Empty Containers several different web links http://pesticidestewardship.org/Pages/default.aspx This module provides general principles on the proper handling of empty pesticide containers. Carol Ramsay, Washington State University Extension Pesticide Specialist and members of The Pesticide Stewardship Alliance, compiled the information in this module using noted resources and contributions from national subject matter experts. Remember to follow all local, state, and federal regulations regarding pesticide emptying and handling empty containers. Review the product label for any specific directions. A brief description of, and links to, the various topics within this module follows: 1. An Introduction states the importance of immediate and proper handling of empty containers. 2. Building and Location provides resources and guidelines for the establishment of a storage facility. 3. Paper and Plastic Bags rarely are rinsed, but still require careful handling prior to disposal. 4. Nonrefillable containers are usually made of plastic, require immediate rinsing and then can be recycled or taken to a landfill. 5. Refillable containers and shuttles must be emptied as best possible. Cleaning, refilling, and disposal are the responsibility of the dealer or registrant, not the applicator. 6. Two methods of Rinsing Instructions (triple- and pressure-rinsing) are reviewed with links to videos as well as standards of acceptance for recycling. 7. Both plastic recycling and landfills are discussed as Disposal Options, as well as links to the Disposal web pages. 8. Additional resources for handling empty pesticide containers are located in the Fact Sheets section. Introduction Take that little extra time to handle empty containers properly when preparing your spray batch or filling application equipment. Careful emptying and rinsing of containers reduces concerns for human exposures and possible impacts on wildlife and the environment. Save yourself from hazardous waste headaches and expense by properly handling of paper and plastic containers. Get all your money’s worth by using up that last granule or drop. Credit: Pesticide Properly rinsed plastic containers can be recycled in most states through an approved Pic - Virginia Tech pesticide container recycling program. Properly handled paper or plastic can be taken to local landfills and transfer stations. If paper or plastic containers are not properly emptied or rinsed, the container itself becomes a hazardous waste. Hazardous wastes are very expensive to farmers, foresters, public agencies and commercial pesticide application operations because federal law requires they be handled by certified hazardous waste professionals for their packaging, transport and acceptance at a hazardous waste landfill or incineration facility (DISPOSAL) Lastly, take precautions when handling containers. Wear appropriate protective gear when mixing, loading, and rinsing containers. Never reuse a pesticide container for any purpose. Product labels prohibit the reuse of containers and the label is the law. Credit: Northwest Ag Plastics Paper and Plastic Bags Granular and dust formulations often are packaged in plastic bags, waxed-paper or other water-resistant paper packaging. Completely empty the contents of paper-based containers as best possible into your application equipment. Shake and tap the sides and bottom to dislodge particles. If bags have seams, open side seams with a utility knife (not your pocket knife) to loosen particles trapped in the seams. If paper or plastic bags are not emptied sufficiently and hold pesticide product, the paper container might require handling by a hazardous waste contractor depending on the toxicity of the pesticide. Properly emptied bags can be taken to your local landfill or waste transfer station. Credit: Pesticide Pic - Virginia Tech Nonrefillable Containers (Plastic) Most nonrefillable containers are made of high density polyethylene (HDPE) plastic; some are constructed of metal. Recycling and landfills provide disposal options. All nonrefillable plastic containers must be rinsed prior to taking for recycling (instructions for acceptable containers http://www.usagrecycling.com/containers.asp and http://www.acrecycle.org/acceptable.html). Note that the type of plastic in the cap on the container is different from the type of plastic in the container. Rinse the cap and dispose of it with your normal refuse; take the uncapped, rinsed container for recycling. The rinsed container cannot be recycled through a household recycling service and must be processed by an approved pesticide container recycler, Ag Container Recycling Council (ACRC). Immediately rinse nonrefillable plastic containers when you fill the sprayer. Drain the container rinsewater directly in the spray tank. Rinsing (pressure or triple-rinse) immediately easily removes all product concentrate and renders the container sufficiently clean to Photo Credit: Northwest AgPlastic recycle or send for disposal. Do not allow any residue to become dried and difficult or impossible to rinse; if this occurs, the container is consider full and is classified an expensive hazardous waste. Federal regulations provide that properly rinsed plastic containers become a general waste product that can be recycled by an approved “pesticide container recycler” or disposed of at a landfill or waste transfer station. As of 2010, labels on nonrefillable plastic containers state the following use instructions: “Do not reuse or refill this container. Once cleaned, some agricultural plastic pesticide containers can be taken to a container collection site or picked up for recycling. Triple rinse container (or equivalent) promptly after emptying.” Instructions for triple rinsing are included on the label. Pressure rinsing is an accepted equivalent for triple rinsing. Refillable Container & Shuttles As of 2011, all refillable containers must have a tamper resistant device that applicators must break prior to removing product from the shuttle. Applicators and mixer/loaders need to empty their refillable container or shuttle as much as possible. Return refillable containers or shuttles to the dealer. The dealer is responsible to refill the container with pesticide only or process for disposal. Do not reuse this container for any other purpose. Cleaning before refilling is the responsibility of the refiller, not the applicator. Dealers have specific requirements for handling bulk pesticide repackaging to accommodate the return and refill of greater than 55 gallons liquid or 100 pounds dry material. If the same product is used for refilling, this activity can be done without cleaning the container. If the dealer wishes to place a pesticide in a container which is different than the pesticide the container previously held, the dealer must thoroughly clean the container according to the written instructions of the registrant of the product being placed in the container. Once refilled, a new tamper resistant device must be installed. Both the dealer and the registrant of the pesticide being sold or distributed are liable for any cross-contamination or other adulteration which may occur. Rinsing Instructions Why would you want to leave concentrate in a container? Leaving six ounces in a 2.5 gallon container is a loss of 2%. If the product cost you $250, that is five dollars right off the top. This is greatly compounded by the need to handle the unrinsed container as a hazardous waste (EPA, DOT, state environmental agency oversight, hoops, and expense). However there are state programs and companies who can assist you with hazardous wastes. It is strongly recommended to rinse containers immediately as you empty them to ensure you get the containers sufficiently clean. A delay in rinsing can result in dried, caked residues that may be very difficult if not impossible to rinse clean. Visit the ACRC web site to view a video on pressure or triple rinsing smaller containers or drums: http://www.acrecycle.org/video.html. Plastic recycling companies, solid waste facilities, and incineration facilities require pesticide containers be properly rinsed. Some companies or facilities may require you to sign a document to verify the containers were triple or pressure rinsed. In rare instances, triple-rinsed pesticide container are turned away from disposal facilities. ACRC has great resources for knowing how to properly handle your containers and illustrates what types of issues impact whether a container is accepted for recycling; visit their web site: http://www.acrecycle.org/acceptable.html. Pressure-Rinsing: Consider eye protection when pressure rinsing nonrefillable containers (plastic or metal). Attach a special nozzle to the end of a hose. The special nozzle has an on/off valve and when on the water released by the nozzle forces the pesticide residues from the container. Rinse directly into your spray batch. Some people think pressure-rinsing is faster and easier than triple-rinsing. (link to ACRC video) Directions: 1. When you empty a container, allow it to drain into the spray tank for 10 seconds after it begins to drip. 2. Remove guard from pressure-rinse nozzle which is connected to a water hose. 3. Place the container against a hard object and puncture the side or bottom of container carefully. Do not puncture against your leg. Either puncture the: 1. narrow side with the handle near the bottom of the container, or 2. bottom of the container near the handle side (not the opening side). 4. Hold the container upside down with the pour spout over the sprayer tank opening so rinsate drains directly into the sprayer tank. 5. Rinse for length of time recommended by the manufacturer (generally 30 seconds or more). Rotate the nozzle to rinse all inside surfaces. USAg Recycling 6. Take care to make sure hollow handles are well rinsed. 7. Rinse cap, leave it removed, and dispose of in normal refuse. Graphic Credit: USAg Recycling 8. Allow clean container to dry. Store for later recycling or disposal Triple-Rinsing does not require any special equipment and can be used with plastic, non-pressurized metal, and glass containers. Triple rinse when you empty the container. (link to ACRC video) Directions: 1. Empty the pesticide into the spray tank and allow it to drain for 10 seconds after it begins to drip. 2. Fill the container ¼ full of water and securely replace the cap. 3. Shake for 10 seconds to rinse all inside surfaces. 4. Pour rinsate into application equipment and allow container to drain for 10 seconds after it begins to drip. Graphic Credit: USAg Recycling 5. Repeat steps 2 through 5 two more times. 6. Rinse cap, leave it removed, and dispose of in normal refuse. 7. Allow clean container to dry. Store for later recycling or disposal Disposal Options Plastic recycling is an option for plastic pesticide containers made of high-density polyethylene (HDPE) can be recycled through an approved pesticide container recycler. Rinsed containers are not to be handled as general household plastics and put in the general plastic recycling stream. Contact the Ag Container Recycling Council (ACRC) or your state agency responsible for pesticide regulations for assistance (AAPCO) if you need pointed in the direction of your local pesticide container recycler. ACRC and the American Society of Agricultural and Biological Engineers have developed stringent guidelines for Credit: USAg Recycling handling recovered high-density polyethylene HDPE, from the moment when containers are rinsed right through the manufacturing process. You can also learn more about safety and public health issues here. ACRC needs to ensure how the plastic will be used and what the end product is for the plastic so no residues on or in the resin will have any real or perceived adverse affect on the environment or the user. Some of the end product generated from chipped containers include underground conduit, pallets, field drain tiles, speed bumps, and many more. All sizes of plastic containers are accepted from pints to drums; however, they must be triple or pressure rinsed. Landfilling. Rinsed containers generally are accepted by most local landfills or waste transfer stations. Some landfill facilities require people to sign a verification statement that states the pesticide containers were triple rinsed or equivalent. Facilities that accept household refuse generally are prohibited from accepting waste classified as hazardous by the federal Resource Conservation and Recovery Act. Since pesticide containers that are not properly emptied (paper) or rinsed (plastic/metal) fall into this category, pesticide applicators frequently have difficulty disposing of unrinsed or improperly rinsed containers. Resources Fact Sheets Whitford F., A.G. Martin, J. D. Becovitz, A. Blessing, F. Koontz, R. Merzdorf. 2006. Pesticides and Container Management. Purdue University. PPP 21. 12 pp. http://www.btny.purdue.edu/Pubs/PPP/PPP-21.pdf Hofman, V. and G. Dahl. 1993. Pesticide Container Rinsing and Water Quality. http://www.ag.ndsu.edu/pubs/plantsci/pests/ae1052w.htm Web Sites Ag Container Recycling Council (ACRC) - http://www.acrecycle.org/ ACRC Contractors - http://www.acrecycle.org/contact.html Association of American Pesticide Control Officals - State Directory http://www.aapco.org/htm/control.htm The Pesticide Stewardship Alliance (TPSA) - http://www.tpsalliance.org/ TPSA Hazardous Waste Collection Contacts - http://www.tpsalliance.org/state_programs.html Regional Plastic Pesticide Container Recyclers Container Services Network - http://www.containerservicesnetwork.com/ Interstate Ag Plastics - http://www.interstateagplastics.com/ Northwest AgPlastics - http://www.nwagplastics.com/ USAg Recycling - http://www.usagrecycling.com/