Name:____________________________________________ Pd.:_____ Modern Atomic Theory Homework #1 SHOW ALL WORK! 1. What is the wavelength of radiation whose frequency is 4.621014 1/s? What is the energy? λ=? ν = 4.62x1014 1/s ΔE = ? c=λν ΔE = h*c / λ 8 14 (3x10 m/s) = λ (4.62x10 1/s) ΔE = (6.626x10-34 J *s)(3x108 m/s) / 6.49x10-7 m λ = 6.49 x 10-7 m ΔE = 3.06 x 10-19J 2. What is the frequency of radiation whose wavelength is 180 nm? What is the energy? λ= 180nm (1m / 1x109nm) = 1.8 x 10-7m ν = ? ΔE = ? c=λν ΔE = h*c / λ (3x108 m/s) = (1.8x10-7m) ν ΔE = (6.626x10-34 J *s)(3x108 m/s) / 1.8x10-7 m ν = 1.7 x 1015 1/s ΔE = 1.1 x 10-18J 3. A neon light emits radiation of 616 nm wavelength. What is the frequency of this radiation? What is the energy? λ= 616nm (1m / 1x109nm) = 6.16 x 10-7m ν = ? ΔE = ? c=λν ΔE = h*c / λ 8 -7 (3x10 m/s) = (6.16x10 m) ν ΔE = (6.626x10-34 J *s)(3x108 m/s) / 6.16x10-7 m 14 ν = 4.87 x 10 1/s ΔE = 3.23 x 10-19J Write the electron configuration for the following elements. 4. Na 1s22s22p63s1 5. Cl 1s22s22p63s23p5 6. Sn 1s22s22p63s23p64s23d104p65s24d105p2 Write the orbital diagram for the following elements. 7. Ca 1s↑↓ 2s↑↓ 2p ↑↓ ↑↓ ↑↓ 3s↑↓ 3p ↑↓ ↑↓ ↑↓4s↑↓ 8. Fe 1s↑↓ 2s↑↓ 2p ↑↓ ↑↓ ↑↓ 3s↑↓ 3p ↑↓ ↑↓ ↑↓4s↑↓ 3d↑↓ ↑ ↑ ↑ ↑ 9. Pb 1s↑↓ 2s↑↓ 2p ↑↓ ↑↓ ↑↓ 3s↑↓ 3p ↑↓ ↑↓ ↑↓4s↑↓ 3d↑↓ ↑↓ ↑↓ ↑↓ ↑↓ 4p ↑↓ ↑↓ ↑↓ 5s↑↓ 4d ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ 5p ↑↓ ↑↓ ↑↓ 6s↑↓ 4f ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ 5d↑↓ ↑↓ ↑↓ ↑↓ ↑↓ 6p↑↓ Name:____________________________________________ Pd.:_____ Write the noble gas configurations for the following elements. 10. Fluorine [He] 2s22p5 11. Strontium [Kr] 5s2 12. Tungsten [Xe] 6s24f145d4 13. Mercury [Xe] 6s24f145d10 Answer the following in complete sentences. 14. The element sulfur has an electron configuration of 1s22s22p63s23p4. a. What does the superscript 6 refer to? # of electrons b. What does the letter s refer to? sublevel c. What does the coefficient 3 refer to? Principal energy level 15. What is the Pauli Exclusion Principle? Why does the name include the word exclusion? Each orbital contains electrons with opposite spins, excludes 2 up spins and 2 down spins 16. Identify the element with each of the following electron configurations. a. 1s22s22p2? carbon b. 1s22s22p63s23p1? aluminum c. 1s22s22p63s23p64s23d104p65s24d9? silver 17. What element is represented by [Ne] 3s23p6? What does it have in common with neon? Argon, both have noble gases, share core electron configurations 18. Tell the valence shell and the number of valence electrons for the following elements. a. Calcium valence shell: 4 electrons, valence electrons: 2 electrons b. Radon valence shell: 6 electrons, valence electrons: 8 electrons c. Phosphorus valence shell: 3 electrons, valence electrons: 5 electrons d. Sulfur valence shell: 3 electrons, valence electrons: 6 electrons e. Magnesium valence shell: 3 electrons, valence electrons: 2 electrons