AP Chemistry Period 1 Name:____________________________ Multiple Choice Question Practice 1. In which of the following compounds does sulfur have an oxidation state of +4? a. H2S b. SO3 c. MgSO4 d. H2SO3 e. H2SO4 In H2SO3, the H’s have a +1 state, the O’s have a -2 state. To cancel out a +2 and a -6 (the balance is 4) the S has to be +4. 2. You have two samples of the same gas in the same size container, at the same pressure. The temperature in the first container is -23oC and the temperature in the second container is 227oC. What is the ratio of the number of moles of gas in the first container compared to that in the second container? a. 4 : 1 b. 1 : 4 c. 1 : 1 d. 2 : 1 e. 1 : 2 V=V2, P=P2, T = -23+273, T2 = 227 + 273 N1 = T2 = 500 = 2 N2 T1 250 1 3. 435 mL of a 0.100 M HNO3 solution is mixed with 235 mL of 0.175M Ca(OH)2. Which of the following statements are true? 1. Some HNO3 remains unreacted. 2. The solution is alkaline. 3. Water is a product. 4. The solution is acidic. 5. Some Ca(OH)2 remains unreacted. a. 1 and 5 b. 3 and 4 c. 2 and 3 d. 1 and 4 e. 1, 4, and 5 2 HNO3 + Ca(OH)2 2H2O + Ca(NO3)2 435mL*0.100M = 43.5mmol HNO3 (LR) 235mL*0.175M = 41.1mmol Ca(OH)2 Excess calcium hydroxide makes solution alkaline(basic) Water IS a product Statement 5 is also true, but there’s no option for that! Pick the most true choice. 4. A valve separates two tanks, one containing 7.6 liters of oxygen at 4.0 atmospheres and the other containing 4.0 liters of carbon dioxide at 11.0 atm. When the valve is opened and the two gases are allowed to come together, what is the final pressure? a. 6.4 atm b. 9.5 atm c. 1.8 atm d. 3.6 atm e. 8.2 atm Total V = 7.6 + 4.0 = 11.6 L Use PV=nRT for gas one to find moles Use PV=nRT for gas two to find moles. Add moles, use total volume to find total pressure. 5. How many grams of sodium chloride are dissolved in 50.0 mL of 1.50 M solution? a. 117 g b. 4.38 x 103 g c. 0.00324 g d. 4.38 g e. 23.4 g 0.050L * 1.50M = 0.075mol 0.075mol *58.44g/mol = 4.38 g 6. How many moles of gas would it take to fill an average man’s lungs, total capacity of which is about 4.5 liters? Assume 1.00 atm pressure and 37oC. a. 0.75 mol b. 37 mol c. 1.24 mol d. 11.2 mol e. 0.18 mol PV=nRT plug in and solve!! 7. Which of the following is the most soluble base? a. Ca(OH)2 b. Mg(OH)2 c. Ba(OH)2 d. NaOH e. Al(OH)3 Hydroxides are mostly soluble, sodium (alkalai metal!) is extremely soluble. 8. 325 mL of a gas at STP has a mass of 0.805 grams. What is the molar mass of the gaseous compound? a. 9.04 g/mol b. 55.5 g/mol c. 0.0555 g/mol d. None of these e. 31.7 g/mol Moles = 0.805(Molar Mass) Plug into PV=nRT… PV=(0.805)(MM)RT 9. In the balanced molecular equation for the neutralization reaction between phosphoric acid and potassium hydroxide, the products are: a. KPO4 + H3OH b. K3PO4 + 3H2O c. K+(aq) + PO4-3(aq) + 3H+ + 3OHd. 3 H2O e. None of these H3PO4 + 3KOH 3H2O + K3PO4 10. An 8.25 L sample of oxygen is collected at 25oC and 1.022 atm pressure. What volume will the gas occupy at 0.940 atm and -15oC? a. 10.4 L b. 8.76 L c. 5.00 L d. 7.77 L e. 1.78 L PV =P2V2 Plug in and solve T T2 11. NaCl + H2SO4 + MnO2 Na2SO4 + MnSO4 + H2O + Cl2 In this reaction, the reducing agent is: a. Mn4+ b. H+ c. O2d. Na+ e. ClCl-1 Cl2 and MnO2 MnSO4 -1 0 +4 +2 Oxidized (red.ag.) Reduced (Ox.Ag) 12. Which of the following is not a weak acid? a. HClO b. H2CO3 c. HF d. H2S e. HNO3 Nitric acid is a strong acid! 13. A chemist makes a stock solution of potassium chromate solution by dissolving 97.1 grams of the compound in 1.00 liter of solution. What volume of the solution must be diluted with water in order to prepare 200. mL of 0.200 M solution? a. 0.150 L b. 0.0800 mL c. 80.0 mL d. 750. mL e. 120 mL (97.1g / (194.2g/mole))/1.00L = 0.5 M M1V1 = M2V2 0.5(x) = (200)(0.2) 14. In which flask do the molecules have the highest average velocity? Flask 1: 1 Liter of NH3 at STP Flask 2: 1 Liter of CH4 at STP Flask 3: 1 Liter of O2 at STP a. b. c. d. e. Flask 2 Flask 2 and 3 Flask 1 Flask 3 All are the same All are at the same temperature, all have the same kinetic energy, so all are at the same speed. 15. In which of the flasks from question 14 is the greatest number of molecules? a. Flask 1 b. Flask 3 c. Flask 2 d. Flasks 2 and 3 e. All are the same CH4 has the lightest molar mass, so in an equal volume under constant conditions, there are more moles of CH4