Safety Data Sheet
according to 1907/2006/EC, Article 31
Date of printing: 11/09/2013
Date of revision:
Page 1 of 5
1. Identification of substance/mixture and company/undertaking
Identification of substance/mixture
Isokor Glass Profi 25 ml, 90 ml, 100 ml, 500 ml, 950 ml, 1000 ml, 5000 ml
Use of the substance/mixture
Hydrophobic coating against dirt
Manufacturer: ISOKOR Ltd
Address: 976 34 Tajov 242, Slovakia
Telephone: +421(0)903423582
E-mail: info@isokor.com
Internet: www.isokor.com
Information department:
+421(0)254774166
National Toxicological Information Centre at University Hospital in Bratislava and Faculty of Medicine
in Bratislava, Clinic of Industrial Medicine and Toxicology, Limbová 5, 833 05 Bratislava, Slovakia
2. Hazards identification
Classification
Hazard symbols: F – Highly flammable, Xi – Irritant
R phrases: 11 Highly flammable.
36 Irritant to eyes
67 Vapours may cause drowsiness and dizziness.
S- phrases: 2, 7, 16, 24-25, 26, 46
GHS: Classification:
Flammable liquid: Flam. Liq. 2
Serious eye damage/eye irritation: Eye Irrit. 2
Target Organ Systemic Toxicity – Single Exposure: STOT SE 3
Hazard statement codes: H225 – Highly flammable liquid and vapour,
H319 – Causes serious eye irritation, H336 – May cause drowsiness or dizziness,
Pictogram codes: GHS02, GHS07, Dgr. – Signal word: Danger
3. Composition/information on ingredients
Chemical characteristics (mixtures)
Description: Modified hybrid materials dissolved in solvent
Hazardous substances contained:
ES-number 200-661-7
Label: Propan-2-ol
Proportion: 90 – 97%
CAS-number 67-63-0
Index number 603-117-00-0
Classification F, Xi R11-36-67
ES-number 200-578-6
CAS-number 64-17-5
Index number 603-002-00-5
Label: Ethanol
Proportion: 0,2 - 1%
Classification F, R11
GHS Classification Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336
For the full text of R- and H-phrases see section 16.
4. First aid measures
General instructions
Take off immediately all contaminated clothing.
Safety Data Sheet
according to 1907/2006/EC, Article 31
Date of printing: 11/09/2013
Date of revision:
Page 2 of 5
Inhalation
Remove victim to fresh air.
Skin contact
Immediately rinse with plenty of water for at least 15 minutes. Take off immediately all contaminated
clothing. If skin irritation persists, seek medical help.
Eye contact
Rinse opened eyes thoroughly with plenty of water for at least 15 minutes. Consult a doctor.
Ingestion
Rinse mouth with water and drink plenty of water. Do not induce vomiting. Consult a doctor.
Special instructions for physician
Treat symptomatically.
5. Firefighting measures
Suitable extinguishing media Foam, dry powder
Special hazards arising from the substance or mixture itself, combustion products, resulting
gases
May produce hazardous toxic gases or fumes in case of fire
Advice for firefighters
Wear protective respirator with independent air supply in case of fire. Avoid contact with skin – keep a
safe distance from the fire or wear appropriate protective clothing.
Further instructions
Dispose of combustion residues and contaminated extinction water according to local official
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up
Soak up with an inert absorbent material and dispose of as hazardous waste.
Further instructions
Dispose of combustion residues and contaminated extinction water according to local official
regulations.
7. Handling and storage
Handling
Precautions for safety handling
Use only in well-ventilated areas. Do not inhale vapours/dust.
Precautions on protection against fire or explosion
Highly flammable
Storage
Storage spaces and containers
Keep the container tightly closed in a dry, cold, well-ventilated place.
Instructions on storage with other products
Do not store together with acids or oxidizing agents.
8. Exposure controls/personal protection
Exposure limit values
Permissible exposure limit (PEL)
500mg/m³
Permissible concentration limit (maximum)
1000mg/m³
In case of exposure, the substance absorbs through the skin significantly.
Safety Data Sheet
according to 1907/2006/EC, Article 31
Date of printing: 11/09/2013
Date of revision:
Page 3 of 5
Personal protective equipment
Respiratory protection: organic vapour respirator (filter A), ensure sufficient ventilation
Eye protection: protective glasses with side shields or face shield
Hand protection:
Use protective hand cream for the prevention.
Gloves against chemicals, made of butyl rubber or nitrile rubber – level 3 according to EN 374
In case of direct contact: Gloves material: Thickness of plastic: 0, 70 mm Breakthrough time: >480
min.
In case of sprinkling: Gloves material: Thickness of nitrile rubber: 0, 20 mm Breakthrough time: >30
min.
Skin protection (i.e. body protection): protective clothing, protective footwear
Other information: When using, do not drink, eat or smoke; after use, wash your hands with warm
water and soap, or treat with reparation cream. Do not wear the contaminated clothing again until it
has been washed.
9. Physical and chemical properties
General information
Physical state: liquid
Colour: colourless
Odour: strong, alcohol-like
Change of physical state
Boiling point/distillation range: 82,4 °C
Auto-ignition temperature: 399 °C
Flash point: 11,7 °C
Lower explosive level: 2,5 obj. %
Upper explosive level: 12,0 obj. %
pH (at 20 °C): 6,8 - 7,0
Density (at 20 °C): 0,78 - 0,79 g/cm³
10. Stability and reactivity
Conditions to avoid
Heat, flame and sparks.
Stable under normal conditions
Materials to avoid
Oxidizing agents, Aluminium, Paraffin
Hazardous decomposition products
Hazardous gases may be released if heated
11. Toxicological information
Acute toxicity
LC50/oral/rat= 5045 mg/kg
LC50/inhalant/8hour/rat = 12000 ppm
LD50/transdermal/rabbit = 12800 mg/kg
Irritation/corrosion effects
Irritation effects
12. Ecological information
Toxicity for aquatic organisms:
LC50, 96 hours, fish (mg/l)
Fathead minnows 9600
EC50, 48 hours, daphnia (mg/l)
1000
Degradability:
good
Bioaccumulation:
BCF: 0,5
Toxicity for other environments: toxicity No. for fish 2,1, bacterium 3,0, mammals 1
Safety Data Sheet
according to 1907/2006/EC, Article 31
Date of printing: 11/09/2013
Date of revision:
Page 4 of 5
13. Disposal considerations
Information on disposal
According to local and national regulations. Dispose of in accordance with the Act No. 223/2001 Coll.
On Wastes and Decree No. 284/2001 Coll. setting up a Waste catalogue.
Waste disposal number of waste from residues
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gasses in pressure containers and
discarded chemicals; laboratory chemicals consisting of or containing dangerous substances,
including mixtures of laboratory chemicals
Waste disposal number of waste from unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gasses in pressure containers and
discarded chemicals; laboratory chemicals consisting of or containing dangerous substances,
including mixtures of laboratory chemicals
Hazardous waste 160506
14. Transport information
Transport by road/rail (ADR/RID)
UN Number: 1993
Class ADR/RID: 3
Proper shipping label: Flammable liquid, N.O.S. (Propane-2-ol, Ethanol)
Packaging group ADR/RID: II
Transport by inland waterways
Not tested
Other usable information (Transport by inland waterways)
Transport by sea IMDG
UN Number: 1993
Class IMDG: 3
Marine pollutant: No
IMDG-packaging group: II
EmS: F-E, S-E*
Proper shipping label Flammable liquid, N.O.S. (Propane-2-ol, Ethanol)
Transport by air ICAO-TI and IATA-DGR
UN/ID number: 1993
Class ICAO/IATA-DGR: 3
ICAO-packaging group: III
Proper shipping label Flammable liquid, N.O.S. (Propane-2-ol, Ethanol)
These transport information apply to the whole packaging.
15. Regulatory information
Label
Hazard symbols: F – Highly flammable; F – Highly flammable; Xi - Irritant
F – Highly flammable; F – Highly flammable; Xi - Irritant
Hazardous components to be cited on the label
Contains: Propane-2-ol
R-phrases
11 Highly flammable
36 Irritating to eyes
67 Vapours may cause drowsiness and dizziness
S–phrases
02 Keep out of the reach of children.
07 Keep container tightly closed
16 Keep away from sources of ignition – No smoking.
Safety Data Sheet
according to 1907/2006/EC, Article 31
Date of printing: 11/09/2013
Date of revision:
Page 5 of 5
24/25 Avoid contact with skin/eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
46 If swallowed, seek medical advice immediately and show this container or label
GHS label
Signal word: danger
Pictograms: flame; exclamation mark
H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces – No smoking
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
EU Regulatory information
Classification according to directives EU 67/548/EEC or 1999/45/EC
The product is classified as dangerous according to Regulation EC no. 1272/2008. Working restriction:
Take into consideration directive 94/33/EC on the protection of young people at work.
Water danger class (D): 1 - low water contamination
Further instructions
Act No. 67/2010 Coll. on the conditions of introduction of chemical substances and chemical mixtures
to the market and on amending and supplementing certain acts of the Regulation EC No. 1272/2008
of the European Parliament and of the Council on classification, labelling and packaging of substances
and mixtures amending and repealing Directives 67/548/EEC and 1999/45/EC and amending and
supplementing Regulation (EC) No. 1907/2006.
16. Other information
Full text of R-phrases referred to in sections 2 and 3
11 Highly flammable
36 Irritating to eyes
67 Vapours may cause drowsiness and dizziness.
Full text of H-statements stated in sections 2 and 3
H225 Highly flammable liquid and vapour
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.