARCH INTERESTS Environmental Particle Interface Chemistry: sorption of inorganic and organic anthropogenic chemicals; redox reactions; mineral dissolution; air-particle partitioning; particles as contaminant transport agents. Nonpoint Source Contaminant Transport: heavy metals and PAHs in stormwater; atmospheric PM. Real-world Contaminant Exposure: vehicle-derived nanoparticles, crystalline silica. EXTRAMURAL FUNDING A. CURRENT FUNDING. TOTAL AS PRINCIPAL INVESTIGATOR > $ 1,000,000 US Department of Agriculture, Generation, Transport and Transformation of Pesticide Residues on Airborne Fine Particulate Matter Derived from Managed Soils [PI, with UC Davis Co-PI’s Cort Anastasio (Atmospheric Science) and Thomas Young (CEE)]. (7/1/99-6/30/03); $286,500 National Science Foundation, POWRE: Lidar Remote Sensing of Particulate Matter: Making the Qualitative to Quantitative Transition [PI] (7/1/99-12/31/01); $74,869 California Air Resources Board, The Physical and Chemical Characterization of Ultrafine and Nanoparticle Particulate Matter Emissions from Gasoline and Diesel On-Road Motor Vehicles [PI with UC Davis Co-PI’s Lowell Ashbaugh (CNL), Debbie Niemeier (CEE) and Thomas Young (CEE)]. (10/1/99 - 4/30/01); $501,847 California Department of Transportation, Gasoline Vehicle Particulate Matter Emissions Composition during Driving Cycles [PI with UC Davis Co-PI’s Peter Kelly (Chemistry) and Norman Kado (Environmental Toxicology)]. (9/1/90-8/30/01); $100,000 California Air Resources Board, >C10 Oxygenated Organics in Size-segregated Particles for Source Apportionment of Diesel-Emissions [Judi Charles (PI, UC Davis Environmental Toxicology) with Co-PI’s Britt Holmén and Lowell Ashbaugh (UC Davis)]. (12/1/00 - 12/30/02); $190,000 BRITT HOLMÉN PAGE 3 California Air Resources Board, Amendment to 98-335: Dynamometer measurements of particle size distributions for ARB’s CNG versus Diesel bus emissions study [PI] (2/1/01-8/31/01); $41,167 B. PENDING PROPOSALS. National Science Foundation, CAREER: Vehicle-derived Ultrafine Particles and Their Adsorbates: Formation and Aging Effects on Organic Composition and Size Distribution [PI]. (2/1/02 - 1/31/07); $375,003 C. RETIRED FUNDING (INCLUDES CONTINUING GRANTS AT PREVIOUS INSTITUTION). California Department of Transportation, North Coast River Loading Study -- Water Quality Analysis Subproject: Contaminants [Subproject Co-PI’s Britt Holmén, Alan Jackman (Chemical Engineering), Jeff Mount (Geology) and Eric Larsen (Geology)]. (8/1/98-7/30/02); $ 366,175 transferred to colleague at UC Davis. California Air Resources Board, Near-Source Exposure to Crystalline Silica and Fine Mineral Fibers in California [PI with Co-PI Randy Southard (Soil Science)]. (10/1/99 - 12/31/02); $249,970 contract terminated 8/12/01. National Science Foundation, Research Experiences for Undergraduates, LURE: Linking Undergraduates to Research on the Environment [Jeannie Darby (PI, CEE) with Co-PI’s Britt Holmén and Debbie Niemeier]. (7/1/97 – 6/30/02); $325,000 continuing at UC Davis. National Science Foundation, PG: Planning the Central Valley Community Science Project for Gender Equity in Culture, Climate and Curriculum [PI with Co-PI’s Kim Longworth (Director, OES), Karen McDonald (Chemical Engineering) and Jessica Utts (Statistics)]. (7/1/99 - 6/30/00); $30,000 completed 6/30/01 with one-year no-cost extension. California Air Resources Board, Analysis of Crystalline Silica in Air Samples from Lompoc, California [PI]. (12/1/00 - 6/30/01); $7,000 completed 6/30/01. BRITT HOLMÉN PAGE 4 DISSEMINATION OF RESEARCH A. PEER-REVIEWED PUBLICATIONS. 1996 Holmén, B.A. and W. H. Casey. Hydroxamate ligands, surface chemistry, and the mechanism of ligand-promoted dissolution of goethite [-FeOOH(s)] Geochim. Cosmochim. Acta, 60, 4403-4416. 1997 Holmén, B.A. and P.M. Gschwend. Estimating sorption rates of hydrophobic organic compounds in iron oxide- and aluminosilicate clay-coated aquifer sands Environ. Sci. Technol., 31, 105-113. 1997 Holmén, B. A., M. Isabel Tejedor-Tejedor, W. H. Casey. Hydroxamate complexes in solution and at the goethite-water interface: A cylindrical internal reflection Fourier transform infrared spectroscopy study Langmuir, 13, 2197-2206. 1998 Holmén, B.A., D. A. Niemeier. Characterizing the effects of driver variability on real-world vehicle emissions Transportation Research, Part D., Transport and Environment, 3, 117-128. 1998 Holmén, B.A., W. Eichinger, R.G. Flocchini. Application of elastic lidar to PM10 emissions from agricultural non-point sources Environ. Sci. Technol., 32, 3068-3076. 1999 Holmén, B.A., J. D. Sison, W. H. Casey, D. Nelson. Hydroxamate siderophores, cell growth and Fe(III) cycling in two anaerobic iron oxide media containing Geobacter metallireducens. Geochimica et Cosmochimica Acta, 63, 227-239. 2001 Holmén, B.A., Y. Meng, D. A. Niemeier. Time series analysis of above-road particulate matter at the Caldecott Tunnel exit. J. Air & Waste Management Assoc., 51, 601-615. 2001 Johns, C., B.A. Holmén, R.H. Shumway, D.A. Niemeier. Nonlinear regression for modeling censored one-dimensional concentration profiles of fugitive dust plumes. (accepted for publication., J. Agricultural, Biological, and Environmental Statistics). 2001 Holmén, B.A., T. A. James, L. L. Ashbaugh, R.G. Flocchini. Lidar-assisted measurement of PM10 emissions from agricultural tilling in California’s San Joaquin Valley I: Lidar (submitted, Atmospheric Environment). 2001 Holmén, B.A., T. A. James, L. L. Ashbaugh, R.G. Flocchini. Lidar-assisted measurement of PM10 emissions from agricultural tilling in California’s San Joaquin Valley II: Emission Factors (submitted, Atmospheric Environment). 2001 Niemeier, D. A., B.A. Holmén. Driver variability and emissions: Do demographics count? (in prep., Transportation Research, Part D., Transportation and the Environment). BRITT HOLMÉN PAGE 5 2001 Niemeier, D.A., B.A. Holmén Y. Meng, J.M. Utts. Daily heavy-duty truck traffic: Implications for the ozone "weekend effect" in southern California. (in prep., J. Air & Waste Management Assoc.) B. CONFERENCE PROCEEDINGS (* = PEER-REVIEWED) 1985 Holmén, B.A. and J.R. Delaney. Fluid compositional constraints on recharge and upflow portions of a BOI, NFLD, hydrothermal system, EOS, Transactions, American Geophysical Union, 66, 402. 1986 Holmén, B.A. and J.A. Wood. Chondrules that indent one another: Evidence for hot accretion? 49th Meteoritical Society Meeting, New York, New York. 1987 Holmén, B.A. and J.A. Wood. Refractory inclusions in the Kaba CV3 chondrite. 50th Meteoritical Society Meeting, Newcastle-Upon-Tyne, England. 1990 Taylor, B., D. Mauro, M.B. Hayes, B. Holmén, M. Young. Composition and migration of coal tar-derived organic compounds in a sandy aquifer. Proceedings: Environmental Research Conference on Groundwater Quality and Waste Disposal; May 2-4, 1989, Washington, D.C. Electric Power Research Institute, EN-671992 Gordon Conference Participant, Environmental Sciences: Water. New Hampton School, NH. 1994 Holmén, B.A. and P.M. Gschwend. Evaluation of sorption kinetics in an Atlantic Coastal Plain aquifer sand. 207th American Chemical Society National Meeting, San Diego, CA, March 1318, 1994. 1994* Gschwend, P.M., B.A. Holmén, A.A. MacKay, J.N. Ryan, D.A. Backhus, Y.-P. Chin. Overview: Processes limiting the occurrence of organic contaminants in moving groundwater. In Transport and Reactive Processes in Aquifers, Dracos, Th. & F. Stauffer (Eds) Proceedings of the IAHR Symposium, April 11-15, 1994, Zurich, Switzerland. 1994 Holmén, B.A. and P.M. Gschwend. Sorption kinetics in an Atlantic Coastal Plain aquifer sand. 208th American Chemical Society National Meeting, Washington, DC, August 21-26. 1996 Gschwend, P., O. Gustafsson, B. Holmén. “Two possible explanations for slow sorption kinetics: (a) the presence of soot in surface soils and sediments, and (b) the physical encapsulation of natural organic matter in geologically formed solids”. Workshop on Chemical Processes that May Bind or Sequester Organic Contaminants in Soils and Sediments, Carnegie Mellon University, Pittsburgh, PA., May 2-3, 1996. 1996 Holmén, B.A., J.D. Sison, D. Nelson, W.H. Casey. Sciences: Water. New Hampton School, NH. 1997 J.D. Sison, B.A. Holmén, D. Nelson, W.H. Casey. Hydroxamate Siderophores: Iron Sources or Sinks? 213th American Chemical Society National Meeting, San Francisco, CA, April 13-17. Gordon Conference, Environmental BRITT HOLMÉN PAGE 6 1997 Holmén, B.A., P.M. Gschwend. Aquifer sorbent textures and PAH sorption kinetics. American Geophysical Union, San Francisco, CA. December 8-12. 1998* Casey, W.H., C. Ludwig, B. Holmén. Toward understanding the rates of reactions at mineral surfaces. Marini, L and G. Ottonello (Eds.) Proceedings of the Rome Seminar on Environmental Geochemistry, Castelnuovo di Porto, May 22-26, 1996. Pacini Editore, Pisa. 1999 Eichinger, W., B. Holmén, L. Chen. Wide Area Measurement of Wind Velocities by Lidar. International Water Resources Engineering Conference Seattle, WA. August 8-12. 1999 Kuhna, K. M., B. A. Holmén. Bridge Runoff from a Rural California Highway as a Source of Metal Contamination in Small Streams. American Geophysical Union Fall Meeting, December 13-17, 1999. San Francisco, CA. 1999 Holmén, B.A., W.E. Eichinger, R.G. Flocchini. Spatially distributed wind field measurement by lidar cross correlation technique. American Geophysical Union Fall Meeting, December 1317, 1999. San Francisco, CA. 2000 Clymo, A., B.A. Holmén. Herbicide sorption to particulate matter derived from managed soils. UC Toxic Substances Research and Teaching Program annual symposium, April 28-29, San Diego, CA. 2000* Holmén, B.A., T. A. James, L. L. Ashbaugh, R.G. Flocchini. Tractor-generated Fugitive Dust Plumes: Improving PM Emission Flux Calculations with Lidar. American Society of Agricultural Engineers Air Pollution 2000 conference, October, Des Moines, IA. 2000 Clymo, A., B.A. Holmén, J.M. Higa, T. Young, C.Anastasio. Generation and transport of herbicide residues on airborne fine particulate matter derived from managed soils. Society of Toxicology and Environmental Chemistry, November, Nashville, TN. 2001 Anastasio, C., J.M. Higa, A.S. Clymo, B.A. Holmén, T.M.Young. Generation and atmospheric fate of pesticides on airborne soil dust. 221st American Chemical Society, San Diego, CA. April 1-4. 2001 Clymo, A., B.A. Holmén. Herbicide sorption to particulate matter derived from managed soils. UC Toxic Substances Research and Teaching Program annual symposium, April 20-21, Lake Tahoe, CA. 2001 Nanzetta, M.K., B.A. Holmén. Roadside particle number and size distributions of vehicular ultrafine and nanoparticle particulate matter emissions. 94th Annual Conference Air & Waste Management Association, Orlando, FL, June 24-28. 2001 Hefner, B.T., K. Trzepla-Nabaglo, B.A. Holmén, R.G. Flocchini. Toward mass calibration of lidar backscatter signals: Preliminary results from “dual string” field technique. American Association of Aerosol Research 20th Annual Conference, October 15-19, Portland, OR BRITT HOLMÉN PAGE 7 C. INVITED SEMINARS “Contaminants in the Environment: Where they are, what they do, where they go...”. UC Davis Toxic Substances Research and Teaching Program, Fall Retreat, Sacramento, CA. December, 8, 1999. “Agricultural fugitive dust plumes: What can lidar tell us?” October 14, 1999. Air/Water Symposium, UC Davis, “Processes Affecting Solute Transport”. California Institute of Technology, Environmental Engineering Science Seminar Series. May 14, 1997. D. BOOKS Niemeier, D.A., B. A. Holmén, J. Lin (2001) Transportation and Air Quality: Theory and Practice (In preparation). TEACHING EXPERIENCE A. UNIVERSITY OF CALIFORNIA, DAVIS GRADUATE LEVEL GRADUATE COURSES ECI 247L Airborne Particles Laboratory. Fall 2000. New course to be team-taught with 4 other faculty from various departments across campus. Civil & Environ. Engineering. ECI 245B Applied Environmental Chemistry: Organic. Spring 2001. Civil & Environ. Engineering. GRADUATE PROGRAM MEMBERSHIPS Agricultural and Environmental Chemistry Atmospheric Science Civil & Environmental Engineering Hydrologic Science Transportation Technology and Policy MENTORING – POST-DOCTORAL SCHOLARS AND GRADUATE STUDENTS Ryoji Shiraki. (Post-doctoral scholar, 2000-). Crystalline silica from stationary sources. Juan Suro-Pérez (Post-doctoral scholar, 2000- ). North Coast watershed organic contaminants. Birsen Buyuktas. (Post-doctoral scholar, 1999-2000). North Coast watershed organic contaminants. Yu Meng (CEE, Ph.D. 1998) “A new statistical framework for estimating carbon monoxide impacts at intersections”, Member: Doctoral Committee. BRITT HOLMÉN PAGE 8 Craig Johns (Statistics, Ph.D. 1999) Research Assistant – Lidar data analysis. “Estimation of Nonlinear State-Space Models in the Presence of Censored Observations”. Kathy Nanzetta (CEE, Ph.D. candidate). Vehicle emissions modeling/ air pollution. Coadviser with D. Niemeier (CEE) and C. Anastasio (Atmospheric Science). Jie Lin (CEE, Ph.D. candidate). Driving cycle development. Member: Doctoral Committee. Ana-Lucia Cordova (Ag & Environ Chem., Ph.D. candidate). North Coast watershed organic contaminants, Major Professor. Courtney Palko (CEE, Plan II M.S. 2000). North Coast Project RA – Organic Contaminants. Kristine Kuhna (CEE, M.S. candidate) North Coast Project Research Assistant – Inorganic Contaminants, Major Professor. Amy Clymo (CEE, M.S. candidate). USDA herbicide-dust flux. Major Professor. Saskia van Bergen (Ag & Environ Chemistry, M.S. candidate). Organic chemical signature of on-road vehicles and EC/OC pyrolysis GC/MS method development. Major Professor. Patricia Buis (CEE, M.S. candidate). North Coast watershed trace metal contaminants – sediment/ surface water relationships. Major Professor. UNDERGRADUATE LEVEL UNDERGRADUATE COURSES ECI 90X. Undergraduate Research Methods Laboratory, Winter 1999.Civil & Environ. Engineering. “Vehicle Tailpipe Emissions – Regulations and Air Quality”. ECI 269 (Transportation- Air Quality: Theory and practice), Civil and Environmental Engineering (1998, 1999) “Air Quality and Particulate Matter”. ECH 1 (The Scope of Chemical Engineering). Chemical Engineering, 1999. “Lidar Applied to the Atmospheric Boundary Layer”. ATM 158 (Boundary-Layer Meteorology). Atmospheric Science, 1999. MENTORING – UNDERGRADUATE STUDENTS Undergraduate Research Supervisor for following students at University of California, Davis: Jennette Sison (June 2000 received MPH at Univ. of Michigan) -- Hydroxamate siderophores and Fe(III) cycling in an anaerobic goethite medium. Benjamin Ashbaugh (Computer Science Engineering, B.S. 2000, UCSD) -- Lidar Data Analysis Program correlation routine for wind analysis with lidar. Rashi Gupta (CEE B.S.; currently: graduate student, Univ. of Texas) – “PM2.5 emissions near roadways.” UCD Undergraduate Research Conference oral presentation. Elaine Moon (Environmental Resource Science; currently: graduate student, Oregon State University) – “Development of a tribal values index for wetlands.” UCD Undergraduate Research Conference oral presentation. Christopher Van Wert (ME; currently graduate student at Stanford) -- Construction of a PM sampler for real-time monitoring of diesel bus emissions. Charles Xie (CSE; currently senior, UCD) -- Lidar Data Analysis Program (LidarDAP) programming. Erik Merriman (CEE) “Is coal tar slurry an effective safeguard for lead soil contamination beneath model airport surfaces?” UCD Undergraduate Research Conference oral presentation. Cindy Vahey (CEE) “Effect of surface particles on lead levels in stormwater runoff caused by discarded aviation fuel.” UCD Undergraduate Research Conference oral presentation. BRITT HOLMÉN PAGE 9 Joyce Vivian (Environmental Resource Science) “Phytoremediation at small airports: How much lead will African alfalfa remove from Pb-contaminated soil?” UCD Undergraduate Research Conference oral presentation. Matthew Graham (Solano Community College) Lidar contributions to understanding aerosol homogeneity at the Grand Canyon. Larry O’Neill (Atmospheric Science; currently graduate student Oregon State University). “LIDAR estimates of aerosol optical properties in the lower atmosphere”. UCD Undergraduate Research Conference poster, April 28, 2000. Cassidy Houchins (Sacramento State University) Fine particles near roadways. UCD Undergraduate Research Conference oral presentation, April 28, 2000. B. OTHER Expanding Your Horizons Conference Workshop Leader, March 2000. 7th and 8th grade girls. Scientist Pen-Pal, 1995-1996. Participant in Boston Museum of Science “Science By Mail” program for 4-6th and 7-9th grade students. UROP Supervisor, one-on-one interaction with undergraduate student working on laboratory research project, Spring 1991 and Fall 1993. Massachusetts Institute of Technology Teaching Assistant, prepared and supervised twice-weekly laboratory course on environmental chemistry, Spring 1991. Massachusetts Institute of Technology Teaching Assistant, Introductory Oceanography, 3 quarters. Duties included teaching undergraduate classes of 25-30 students a weekly laboratory session. University of Washington Teaching Assistant, Geological Oceanography, 1 quarter. Organized and supervised an oceanographic cruise in Puget Sound. University of Washington Tutor, Introductory Geology, Fall 1981. Colby College TEACHING INTERESTS Colloid and Surface Chemistry (G) – physical chemistry of aquatic surfaces with emphasis on environmental applications. Environmental Organic Chemistry (G) – physicochemical modeling of processes affecting the transport and transformation of anthropogenic organic chemicals in the environment. Airborne Particles Laboratory (G) – hands-on laboratory course on sampling and analysis of airborne particulate matter. Transportation and Air Quality (G) – Vehicle emissions and airborne pollutants: regulatory framework, modeling at regional and micro-scales. Hydrogeochemistry (G) – chemistry of aqueous systems treated in a quantitative manner. Subsurface Water Quality (UG,G) – comprehensive overview of processes controlling groundwater composition; emphasis on quantitative analysis; remediation technologies. Water Quality Laboratory (UG) – hands-on wet chemistry and instrumentation laboratory that incorporates field trips and student-designed research projects. Current Environmental Topics (UG) – interdisciplinary survey course on current environmental problems with emphasis on design of engineering solutions. BRITT HOLMÉN PAGE 10 PROFESSIONAL SERVICE Peer-reviewed manuscripts for following journals: 1. Langmuir 2. Environmental Science & Technology 3. Geochimica et Cosmochimica Acta 4. Journal of the Air & Waste Management Association Peer-reviewed proposals: 1. National Science Foundation Association for Women in Science (AWIS). Sacramento Valley chapter, Board member and Secretary 1999 – 2000. Sacramento Valley chapter, Board member and Secretary 2000 – 2001. UNIVERSITY SERVICE UC Davis Academic Federation Academic Freedom, Rights, and Privileges Committee 1999 – 2000 UC Davis Academic Federation Academic Freedom, Rights, and Privileges Committee 2000 – 2001 Opportunities in Engineering and Science (OES) Steering Committee, 1997 – present. Conference Session Moderator at UCD graduate and undergraduate conferences: Agricultural and Environmental Chemistry Winter 2000 Symposium, Atmospheric Chemistry session. UCD Undergraduate Research Conference, April 24, 1999. UCD Undergraduate Research Conference, May 2, 1998.