Acids, and Bases Learning Goals Acids and Bases 1. I can describe acids and bases in terms of their degree of dissociation in water and concentration of hydronium (H3O+) and hydroxide (OH-) ions. (14.1) A. I can diagram the dissociation of ions for acids and bases in water at the molecular level. 2. I can use nomenclature rules to name acids and bases. (14.1) A. I can name binary acids, (not containing oxygen) using the “hydro” prefix. B. Given a list of polyatomic ions, I can name oxy-acids using the correct “ic” or “ous” suffix. i. I can use “per” and “hypo” prefixes to name derivatives of polyatomic acids. C. Given names of acids and bases, I can predict chemical formulas. 3. I can use the pH scale to determine the acidic or basic nature of substances. (14.5 & 14.6) A. I can calculate the pH or pOH from [H3O+] or [OH-]. B. Given the pH or pOH, I can calculate the [H3O+] or [OH-] of a solution. C. I can use the ion product of water, Kw, to calculate the [H3O+] or [OH-] of a solution. 4. I can write and predict neutralization reactions for acids and bases. (14.7) 5. I can use titration results to calculate the molarity or volume for a solution of unknown concentration. (14.8) Vocabulary Dissociate Ionize Electrolyte Nonelectrolyte Hydronium ion Hydroxide Acid Base Neutral pH pOH Neutralization Indicator Titration Kw (Ion product constant) [H3O+] / [H+] [OH-] Salt End Point Titrant Buret Erlenmeyer Flask binary acids oxy-acids Achievement Scale Goal I can describe the formation of a solution at the molecular level. C Level I can identify the solute and solvent in a solution. B Level I can predict whether two substances will be miscible. I can identify solutes as strong electrolytes, weak electrolytes or nonelectrolytes based on their degree of dissociation. I can use molarity to calculation concentration. I can list which types of substances are strong electrolytes, weak electrolytes, and nonelectrolytes. Given a list of substances, I can identify which types of substances are strong electrolytes, weak electrolytes, and nonelectrolytes. Given the number of moles and the volume of solution, I can calculate the molarity. I can calculate the amount of another reactant or product in a chemical reaction using stoichiometry and molarity. I can describe acids and bases in terms of their degree of dissociation in water and concentration of hydronium (H3O+) and hydroxide (OH-) ions. I can use the pH scale to determine the acidic or basic nature of substances. I can use mole ratio and molarity to convert from moles of one substance to volume of another substance. Given the molarity, I can calculate the volume of solution, moles of a solute, or grams of a solute from the given information. I can use mole ratio and molarity to convert from volume of one substance to volume of another substance. I can contrast characteristics of acids and bases. I can identify the acids and bases and their conjugates in a chemical reaction. Given the pH, I can identify a substance as an acid, base, or neutral. I can calculate pH and pOH given the hydronium ion concentration. A Level I can explain using polarity why substances are miscible or immiscible. I can explain using diagram what occurs when strong and weak electrolytes are in solution. I can use the dilution equation to calculate dilution quantities and molarity. I can use mole ratio, molar mass, and molarity to convert from grams of one substance to volume of another substance. I can diagram acids and bases in aqueous solution and explain how strong and weak acids and bases dissociate. I can convert between pH, pOH, [H3O+] and [OH-] given one known variable. I can write and predict neutralization reactions for acids and bases. I can list the fundamental reactants and products in any neutralization reaction. Given the reactants, I can predict the products in a neutralization reaction. Given the reactants, I can complete and balance the neutralization equation. Sample Questions C Level 1) A solution of a gas contains 75% nitrogen and 25% oxygen. Which compound is the solute and which is the solvent? 2) Li st three different categories of substances that are strong electrolytes. 3) W hat is the molarity of a solution containing 36 moles of HNO3 in 6L of water? 4) G iven the following equation, 2NaOH + H2SO4 Na2SO4 + 2H2O, what volume of 6M NaOH is needed to completely react with 2 moles H2SO4? 5) Li st three differences between acids and bases. 6) A substance has a pH of 9. Describe the substance as a strong acid, strong base, weak acid, weak base, or neutral. 7) W hat are two products of any neutralization reaction? B Level 8) H4 is mixed with water. Will the substances be miscible or immiscible? C 9) W hich of the following substances are weak electrolytes? HNO3, HF, LiOH, NaBr, NH3 10) W hat volume of solution is needed to produce a 3M solution from 6 moles of NaOH? 11) G iven the following equation, 2NaOH + H2SO4 Na2SO4 + 2H2O, what volume of 6M NaOH is needed to completely react with 0.5L H2SO4 with a 3M concentration? 12) I dentify the acid and base and their conjugate acid and base in the following reaction: H2O + H3PO4 H2PO4- + H3O+ 13) W hat is the pH of a solution with a hydronium ion concentration of 2.0 x 14) 10-5M? W hat are the products if KOH is mixed with KNO3? A Level 15) se a diagram to explain why CH3OH is miscible in water. 16) U U se a diagram to show what happens when KOH is dissolved in water. 17) Y our supervisor tells you to make a 3M LiOH solution. If you start with 100mL of a 12M solution, what will your final volume be of the diluted solution? 18) G iven the following equation, 2NaOH + H2SO4 Na2SO4 + 2H2O, how many milliliters of 1M sulfuric acid are needed to completely react with 25.0g NaOH? 19) E xplain the difference of dissociation in solution between 6M nitric acid, HNO3, and 6M acetic acid, HC2H3O2. Use diagrams to show the difference. 20) W hat is the hydroxide concentration of a solution with a pH of 3.5? 21) C omplete and balance a reaction of H3PO4 and Mg(OH)2. Answers to Sample Problems: 1) S olute = oxygen, solvent = nitrogen 2) St rong Acids, Strong Bases, Salts 3) 6 M 4) 0. 67L NaOH 5) A + -7 cids: pH<7, pOH>7, [H3O ]>1x10 M, form hydronium ions in water, proton donors, turn blue litmus red, taste sour; Bases: pH>7, pOH<7, [OH-]>1x10-7M, proton acceptors, form hydroxide ions in water, turn red litmus blue, feel slippery, taste bitter 6) W eak base 7) W ater and salt (ionic compound) 8) I mmiscible (polar and nonpolar do not mix) 9) H F, NH3 10) 2L 11) 0.5L NaOH 12) Acid = H3PO4; Base = H2O; Conj. Acid = H3O+; Conj. Base = H2PO4- 13) 14) 15) 16) 17) 4.7 H2O and KNO3 Diagram should show positive and negative polar sections of CH3OH and H2O aligning. Diagram should show complete dissociation of K+ and OH- ions. 400mL 18) 19) 20) 21) 312 mL H2SO4 D iagram should show complete dissociation of the HNO3 and partial dissociation of HC2H3O2. 3.16 x 10-11M OH2H3PO4 + 3Mg(OH)2 6H2O + Mg3(PO4)2