Safety Data Sheet according to 1907/2006/EC, Article 31 Date of printing: 12/09/2013 Date of revision: Page 1 of 5 1. Identification of the substance/mixture and company/undertaking Identification of the substance/mixture Isokor SW 950 ml, 1000 ml, 5000 ml Use of the substance/mixture Hydrophobic coating against dirt Manufacturer: ISOKOR Ltd Address: 976 34 Tajov 242, Slovakia Telephone: +421(0)903423582 E-mail: info@isokor.com Website: www.isokor.com Information department: +421(0)254774166 National Toxicological Information Centre at University Hospital in Bratislava and Faculty of Medicine in Bratislava, Clinic of Industrial Medicine and Toxicology, Limbová 5, 833 05 Bratislava, Slovakia 2. Hazards identification Classification Hazard symbols : F – Highly flammable, Xi - Irritant R-phrases: 11 Highly flammable 36 Irritating to eyes 67 Vapours may cause drowsiness and dizziness S-phrases: 2, 7, 16, 24-25, 26, 46 GHS: Classification: Flammable Liquid - Category 2 Serious eye damage/eye irritation – Category 2 Target Organ Systemic Toxicity - Single Exposure – Category 3 Hazard statements codes: H225 – Highly flammable liquid and vapour, H319 – Causes serious eye irritation, H336 – May cause drowsiness or dizziness Pictogram codes: GHS02, GHS07, Dgr. – Signal word: Danger 3. Composition/information on ingredients Chemical characteristics (of the mixture) Description: Modified hybrid materials dissolved in a solvent Contained hazardous substances EC-number 200-661-7 Label: Propan-2-ol Percentage: 82 – 94% CAS-number 67-63-0 Index number 603-117-00-0 Classification F, Xi R11-36-67 GHS classification: Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 For the full text of R- and H-phrases see section 16. 4. First aid measures General instructions Take off immediately all contaminated clothing. Inhalation Remove victim to fresh air. Skin contact Immediately rinse with plenty of water for at least 15 minutes. Take off immediately contaminated clothing. If skin irritation persists, seek medical help. Safety Data Sheet according to 1907/2006/EC, Article 31 Date of printing: 12/09/2013 Date of revision: Page 2 of 5 Eye contact Rinse opened eyes thoroughly for at least 15 minutes under running water. Consult a doctor. Ingestion Rinse mouth with water and drink plenty of water. Do not induce vomiting. Consult a doctor. Special instructions for physician Treat symptomatically. 5. Firefighting measures Suitable extinguishing media Foam, dry powder Special hazards arising from the substance or mixture itself, combustion products, resulting gases May produce hazardous toxic gases or fumes in case of fire Advice for firefighters Wear protective respirator with independent air supply in case of fire. Avoid contact with skin – keep a safe distance from the fire or wear appropriate protective clothing. Further instructions Dispose of combustion residues and contaminated extinction water according to local official regulations. 6. Accidental release measures Personal precautions Wear personal protective equipment. Environmental precautions Do not flush into surface water or sanitary sewer system. Methods for cleaning up Soak up with an inert absorbent material and dispose of as hazardous waste. Further instructions Dispose of combustion residues and contaminated extinction water according to local official regulations. 7. Handling and storage Handling Precautions on safety handling Use only in well-ventilated areas. Do not inhale vapours/dust. Precautions on protection against fire or explosion Highly flammable Storage Storage spaces and containers Keep the container tightly closed in a cool, dry, well-ventilated place. Instructions on storage with other products Do not store with acids or oxidizing agents. 8. Exposure controls/personal protection Exposure limit values Permissible exposure limit (PEL) 500mg/m³ Ceiling PEL 1000mg/m³ Conversion factor ppm 0.407 In case of exposure, the substance absorbs through the skin significantly. Personal protective equipment Respiratory protection: organic vapour respirator (type A), ensure adequate ventilation Eye protection: protective glasses with side shields or face shield Hand protection: Preventive skin protection by using protective hand cream. Safety Data Sheet according to 1907/2006/EC, Article 31 Date of printing: 12/09/2013 Date of revision: Page 3 of 5 Gloves against chemicals, made of butyl caoutchouc or nitril caoutchouc – level 3 according to EN 374 In case of direct contact: Gloves material: Thickness of plastic: 0,70 mm Breakthrough time: >480 min. In case of sprinkling: Gloves material: Thickness of nitril caoutchouc: 0,20 mm Breakthrough time: >30 min. Skin protection (i.e. body protection): protective clothing, protective footwear Other information: When using, do not drink, eat or smoke; after use, wash your hands with warm water and soap, or treat with reparation cream. Do not wear the contaminated clothing again until it has been washed. 9. Physical and chemical properties General information Physical state: liquid Colour: colourless Odour: strong, alcohol-like Change of physical state Melting point/melting rate: -89,5 °C Boiling point/distillation range: 82,4 °C Autoignition temperature: 399 °C Flash point: 11,7 °C Lower explosive limit: 2,5 vol % Upper explosive limit: 12,0 vol % Vapour pressure(at 20 °C): 43 hPa Density (at 20 °C): 0,80-0,81 g/cm³ 10. Stability and reactivity Conditions to avoid Heat, flames and sparks. Stable under normal conditions Incompatible materials Oxidizing agents, Aluminium, Paraffin Hazardous decomposition products Hazardous gases may be released if heated 11. Toxicological information Acute toxicity LC50/oral/rat= 5045 mg/kg LC50/inhalation/8h/rat= 12000 ppm LD50/transdermal/rabbit = 12800 mg/kg Irritation/corrosion effects Irritation effects 12. Ecological information Toxicity for aquatic organisms: LC50, 96 hours, fish (mg/l) Fathead minnows 9600 EC50, 48 hours, daphnia (mg/l) 1000 Degradability: good Bioaccumulation: BCF: 0,5 Toxicity for other environments: toxicity number for fish 2,1; bacteria 3,0, mammals 1 Safety Data Sheet according to 1907/2006/EC, Article 31 Date of printing: 12/09/2013 Date of revision: Page 4 of 5 13. Disposal considerations Information on disposal According to local and national regulations. Dispose of in accordance with the Act No. 223/2001 Coll. on wastes and Decree No. 284/2001 Coll. setting up a Waste catalogue. Waste disposal number of waste from residues 160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gasses in pressure containers and discarded chemicals; laboratory chemicals consisting of or containing dangerous substances, including mixtures of laboratory chemicals Waste disposal number of waste from unused products 160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gasses in pressure containers and discarded chemicals; laboratory chemicals consisting of or containing dangerous substances, including mixtures of laboratory chemicals Hazardous waste. 160506 14. Transport information Transport by road/rail (ADR/RID) UN number: 1219 Class ADR/RID: 3 Proper shipping name Isopropanol Packing group ADR/RID: II Transport by inland waterways Not tested Other usable information (Transport by inland waterways) Transport by sea IMDG UN number: 1219 Class IMDG: 3 Marine pollutant: -IMDG-packing group: II EmS: F-E, S-D Proper shipping name Isopropanol Transport by air ICAO-TI and IATA-DGR UN/ID number: 1219 Class ICAO/IATA-DGR: 3 ICAO-packing group: II Isopropanol Proper shipping name Isopropanol These transport information apply to the whole packaging. 15. Regulatory information Label Hazard symbols: F – Highly flammable; F – Highly flammable; Xi - Irritant F – Highly flammable F – Highly flammable, Xi - Irritant Hazardous components to be cited on the label Contains: Propan-2-ol R - phrases 11 Highly flammable 36 Irritating to eyes 67 Vapours may cause drowsiness and dizziness S - phrases 02 Keep out of the reach of children. 07 Keep container tightly closed Safety Data Sheet according to 1907/2006/EC, Article 31 Date of printing: 12/09/2013 Date of revision: Page 5 of 5 16 Keep away from sources of ignition – No smoking. 24/25 Avoid contact with skin/eyes. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 46 If swallowed, seek medical advice immediately and show this container or label GHS label Signal word: danger Pictograms: flame; exclamation mark H225 Highly flammable liquid and vapour H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces – No smoking P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/fume/gas/mist/vapours/spray P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. EU Regulatory information Classification according to directives EU 67/548/EEC or 1999/45/EC The product is classified as dangerous according to Regulation EC no. 1272/2008. Working restriction: Take into consideration directive 94/33/EC on the protection of young people at work. Water danger class (D): 1 - low water contamination Further instructions Act No. 67/2010 Coll. on the conditions of introduction of chemical substances and chemical mixtures to the market and on amending and supplementing certain acts of the Regulation EC No. 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures amending and repealing Directives 67/548/EEC and 1999/45/EC and amending Regulation (EC) No. 1907/2006. 16. Other information Full text of R-phrases referred to in sections 2 and 3 11 Highly flammable 36 Irritating to eyes 67 Vapours may cause drowsiness and dizziness. Full text of H-statements stated in sections 2 and 3 H225 Highly flammable liquid and vapour H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.