Calculations: Energy, Frequency, and Wavelength 1. What are the frequency and energy of blue light that has a wavelength of 400.00 nm? Ans: = 7.50 x 1014 Hz E = 4.97 x 10-19 J 2. What are the wavelength and energy of light that has a frequency of 1.50 x 1015 Hz? Ans: = 2.0 x 10-7 m E = 9.95 x 10-19 J 3. Calculate the wavelength of a photon of radiation whose frequency is 7.5 x 1012 Hz. Ans: = 4.0 x 10-5 m 4. A photon of radiation has a frequency of 3.33 x 1013 Hz. Calculate the energy in one mole of these photons. Ans: E = 1.33 x 104 J 5. Co-60 is used as a source of gamma rays in the treatment of certain cancers. If the wavelength of one photon of this radiation is 1 x 10-8 Ao (Angstrom (Ao) = 10-8 cm), determine it’s energy. Ans: E = 1.99 x 10-7 J 6. Heating sodium releases light with many different wavelengths. One of these has a wavelength of 589 nm. Calculate the energy associated with one photon of this light. Ans: E = 3.38 x 10-19 J 7. Calculate the number of photons having a wavelength of 10.0 m required to produce 1.0 kJ of energy. Ans: 5.0 x 1022 photons 8. Calculate the energy released by a photon of radiation having a wavelength of 3.12 x 10-7 m. Ans; E = 6.37 x 10-19 J 9. Calculate the energy for the 2nd energy level (n = 2) of Bohr’s hydrogen atom. (Rydberg constant RH = 2.18 x 10-18 J). Ans: E = 5.45 x 10-19 J 10. Calculate the energy of the 6th energy level (n = 6) of Bohr’s hydrogen atom. Ans: E = 6.1 x 10-20 J 11. An electron in the Lyman series of a hydrogen atom transitions from n = 2. Calculate the frequency of the photon released from this transition. Ans: = 2.47 x 1015 Hz 12. Calculate the wavelength in nm of a photon of light emitted in the Balmer series by a hydrogen atom when n = 3. Ans: = 656 nm 13. Calculate the wavelength in nm of a photon of light emitted during a transition from n = 5 to n = 2. Ans: = 434 nm 14. Calculate the energy released by a photon of light in the Brackett series as it transitions from n = 12. Ans: 1.21 x 10-19J 15. Calculate the total energy in 12 dozen photons of UV radiation (ν = 1016 Hz). Ans: E = 9.55 x 10-16 J Equations: En = -RH(1/n2) where RH = 2.18 x 10-18 J E = Ef – Ei = RH(1/ni2 – 1/nf2) and E = h = hc/ = RH(1/ni2 – 1/nf2) to calculate frequency or wavelength