CLAYS CLAYS AND CLAY BODIES The concept of a clay body has evolved in order to give the ceramic artist certain advantages over the problems and limitations of using single clays for all kinds of wares. Historically potters have always tended to settle where there was a good deposit of useful clay. The wares that were made reflected the character and limitations of that clay. Much of the world’s most beautiful pottery was made in just that way. If properly used, contemporary potters have the opportunity to utilize technology and the cheap and widely available selection of different clays and other materials to expand their possibilities and the expression of their character in pottery. There is no longer the imperative of setting up shop near ideal clay deposits. Adding sand or grog to a plastic clay in order to reduce cracking and shrinkage has been practiced for thousands of years and might be thought of as the first clay body. EGYPTIAN PASTE is another example of a very early type of clay body, as was the discovery of the Islamic potters that ground glass (FRIT) could be added to whitish clays in order to made them hard and translucent at low temperature, seeming to reproduce the “real” porcelains being made by the Tang Dynasty potters in China and much admired in the Middle Eat and Europe. The examples given above lead directly to what has become the first principle of clay bodies, which is that clay bodies are usually composed of three types of materials: Clays- Lend plasticity, color, texture and are of course, the main ingredient in clay bodies. Main types or groups of clays – KAOLINS, BALL CLAYS, STONEWARES, FIRE CLAYS and EARTHENWARES. Within each group are all sorts of properties. These properties must be studied in order to understand their proper and logical use in clay bodies. Flux- A flux is a material (or materials) that causes melting and fusion of the clays, giving hardness, density and durability to the body. The main clay body fluxes are FELDSPARS, FRITS and TALC with the occasional use of WHITING, DOLOMITE, BONE ASH, GERSTLEY BORATE and a few others to supplement the main ones. Fillers- Fillers are materials that reduce shrinkage, both wet to dry and in firing and impart other special properties to specific types of clay bodies. Mainly flint, grog, sand, wollastonite and alumina, with the less frequent and special uses of things like fiberglass, nylon fibers, sawdust, vermiculite, pearlite, pyrophlyte, barium carbonate, petalite, etc. The study of main clay bodies is a study of an informed combination of the three groups listed above. How do these materials interact with each other to give specific results at specific temperatures? CLAY BODIES: CLAY BODY considerations: Considerations for Body Development Color Defines material selection of clays and fluxes Significant influence on glaze color response May alter color with body stain (see Mason) or oxide Firing Temperature A function of the firing capabilities available to you Direct influence upon color palette Influences material selection to address thermal shock or other stresses on thick ware Greatly influences fired strength and body/glaze integration Density Will determine overall strength, lightness, permeability, durability, resistance to staining and acids, translucency and glaze fit. Texture Smooth or course textures are both visual and structural considerations Influences both clay and filler material selections Greatly influences suitability of various forming processes Plasticity Greatly influences suitability of body to various forming processes (esp. throwing) High plasticity=high clay content=high shrinkage Shrinkage (dry and fired) Low shrinkage=low clay content=low plasticity Greatly influences suitability for various forming processes Determines how susceptible ware is to cracking and warping during drying Greatly influences clay and filler selection Direct impact upon finished size of work (proportional to scale of work) Thermal Properties Coefficient of Thermal Expansion (CTE) Influences firing schedule/type (raku/quick fire) Affects durability of flameware/ovenware Influences glaze fit Kiln Atmosphere Vapor glazing will influence selection of clays (i.e. high free silica=more vapor glaze) Oxidation or reduction may also influence materials selection These considerations are inseparably integrated in composing a clay body. To successfully discuss clay body composition, it is necessary to break down the individual components of a body. Clay bodies can be broken down into three basic categories: Clays Kaolins Fire Clays Ball Clays Stoneware Earthenware Fillers Grog Sand Pyrophyllite Wollastonite Flint Fiber Fluxes Feldspars Nepheline Syenite Frits Talc Individual materials within the more general categories have distinctive characteristics. Each clay and material has a rather specific color (at different temperatures), maturation temperature, working properties and texture. These individual characteristics are of ultimate importance when choosing materials for a clay body composition. A basic description of some common materials and their characteristics follow. CLAY DESCRIPTIONS: KAOLINS - Most refractory (highest temperature) and white. Stocked at Metro: EPK (Edgars Plastic Kaolin) - Grolleg/China Clay - Florida Kaolin, white 200 mesh, medium plasticity. EPK is a water washed, secondary kaolin mined near Edgar, Florida. It is among the whitest-firing and most plastic of the North American kaolins, making it a valuable addition to both porcelain bodies and glaze suspensions. In glaze mixtures, EPK provides suspension, gelling, and application characteristics found in no other clay. It is economical and has been consistent over the years. English Kaolin, pure white, 200 mesh, high plasticity (higher cost). Grolleg is moderately plastic, has low titania content and relatively high flux content, low shrinkage, and white fired color, making it excellent for translucent throwing or casting bodies. Note that it has twice the iron oxide of #6 Tile kaolin but 40 times less titania. This is the primary reason for Grolleg’s translucency. The high flux content also allows one to formulate a porcelain with Tile #6 Helmar Kaolin Not stocked: Kaopaque Kaolin - FIRE CLAYS - more clay and less feldspar, making up for the lower plasticity of Grolleg. 6 Tile Kaolin is a selectively mined, airfloated kaolin produced in Georgia. It is offers high plasticity, white fired color, and high green strength. It is not as white as EPK; its higher titanium content tends to make bodies high in Tile #6 rather ivory-colored in oxidation firings, and grey in reduction. Kaolin that works especially well as flashing slip for salt, soda, and wood firing, especially since Avery kaolin is no longer being mined. Commercially purified and plasticized Kaolin, pure white, 200 mesh, good plasticity, used a whitener. High temperature, shale clays, coarse texture Stocked at Metro: Hawthorn Bond - Lincoln Not stocked: PBX or Valentine - BALL CLAYS - Missouri Fire Clay (A.P. Green & Hawthorn Bond), flint clay, 20 mesh, medium iron content, medium to low plasticity Pennsylvania/Ohio Fire Clay, 30 mesh, low iron content, medium plasticity Red Fireclay (A.P. Green), 20 mesh, high iron content, red/brown, medium plasticity High plasticity, high shrinkage Stocked at Metro: Kentucky Ball (OM4) - 200 mesh, low iron content, high plasticity, white to gray. Tennessee Ball Clay(SGP) - 200 mesh, low iron content, high plasticity, off white to gray. Excellent for quick slip casting. Gold Label. XX Sagger - High refractory ball type clay, 200 mesh Medium iron content, medium to high plasticity, warm white to orange, not as plastic and more refractory than ball clay. PV(Plastic Vitrox) STONEWARE - A California feldspathic earth, usually packaged under the label PVC for “Plastic Vitrox Clay”, that is similar in makeup to Cornwall Stone but fires whiter. It is preferred by many for use in white clay or glaze formulas where kaolin or a “white clay” is called for. Middle temperature Stocked at Metro: Goldart - 200 mesh, medium iron content, medium plasticity, gray-brown Foundry Hill Cream A good plastic ball clay that was out of production for awhile. Not as plastic as Not Stocked: Cedar Heights Bonding EARTHENWARE – Semi plastic, same as composition as Goldart - coarser grind Low temperature, secondary clay Stocked at Metro: Barnard - Redart - Not stocked: Ocmulgee - FILLERS Slip clay, 200 mesh, high iron content, dark brown to black. This is not a basic clay body, material, but a slip clay used mainly for color. (Cedar Heights Co.) 200 mesh, high iron content, high plasticity and shrinkage, low temperature, red color. Coarse Georgia earthenware, 20 mesh, medium to high iron content, medium plasticity, wide temperature range, tan to red color At Metro: Fiber - Paper Fiber: Flint/Silica/Quartz - Grog and Sand - Calcined Kaolin/Glomax Pyrophyllite - Sawdust Wollanstonite - Bentonite Macaloid Increases working and dry strength primarily for hand building. Two kinds: nylon fiber or glass fiber, the latter is hard on the hands. Both types melt or burn out in firing. Great for building strength and reduced shrinkage. Used for increased hardness as a glass former, aids in vitrification. Also used for whiteness. 200 mesh for clay bodies and most glazes, 325 mesh for glaze and porcelain. Opens clay bodies; decreases shrinkage and warpage; increases temperature, tooth and the ability to withstand thermal shock. May increase silica levels in vitrified bodies (quartz inversion) Grog is burned fireclay. In various mesh grinds. Molochite is a white, porcelain grog. Grogs and sand available in many different mesh sizes. A white filler that reduces shrinkage but does not contribute plasticity. Used for thermal shock resistance, Primarily in ovenware. Increases Silica levels in vitrified bodies (quartz inversion) Opens clay bodies, decreases shrinkage. Primarily used for excessively thick clay forms, decreases workability when coarse. Burns out in firing. Mixed in wet as a water additive. Used for thermal shock resistance in ovenware, Raku, etc. Available as both a powder and a fiber. Wollastonite reduces drying and fired shrinkage and adds fired strength to clay bodies (use fibrous form as raw material). Also helps make lovely “satin” type glazes (use powder form). plasticizer and suspension agent A very fine-grained plastic clay of volcanic origin containing colloidal matter. Used in small amounts as an additive to clays to aid in plasticity and in glazes as a suspending and binding agent. FLUXES - Encourage minerals to melt, aiding in vitrification Feldspars - Potash Feldspars best for clay bodies, especially high temperature, limit 25% approximately. Nepheline Syenite - Lower temperature Feldspar, used Frits Talc primarily for lower temperature clay bodies (6), limit 25% approximately. Lowfire flux. Limit 20%. For most clays use Frit 3124. Magnesium silicate, low temperature fusion. Low temperature clay body flux, inexpensive. Used in commercial low fire white clays. FELDPARS: Custer - potash spar Cornwall Stone - calcium/soda/potash spar Minspar (Kona) - soda spar, mid range Nepheline Syenite - soda spar, low range melt Spodumene - lithium spar