CHEMISTRY UNIT NOTES Chemistry Unit Notes 1 Objective 4.01: Understand that naturally occurring and synthetic substances are chemicals Key Terms 4.01 Chemical Synthetic chemical Matter Element Synthetic element Mixture Compound Science book page numbers Ch 13 pgs 536-544 Notes 4.01 Chemical—substance that used in a chemical process or that is formed by a chemical process or it may also be any substance that is always made of the same thing o Ex. Water is always H2O Chemicals can be natural or synthetic o Natural—CO2, H2O, gold, and sugar o Synthetic—chemicals made in the laboratory Ex. Plastic, steel, bronze Matter is anything that has mass and volume Mass is the amount of matter in a substance Volume is the amount of space the substance occupies The main three states of matter—solid, liquid, and gas o Solid has a definite shape and volume—table, chair o Liquid has a definite volume but not shape—water, oil o Gas doesn’t have a definite volume or shape—air Element-simplest form of matter, it can not be broken down into simpler substances by ordinary chemical means o Changing an element to another element requires a lot of energy such as a nuclear explosion o There are about 109 elements discovered all of the known elements are combined into natural elements and synthetic elements—93 are natural elements, synthetic elements—16 that scientists created Mixture—when two or more substances combine but do not join together chemically—the different parts keep their individual identities (properties) o Ex. Cereal(mix of bran, fruit, milk, etc) and air (mix of gases) Compound—when two or more elements combine chemically, individual substances join and do not keep their original properties Chemistry Unit Notes 2 o Ex table salt (NaCl—sodium chloride), sodium by itself is a metal that explodes in water and chlorine is a poisonous gas—together you can eat it Mixtures and compounds can be natural or synthetic o Minerals are examples of natural mixtures o Stainless steel is an example of synthetic mixture http://1.bp.blogspot.com/_CxKx0boID9A/TUIo73lCUGI/AAAAAAAAAAM/RBJ3p3M6W4A/s1600/periodic_table3.gif Discussion Question 1 Briefly explain the difference between a mixture and a compound and give two examples of each. Chemistry Unit Notes 3 Objective 4.02: Evaluate evidence that elements combine in a multiple of ways to produce compounds that account for all living and nonliving substances Key Terms 4.02 Compound Molecule Chemical formula Atom Proton Neutron Electron Nucleus Valence electrons Ionic bond Ion Covalent bond Science Book Reading Review Ch 13 Sec 1 Read Ch 15 Sec 1 pgs 604-609 Notes 4.02 Compound—two or more substances chemically combine forming a new substance o Have a definite composition---NaCl is always table salt o Can be broken down into simpler substances by chemical means meaning NaCl can be broken into Na and Cl o Can be identified by their physical properties meaning how you observe it and measure it Molecule—smallest unit of a compound that has all the properties of the compound o Ex smallest molecule of water would be H2O Chemical formula—the makeup of a compound, uses chemical symbols and subscripts to identify the number of atoms of each element in a molecule of a compound o Ex. H and O are chemical symbols of hydrogen and oxygen, 2 is the subscript for the number of hydrogen atoms needed to bond with oxygen to make water…this is the formula for water H2O o When there is not a subscript for a symbol that means there is only 1 atom present, you need one sodium and one chlorine to make salt the chemical formula is NaCl Atom—smallest unit of an element that has the properties of the element, also called the building block of an matter Chemistry Unit Notes 4 http://0.tqn.com/d/chemistry/1/7/w/2/1/helium-atom.jpg Three types of atom particles: protons, neutrons, and electrons o Proton—a particle with a positive charge (+) o Neutron—a particle without a charge (neutral) ( ) o Electron—a particle with a negative charge (-) Protons and neutrons are found in the center of the atom called the nucleus Electrons orbit the nucleus in a region called the electron cloud Electrons have different amounts of energy The closest electrons have less energy than electrons farther from the nucleus Electrons on the same energy level have similar amounts of energy Each energy level can hold a certain number of electrons Energy Level Max Number of Electrons 1 2 2 8 3 18 4 32 Valence electrons are found in the outer shell of the atom o To determine how atoms combine to make compounds is dependent upon the number and arrangement of valence electrons Chemical bonds—forces that hold atoms together o Ionic bond-when a bond is formed by losing or gaining electrons o Ion—atom that has gained or lost one or more electrons Losses electrons—atom becomes positive Gains electrons—atom becomes negative Form because opposite charges attract Chemistry Unit Notes 5 http://3.bp.blogspot.com/-0lmakBuwdIc/TVvctuCdf8I/AAAAAAAAADc/TKzKB8OzE5E/s1600/ionic.bond.jpg To bond atoms need to have a total of eight electrons in their outer energy level o Atoms with 1, 2, or 3 valence electrons normally give their electrons to atoms of elements that have 7, 6, or 5 valence electrons Covalent bonds—atoms share valence electrons o Form between elements whose atoms have 4, 5, 6, or 7 valence electrons Chemistry Unit Notes 6 The same elements and be combined differently to form different elements o Ex. H2O=water, H2O2=hydrogen peroxide; CO=carbon monoxide, CO2= carbon dioxide Atomic Theory o All matter is composed of atoms (building block) o Atoms of a given element are identical—same number of protons and electrons o Atoms of different elements combine in simple whole-number ratios to form chemical compounds—determined by valence electrons o Compounds can make up living or nonliving substances Living—proteins, carbohydrates, fats Nonliving—plastics, rubber, medicines Discussion Question 2 Is it possible to change a mixture into a compound? Objective 4.03: Explain how the Periodic Table is a model for: Classifying elements Identifying the properties of elements Key Terms 4.03 Atomic mass Periodic table Atomic number Period Group Reactivity Metalloid Inert Science Book Reading Review Ch 15 Sec 1 Read Ch 15 Sec 2 pgs 610-617 Notes 4.03 Atomic mass—equal to the number of protons and neutrons in the nucleus Mendeleev’s periodic table arranges elements according to the atomic mass Elements with similar properties are found in the same column Periodic table—chart that organizes information about all of the known elements according to their properties Chemistry Unit Notes 7 http://www.click4chill.com/wp-content/uploads/2010/11/Periodic-Table-of-Elements-fix.jpg Today elements are in order of the atomic number Atomic number—number of protons in the nucleus of an atom Period is the horizontal row in the periodic table o Numbered 1-7, arranged in order of increasing atomic number Chemical family or group is the Vertical column on the periodic table o All have similar properties, numbered 1-18 and from 1A to 8A, all have same number of valence electrons o Groups 1-2(IA-IIA) and 13-18(IIIA-VIIIA) are the main groups o Groups 3-12 are called transition elements o Elements on the left side of the periodic table are metals, except hydrogen o Elements on the right side of the periodic table are nonmetals Properties of Metal Solid at room temperature, except mercury, which is a liquid Malleable(shaped) and ductile (drawn into wire) Have luster (shiny) Have high thermal and electrical conductivity Tend to lose electrons in chemical reactions Properties of Nonmetals Most are gases, except bromine, which is a liquid Brittle in solid phase Normally dull Are poor conductors of heat and electricity Tend to gain electrons in chemical Chemistry Unit Notes 8 reactions Reactivity describes how likely an element is to form bonds with other elements Hydrogen is found above Group 1 but doesn’t belong to any group. It was placed here because it only has one valence electron. It’s properties are different from the other groups. Group 1 (Alkali Metals) on periodic table o Most chemically active o One electron in the outer shell o Easily combine with nonmetals o Reactivity of the metal increases with increasing atomic number Group 2 (Alkaline Earth Metal) on the periodic table o Highly reactive but less reactive than group 1 o Reactivity of the metal increases with increasing atomic number Group 3 –12 (transition metals) on the periodic table o Generally hard solids with high melting points o Often form colored ions Metalloids o Found along the zigzag between the metals and nonmetals on the periodic table o Have properties of both metals and nonmetals Group 17 (Halogens) on the periodic table o Most reactive of the nonmetals o Reactivity in nonmetals increases as atomic number decreases o Fluorine (F) is the most reactive o Halogens react with alkali metals to form salts o Elements in this family are all states of matter Fluorine(Fl) and Chlorine—gases Bromine (Br)—liquid Iodine (I) and Astatine (At) are solids at room temperature Group 18 (Noble Gases) on periodic table o Least reactive of all elements o Inert—unable to react chemically Discussion Question 3 When looking at different versions of the periodic table, why is hydrogen normally not attached to the periodic table? Chemistry Unit Notes 9 Objective 4.04: Describe the suitability of materials for use in technological design: Electrical conductivity Density Magnetism Solubility Malleability Key Terms 4.04 Property Physical property Chemical property Metal Nonmetal Metalloid Malleable Ductile Magnetism Conductor Insulator Semiconductor Density Solubility Science Book Readings Review Ch 15 Sec 2 Read Ch 13 pgs 538-539 Read Ch 13 Sec 2 pgs 546-550 Read Ch 15 Sec 3 pgs 618-624 Read Ch 15 Sec 4 pgs 625-635 Notes 4.04 Property—any factor that can be used identify and describe matter o Helps for deciding the uses of various materials for technology Physical property—observable and measureable characteristic without changing the identity of the substance o Ex Mass, volume, color, hardness, and phase o Every substance has its own unique properties Chemical property—how the matter will change under certain conditions, this characteristic is unique to substances o Ability to burn, rust, react to light, or react with acids are chemical properties of matter Zigzag line divides the table into metalloids, metals, and nonmetals Chemistry Unit Notes 10 Malleable—able to be hammered and shaped and rolled into thin sheets like foil Ductile—able to be stretched or drawn into wires without breaking Magnetism—attraction(moving towards) or repulsion (moving away) between like or unlike poles—iron, cobalt, and nickel are strong magnets Conductor—a material or substance electricity or heat easily flows through Insulators—a material that electricity or heat doesn’t easily flow through—rubber, wood, plastic, glass Semiconductor—a material that has conductive properties that are variable—these can be useful for carrying electricity under certain conditions Density—density=mass/volume certain substances have a specific density Solubility—measure of how much of a substance can dissolve in a certain amount of another substance o Carbon dioxide will dissolve more in water than oxygen, that’s why it is used in sodas Discussion Question 4 Insulation is used in the walls of homes to regulate the flow of heat into and out of the house. Why would aluminum be a poor choice for insulation? Objective 4.05: Identify substances based on characteristic physical properties: Density Boiling/Melting points Solubility Chemical reactivity Specific heat Key Terms 4.05 Physical property Density Melting point Boiling point Specific heat Solubility Solution Reactivity Chemistry Unit Notes 11 Science Book Reading Review pgs 538-539, 549, 550 Read Ch 16 Sec 2 pgs 698-703 Read Ch 14 Sec 1 & 2 pgs 572-583 Notes 4.05 Temperature is a physical property that is used to determine a substance because the temperature that a substance melts or boils is specific for the that substance Melting point—the temperature at which a solid changes into a liquid—water 0C Boiling point—the temperature at which a liquid changes into a gas—water 100C Specific heat—the amount of heat needed to raise 1 gram (1 g) of a substance by 1 degree Celsius o The unit of specific heat is joules per gram per degree Celsius (J/g C) o Used to compare how different substances absorb heat Substance Specific Heat (J/g C) Water (liquid) 4.18 Ethanol 2.44 Water (solid) 2.06 Aluminum 0.897 Lead 0.129 Of the above substances lead heats the fastest it has the lowest specific heat Solubility, chemical properties, and reactivity are also identifiers of substances Discussion Question 5 Is it possible for two different substances to have the same physical property? Explain. Objective 4.06: Describe and measure quantities related to chemical/physical changes within a system: Temperature Volume Mass Precipitate Gas production Chemistry Unit Notes 12 Key Terms 4.06 Physical change Chemical change Chemical reaction Precipitate Reactant Product Science Book Readings Review pgs 538-539 Read pgs 552-554, 556, 650-655 Notes 4.06 Physical change-changing the physical properties of a substance without changing the substance—melting ice it is still water, tearing a sheet of paper it is still paper, and sharpening pencil it is still a pencil Chemical change—changing a substance into a new substance this will make it have different properties—involve chemical reactions Sodium is a metal and chlorine is a gas when they react (chemically change) the new substance created is table salt Chemical reaction—the process by which new substances are formed, most aren’t reversible Sign of Chemical Reaction Formation of precipitate Gas formation Color change Energy change Explanation A solid forms in a solution If you see bubbles or visible gas Substances change color A rise (exothermic) or fall(endothermic) in temperature, light is given off Chemical bonds are either broken or formed—this requires energy—during a chemical reaction Energy is released whenever new bonds form to join substances together Most chemical reactions release energy as heat, temperature rises o Ex. Propane burns in the presence of oxygen Chemical Reaction propane + oxygen carbon dioxide + water + energy (heat and light) Reactants Products Reactant—substance that takes part in a chemical reaction Product—substance formed during a chemical reaction Discussion Question 6 If a solid is added to water and water temperature rises from 20ºC to 26ºC, what type of change does this indicate? Chemistry Unit Notes 13 Objective 4.07: Identify evidence supporting the law of conservation of matter: During an ordinary chemical reaction matter cannot be created or destroyed In a chemical reaction, the total mass of the reactants equals the total mass of the products Key Terms 4.07 Law of Conservation of Matter Law of Conservation of Mass Molecule Science Book Reading Read Pgs 555, 660-667, 670-675 Notes 4.07 Law of conservation of matter states that during a chemical reaction, matter cannot be created or destroyed Law of conservation of mass states that mass of the products must equal the mass of the reactants Discussion Question 7 Compare shuffling a deck of cards to a chemical reaction? Objective 4.08: Identify that some chemical may contribute to human health conditions including: Cancer Autoimmune disease Birth defects Heart disease Diabetes Learning and behavioral disorders Kidney disease Asthma Chemistry Unit Notes 14 Key Terms 4.08 Cancer Carcinogen Fetal alcohol syndrome (FAS) Kidneys Ureter Bronchi Science Book Readings Read pgs 646-647, 686-687 Notes 4.08 Cancer—a group of diseases caused by abnormal (uncontrolled) cell growth and reproduction o Tumor—large mass of cells joined together Carcinogen—chemical that causes cancer o Ex. of chemicals that can cause cancer are asbestos and radon Some chemicals cause birth defects o Ex. smoking during pregnancy can increase the chance cleft lip, cleft palate, and heart defects o Drinking during pregnancy may cause fetal alcohol syndrome (FAS)— causing brain damage, learning disabilities or behavioral problems, slow growth, irregular facial features, visual and hearing problems, and some types of heart, liver, and kidney disorders Heart disease can be caused by nicotine found in tobacco which causes arteries to narrow o cholesterol is a chemical that can cause heart disease A build up of ammonia, uric acid, and calcium can cause kidney stones Some chemicals (cleaning products aerosols) being inhaled can trigger asthma where the bronchi swell making it difficult to breathe Discussion Question 8 You’ve learned about chemicals that have a negative effect on humans. What are some chemicals that positively effect humans? Chemistry Unit Notes 15 Objective 4.09: Describe factors that determine the effects a chemical has on a living organism including: Exposure Potency Dose and the resultant concentration of chemical in the organism Individual susceptibility Possible means to eliminate or reduce effects Key Terms 4.09 Dose Potency Toxicity test Exposure time Concentration Science Book Readings Review previous readings Notes 4.09 Chemicals that are developed for a specific purpose can have unintended effects on the environment, most effects aren’t noticed until a serious problem has occurred o Ex. DDT was made in 1873, 1939 DDT began being used as a pesticide, 1962 people discovered the negative effects of DDT on bird populations The dose, potency, exposure time, individual susceptibility, and concentration determines the effect a chemical will have on an organism Dose—a chemical substance is the amount that is given to one individual, sometimes it hard to tell what dose is appropriate Potency—how powerful a chemical is, any drug that is said to produce visible or measurable effect at a low dose is said to have a high potency o Toxicity test—the test given to see how potent a drug is Exposure time—how long an individual is exposed to a chemical—this is not always easy to determine do to the fact that the stability of chemicals varies, meaning some chemicals breakdown faster than others Individual susceptibility—an individuals response to a chemical, which varies depending on the individual—the factors that determine this are genetic and physical make-up Concentration—a chemical’s concentration refers to the amount of a substance in a given volume—it can be calculated by knowing the mass and volume of a Chemistry Unit Notes 16 substance—however, in the environment it is difficult to calculate because many factors affect how far a chemical will spread Discussion Question 9 Explain why the osprey population has recovered in the past 10 years. Objective 4.10: Describe risks and benefits of chemicals including: Medicines Food preservations Crop yield Sanitation Key Terms 4.10 Risk benefit analysis Food preservatives Oxidation Allergy Food intolerance Antibiotics Fertilizers Pesticides Science Book Readings Read pgs 762-763 Notes 4.10 Benefits-how in the chemical meets the needs of society Risks-the negative affects the chemical may have on the environment or for people Risk-benefit analysis-is the process of weighing the potential harm against the good that will come out of using the chemical Sanitation-all the methods of removal, treatment, and disposal of wastes Wastewater treatment-the process of making water safe to be used for people and other organisms o Activated charcoal can be used to remove contaminants from water o Chlorine used in low amounts can be used to remove contaminants from water…low doses it cleans iron, manganese, and hydrogen sulfide from water, drawbacks is the smell and taste of the water when it is used Chemistry Unit Notes 17 Food preservatives-chemicals used to prevent food spoilage caused by microorganisms o Some inhibit the growth of microorganisms o Some slow oxidation or the substance reacting with oxygen Ex. Preventing fruit to turn brown o Some preservatives used today include MSG, BHT, sodium benzoate, potassium sorbate, etc o Risks of preservatives include allergies or food intolerances Allergies-immune system response to proteins in the food Food intolerance-not able to digest a food or additive Allergy Symptoms Sneezing, headache, rash, coughing, vomiting, drop in blood pressure, difficulty breathing, swelling Food Intolerance Symptoms Rash, congestion, tiredness, weight gain or weight loss, digestive problems, headache Medicines can be natural or synthetic they have been used for years to various treat medical problems. o Antibiotics is one chemical that is used to treat bacterial infections the drawback of using antibiotics all of the time is that bacteria are able to mutate and build up a resistance and withstand many of the older antibiotics Chemicals are also used to increase crop yield. Two that are used are fertilizers and pesticides o Fertilizers are chemicals used to promote plant growth by giving them nitrogen, potash, other nutrients Risk of using fertilizers is when it rains the run-off goes into water sources and causes an excess of algae growth o Pesticides are chemicals used to kill organisms that hinder the growth of plants or are pests Some pesticides include chemicals such as arsenic, lead, mercury, nicotine sulfate The risks of using pesticides is that some organisms that aren’t pests can be harmed Discussion Question 10 Use examples to show that there are both risks and benefits for using chemicals.