Solutions, Acids, and Bases I Can Statements Solutions 1. I can describe the formation of a solution at the molecular level. (12.1) A. I can use polarity to describe and diagram solubility and predict which substances are miscible. 2. I can identify solutes as strong electrolytes, weak electrolytes or nonelectrolytes based on their degree of dissociation. (12.2) A. I can predict whether solutions will conduct electricity based on the nature of the solute. B. I can predict the degree to which solutes will dissociate in solution. 3. I can distinguish between an unsaturated, saturated, and supersaturated solution. (12.3) 4. I can calculate the molarity of a solution. (12.5) A. I can use molarity as a conversion factor to calculate the moles of a solute or the volume needed to prepare of a solution. B. I can use molarity to prepare dilutions. 5. Given the volume and molarity of a solution I can calculate the amount of another reactant or product in a chemical reaction using stoichiometry. (12.6) Acids and Bases 1. I can describe acids and bases in terms of their degree of dissociation in water and concentration of hydronium (H3O+) and hydroxide (OH-) ions. (14.1) A. I can compare the relative amount of dissociation for strong and weak acids and bases. (14.3) B. I can compare the electrolytic nature of strong and weak acids and bases. (14.3) C. I can diagram the dissociation of ions for acids and bases in water at the molecular level. 2. I can use the pH scale to determine the acidic or basic nature of substances. (14.6) A. I can calculate the pH from [H3O+]. B. Given the pH, I can calculate the [H3O+] or [OH-] of a solution. 3. I can write and predict neutralization reactions for acids and bases. (14.7) 4. I can use titration results to calculate the molarity or volume for a solution of unknown concentration. (14.8) Vocabulary Solution Solute Solvent Concentration Molarity Dilution Soluble Miscible Dissociate Ionize Electrolyte Nonelectrolyte Saturated Unsaturated Supersaturated Hydronium Hydroxide Acid Base Conjugate Acid Conjugate Base Neutral pH pOH Neutralization Indicator Titration Achievement Scale Goal I can describe the formation of a solution at the molecular level. C Level I can identify the solute and solvent in a solution. B Level I can predict whether two substances will be miscible. I can identify solutes as strong electrolytes, weak electrolytes or nonelectrolytes based on their degree of dissociation. I can use molarity to calculation concentration. I can list which types of substances are strong electrolytes, weak electrolytes, and nonelectrolytes. Given a list of substances, I can identify which types of substances are strong electrolytes, weak electrolytes, and nonelectrolytes. Given the number of moles and the volume of solution, I can calculate the molarity. I can calculate the amount of another reactant or product in a chemical reaction using stoichiometry and molarity. I can use mole ratio and molarity to convert from moles of one substance to volume of another substance. Given the molarity, I can calculate the volume of solution, moles of a solute, or grams of a solute from the given information. I can use mole ratio and molarity to convert from volume of one substance to volume of another substance. A Level I can explain using polarity why substances are miscible or immiscible. I can explain using diagram what occurs when strong and weak electrolytes are in solution. I can use the dilution equation to calculate dilution quantities and molarity. I can use mole ratio, molar mass, and molarity to convert from grams of one substance to volume of another substance. I can describe acids and bases in terms of their degree of dissociation in water and concentration of hydronium (H3O+) and hydroxide (OH-) ions. I can use the pH scale to determine the acidic or basic nature of substances. I can contrast characteristics of acids and bases. I can identify the acids and bases and their conjugates in a chemical reaction. Given the pH, I can identify a substance as an acid, base, or neutral. I can calculate pH and pOH given the hydronium ion concentration. I can write and predict neutralization reactions for acids and bases. I can list the fundamental reactants and products in any neutralization reaction. I can diagram acids and bases in aqueous solution and explain how strong and weak acids and bases dissociate. I can convert between pH, pOH, [H3O+] and [OH-] given one known variable. Given the reactants, I Given the reactants, can predict the I can complete and products in a balance the neutralization neutralization reaction. equation. Sample Questions C Level 1) A solution of a gas contains 75% nitrogen and 25% oxygen. Which compound is the solute and which is the solvent? 2) Li st three different categories of substances that are strong electrolytes. 3) W hat is the molarity of a solution containing 36 moles of HNO3 in 6L of water? 4) G iven the following equation, 2NaOH + H2SO4 Na2SO4 + 2H2O, what volume of 6M NaOH is needed to completely react with 2 moles H2SO4? 5) Li st three differences between acids and bases. 6) A substance has a pH of 9. Describe the substance as a strong acid, strong base, weak acid, weak base, or neutral. 7) W hat are two products of any neutralization reaction? B Level 8) C H4 is mixed with water. Will the substances be miscible or immiscible? 9) W hich of the following substances are weak electrolytes? HNO3, HF, LiOH, NaBr, NH3 10) W hat volume of solution is needed to produce a 3M solution from 6 moles of NaOH? 11) G iven the following equation, 2NaOH + H2SO4 Na2SO4 + 2H2O, what volume of 6M NaOH is needed to completely react with 0.5L H2SO4 with a 3M concentration? 12) I dentify the acid and base and their conjugate acid and base in the following reaction: H2O + H3PO4 H2PO4- + H3O+ 13) W hat is the pH of a solution with a hydronium ion concentration of 2.0 x 10-5M? 14) W hat are the products if KOH is mixed with KNO3? A Level 15) se a diagram to explain why CH3OH is miscible in water. 16) U U se a diagram to show what happens when KOH is dissolved in water. 17) Y our supervisor tells you to make a 3M LiOH solution. If you start with 100mL of a 12M solution, what will your final volume be of the diluted solution? 18) G iven the following equation, 2NaOH + H2SO4 Na2SO4 + 2H2O, how many milliliters of 1M sulfuric acid are needed to completely react with 25.0g NaOH? 19) E xplain the difference of dissociation in solution between 6M nitric acid, HNO3, and 6M acetic acid, HC2H3O2. Use diagrams to show the difference. 20) W hat is the hydroxide concentration of a solution with a pH of 3.5? 21) C omplete and balance a reaction of H3PO4 and Mg(OH)2. Answers to Sample Problems: 1) S olute = oxygen, solvent = nitrogen 2) St rong Acids, Strong Bases, Salts 3) 6 M 4) 0. 67L NaOH 5) A cids: pH<7, pOH>7, [H3O+]>1x10-7M, form hydronium ions in water, proton donors, turn blue litmus red, taste sour; Bases: pH>7, pOH<7, [OH-]>1x10-7M, proton acceptors, form hydroxide ions in water, turn red litmus blue, feel slippery, taste bitter 6) W eak base 7) W ater and salt (ionic compound) 8) I mmiscible (polar and nonpolar do not mix) 9) H F, NH3 10) 2L 11) 0.5L NaOH 12) Acid = H3PO4; Base = H2O; Conj. Acid = H3O+; Conj. Base = H2PO413) 14) 15) 16) 17) 18) 19) 20) 21) 4.7 H2O and KNO3 Diagram should show positive and negative polar sections of CH3OH and H2O aligning. Diagram should show complete dissociation of K+ and OH- ions. 400mL 312 mL H2SO4 D iagram should show complete dissociation of the HNO3 and partial dissociation of HC2H3O2. 3.16 x 10-11M OH2H3PO4 + 3Mg(OH)2 6H2O + Mg3(PO4)2