Atomic Theory and the Periodic Table Review What are the contributions of the following people to the atomic model? For those that resulted in a revision to the model. Draw the model they proposed. Democritus- originally named atom; atom model is solid homogenous sphere Dalton- proposed the atomic theory, atom model is solid homogeneous sphere Thomson- proved the existence of negative particles through work with cathode ray tubes; atom model had negative particles embedded in positive matrix (also called plum pudding model) Rutherford- proved the existence of the nucleus with gold foil experiment; atom model had positive particles in a nucleus surrounded by electron Chadwick- discovered the neutron Bohr- atom model had a nucleus of protons and neutrons surrounded by electron in fixed orbits like planets orbiting the sun Give the charge and location of each of the subatomic particles. Particle Charge Location Proton __+_____ __nucleus__________ Neutron __0_____ __nucleus__________ Electron __-_____ _orbiting nucleus______ Define the following: Atomic Number- number of protons in an atom Mass Number- number of particles in the nucleus (protons + neutrons) in a particular atom Atomic Mass- average mass of all the naturally occurring isotopes of an element according to their abundance Isotope- atoms of the same element that differ in their number of protons (and so also differ in their mass number) Ion- atom with a charge because of the number of protons and electrons are unequal Calculate the number of protons, neutrons, and electrons of the following isotopes. Isotope # of Protons # of Neutrons # of Electrons Hydrogen-3 1 2 1 Hydrogen-2 1 1 1 Calcium-40 20 20 20 Copper-63 29 34 29 Iodine-127 53 74 53 Barium-137 56 81 56 Write the nuclear symbol for each of the isotopes in the previous problem _3H__ __2H __ ___40Ca __ ___63Cu __ ___127I __ ___137Ba ___ Positive ions are called _cations_____. They form when atoms __lose______ electrons. Negative ions are called _anions_______. They form when atoms __gain______ electrons. Calculate the number of protons, neutrons, and electrons of the following ions. Ion # of Protons # of Neutrons # of Electrons 37 Cl- 17 20 18 22 Na+ 11 11 10 28 Mg+2 12 16 10 N-3 7 7 10 14 Calculate the average atomic mass of the following problems. Silver (Ag) is found as two isotopes (silver-107 and silver-109). What is the average atomic mass if the abundance of silver 107 is 51.86%? 107 x 0.5186 = 55.4902 109 x 0.4814 = 52.4726 55.4902 + 52.4726 = 107.96 amu Iron has four isotopes (listed with their abundances below). Calculate the average atomic mass. Iron-54 5.90% Iron-56 91.72% Iron-57 2.10% Iron-58 0.280% 54 x 0.0590 = 3.186 56 x 0.9172 = 51.3632 57 x 0.0210 = 1.197 58 x 0.00280 = 0.1624 3.68 + 3.666 + 35.232 + 2.695 = 55.91 amu Who is the “father” of the period table? Mendeleev The modern periodic table has the elements arranged by their _atomic number___ forming columns called _groups or families___ and rows called _periods_______. What group numbers are each of the following? Alkali metals- 1 Alkaline earth metals- 2 Halogens- 17 (7A) Nobel gases- 18 (8A) Transition elements- 3-12 Determine whether the following elements are metals, metalloids, or nonmetals. Ca metal Si metalloid Al metal Pb metal Ne nonmetal B metalloid List the seven diatomic elements. N, O, F, Cl, Br, I