BONDING AND NOMENCLATURE REVIEW - KEY BONDING State the octet rule. Atoms react by changing the number of electrons in their outer shells as to acquire the stable structure of noble gases (8 electrons in outer shell). Complete the table below. Element symbol Formula for ion # of electrons gained or lost Name of ion Anion or Cation? 1. Sr Sr2+ 2 electrons lost strontium ion cation 2. P P3- 3 electrons gained phosphide ion anion 3. Br Br- 1 electron gained bromide ion anion 4. O O2- 2 electrons gained oxide ion anion 5. Cs Cs+ 1 electron lost cesium ion cation Complete the table below. Formula and charge for ion 1. SO32- Name of ion sulfite ion 2. PO43- phosphate ion 3. NH4+ ammonium ion 4. CO32- carbonate ion 5. ClO2- chlorite ion 6. CrO42- chromate ion What is the difference between an ionic bond and a covalent bond? Ionic bond – electrons transferred (metal + nonmetal, metal + polyatomic ion, or 2 polyatomic ions) Covalent bond – electrons shared (2 or more nonmetals, no ions) State whether a. KF d. P2O5 g. H2SO4 the following compounds would contain ionic bonds, covalent bonds, or both. ionic b. Br2 covalent c. N2Cl4 covalent covalent e. FeS ionic f. NH4OH both both h. CBr4 covalent i. Mg3(PO4)2 both Draw all of the resonance structures and name the 3-dimensional shape of this molecule: CO32Trigonal planar For each of the following, draw the lewis structure and name the 3-dimensional shape (tetrahedral, pyramidal, bent, linear, or triangular planar). State whether the molecule is polar or nonpolar. If it is polar, then indicate polarity with an arrow or with the appropriate symbols for partial charges. PCl3 N: 8 + 3(8) = 32 A: 5 + 3(7) = 26 S = 6/2 = 3 bonds PYRAMIDAL polar from P to Cl H 2S N: 2(2) + 8 = 12 A: 2(1) + 6 = 8 S: 4/2 = 2 bonds BENT polar towards S SO42N: 8 + 4(8) = 40 A: 6 + 4(6) +2 = 32 S: 8/2 = 4 bonds Tetrahedral nonpolar NO2N: 8 + 2(8) = 24 A: 5 + 2(6) +1 = 18 S: 8/2 = 3 bonds BENT polar towards O CO2 N: 8 + 2(8) = 24 A: 4 + 2(6) = 16 S: 8/2 = 4 bonds LINEAR nonpolar SO32N: 8 + 3(8) = 32 A: 6 + 3(6) +2 = 26 S: 6/2 = 3 bonds PYRAMIDAL polar towards electron pair on S NOMENCLATURE Write the correct chemical names or formulas for the following acids: HF hydrofluoric acid H2CO3 H2SO3 sulfurous acid HCN nitrous acid HNO2 chloric acid carbonic acid hydrocyanic acid HClO3 Complete the chart below. (Note: ionic compounds and molecular compounds are mixed together!) Formula Name Ca(OH)2 Calcium hydroxide Na3PO4 Sodium phosphate NCl3 Nitrogen trichloride Pb3(PO4) 2 Lead (II) phosphate Mn3N2 Manganese (II) nitride NBr3 Nitrogen tribromide Co(NO2)2 Cobalt (II) nitrite Zn(HCO3)2 Zinc bicarbonate NO Nitrogen monoxide AgNO3 Silver nitrate PCl3 Phosphorus trichloride MgCrO4 Magnesium chromate CsI Cesium iodide SrSO4 Strontium sulfate Ba(ClO3) 2 Barium chlorate PI3 Phosphorus triiodide MnO Manganese (II) oxide SnF2 Tin (II) fluoride K2Cr2O7 Potassium dichromate Li2SO3 Lithium sulfite Al2(CO3) 3 Aluminum carbonate