N o r t h E a st I n d ep en d e nt S c h o o l D i st ri c t Chemistry Unit 3: Bonding, Formulas, Reactions Clarifying Statements May, 2006 In this unit students will explore chemical bonding by comparing and contrasting ionic and covalent bonding. They will identify the “chemical and physical properties of ionic and covalent compounds” (TEKS 8.B) and compare the “arrangement of atoms in molecules, ionic crystals, polymers, and metallic substances” (TEKS 8.C). Determining Ionic and Covalent – A Brief Comparison A covalent bond results from the sharing of electron pairs between two atoms while an ionic bond results from the attraction of a cation and an anion. Students must be able to analyze the electronegativities of elements in order to determine whether they form a covalent or an ionic bond. If a covalent bond is formed, they should be able to then determine if it is polar or nonpolar. Ionic Bonding Ionically bonded compounds are “composed of positive and negative ions that are combined so that the numbers of positive and negative charges are equal” (Modern Chemistry HRW, p. 176.) The positive ions (cations) result from metals, and the negative ions (anions) result from nonmetals. When ionic compounds are formed, valence electrons are transferred from the cations to the anions so that each atom obtains eight valence electrons, known as an octet. Using electron dot notations such as the one below will help students visualize how valence electrons are transferred. Students should then be able to predict the ionic formula unit of a compound and draw its structure. Clarifying statements are intended to deepen teachers’ understanding of science concepts and serve as a guide for instructional design. They are not intended to serve as student instructional materials. This publication is the property of North East Independent School District. Duplication in whole or in part, outside of NEISD, is prohibited without express written permission from NEISD. 1 N o r t h E a st I n d ep en d e nt S c h o o l D i st ri c t Chemistry Unit 3: Bonding, Formulas, Reactions Clarifying Statements May, 2006 Students will also learn to name and write balanced formulas for ionic compounds. In order to accomplish this, they must be able to name monatomic and polyatomic ions. It is recommended that students commit polyatomic ions to memory. On major assessments, students will be provided appropriate reference materials, including the Periodic Table and a polyatomic ion list. Students must understand that a formula unit is the simplest collection of atoms and that ionic compounds are crystalline structures made up of many, many organized ions (as in the following diagram). Covalent Bonding Covalently bonded compounds are called molecules. Teachers may choose to use simple organic or inorganic compounds to exemplify the characteristics of covalent molecules. Drawing Lewis structures that illustrate the octet rule, such as the figure below, will help students visualize the structure of molecules. Students should be able to draw molecules such as water, which contain single bonds representing lone pairs of electrons. It is appropriate to introduce students to double and triple bonds as well. Clarifying statements are intended to deepen teachers’ understanding of science concepts and serve as a guide for instructional design. They are not intended to serve as student instructional materials. This publication is the property of North East Independent School District. Duplication in whole or in part, outside of NEISD, is prohibited without express written permission from NEISD. 2 N o r t h E a st I n d ep en d e nt S c h o o l D i st ri c t Chemistry Unit 3: Bonding, Formulas, Reactions Clarifying Statements May, 2006 Students must also be able to use the appropriate prefixes (including the seven diatomic molecules) to name and write formulas for covalent molecules, as in the following. Molecular Shapes Students will further investigate covalent bonds by studying intermolecular forces. They must understand the influence of valence electrons on the geometry and structure of molecules. Students will be able to identify the geometry of molecules, including bent and linear. If time allows, students may also be introduced to trigonal planar, trigonal pyramidal, and tetrahedral molecules such as the ones below. Once students are familiar with the basic geometric shapes, they should be prepared to study polarity and hydrogen-bonding. Clarifying statements are intended to deepen teachers’ understanding of science concepts and serve as a guide for instructional design. They are not intended to serve as student instructional materials. This publication is the property of North East Independent School District. Duplication in whole or in part, outside of NEISD, is prohibited without express written permission from NEISD. 3 N o r t h E a st I n d ep en d e nt S c h o o l D i st ri c t Chemistry Unit 3: Bonding, Formulas, Reactions Clarifying Statements May, 2006 Induced dipoles and London forces are also introduced at this point. Students will learn that these intermolecular forces influence many of the chemical and physical properties of molecules. These properties will be expanded upon in future units and intermolecular forces will be referred to again, particularly in reference to water. It is a good practice for teachers to use sigma notation and arrows to indicate the direction of charge while teaching, as shown in the following diagram. Metallic Bonding A metallic bond is a chemical bond that results from the “attraction between metal atoms and the surrounding sea of electrons” (Modern Chemistry HRW, p. 181). Students must know that metallic properties such as conductivity, shiny appearance, malleability, and ductility result from the behavior of the electrons in metallic bonds. Introduction to Writing and Balancing Equations Teachers may wish to have students begin to write balanced chemical equations and determine molar masses of compounds in preparation for the next unit. Students can also be introduced to empirical and molecular formulas; as well as percent composition by mass. These concepts are necessary to conduct appropriate laboratory analysis of molecules. In this unit, students will begin writing balanced reactions from word equations. If time permits at the end of the semester, students can begin to classify these reactions as single replacement, double replacement, decomposition, synthesis, or combustion. Clarifying statements are intended to deepen teachers’ understanding of science concepts and serve as a guide for instructional design. They are not intended to serve as student instructional materials. This publication is the property of North East Independent School District. Duplication in whole or in part, outside of NEISD, is prohibited without express written permission from NEISD. 4