Pre AP Compound Practice Exam 2013 Complete the following free response questions. 1. List four properties of ionic compounds: hard, brittle, high melting point, nonconductor, crystalline solid at room temp. 2. How can you identify a binary molecular compound from the name/formula? 2 nonmetals, prefixes 3. Why is it important to use roman numerals like II or IV when naming an ionic compound with a transition metal? To know the charge for the formula 4. Describe the actions of the valance electrons in metallic bonds. Free floating sea of electrons 5. List three properties of metals that is a direct result of metallic bonding. Shiny, conductor, malleable and ductile 6. In a molecular bond, electrons are shared while in an ionic bond electrons are _lost_ or _gained_. 7. Non-metals tend to _gain_ electrons and become _anions (negative ions)_ in ionic bonding. 8. Atoms want a full outer energy level. For most atoms, this is _8_ electrons which is why this is called the _octet_ rule. 9. Give the molar mass for the following compounds. a. H2SO4 b. C2H2 c. Ba(OH)2 a) 2H(1.0g) + 1S(32.1g) + 4O(16.0)= 98.1 g H2SO4 b) 2C (12.0g) + 2H (1.0g) = 26.0 g C2H2 c) 1Ba (137 g) + 2O (16 g) + 2H (1.0 g)= 171 g Ba(OH)2 10. Draw an electron dot diagram to predict the type of bonding and the number of bonds between two atoms of nitrogen in the diatomic molecule N2. :N=N: covalent triple bonds 11. Name the following compounds: 1. Li2S lithium sulfide 6. N7S8 heptanitrogen octasulfide 2. CO3 carbon trioxide 7. PbO lead(II) oxide 3. CuBr copper(I) bromide 4. Cu2O copper 5. Na2SO4 (I) oxide 8. FeBr3 Iron(III) bromide 9. Ba(CN)2 Barium cyanide sodium sulfate 12. Write the formulas for the following compounds: 6. lithium carbonate 7. potassium cyanide Li2CO3 KCN 5. cupric sulfate CuSO4 6. dihydrogen monoxide H2O 8. tin (IV) chlorite Sn(ClO2)4 7. Lead (II) iodide PbI2 9. beryllium oxide BeO 8. ammonium sulfate (NH4)2SO4 13. What is meant by the term polar? How can you tell if a bond it polar covalent, nonpolar covalent or ionic? Means has electric poles (+ or negative ends), bond polarity by electronegativity differences of atoms (ionic >1.81, nonpolar covalent <0.41, Polar covalent between these 14. Calculate the mass of 1.25 moles of LiCl(42.4 g LiCl/1 mol LiCl)= 53.0 g LiCl 2.57 x 1023 molecules of H2O (18.0 g H2O/6.02 X 1023 Molecules)= 7.68 g H2O 15. Find the % oxygen by mass in water. % O = 16 g O/18 g H2O X 100% 2H (1.0 g) + 1O (16 g) = 18 g H2O = 88.9% O 16. If a compound consists of 38.7 % C, 16.1 % H and 45.2 % N, what is the empirical formula? 38.7 g C (1 mol C/ 12 g C) = 3.225 mol C C 3.225/3.225 16.1 g H (1 mol H/ 1 g H) = 16.1 mol H H 16.1/3.225 1 mol N 45.2 g N ( / 14 g N) = 3.229 mol N N3.2259/3.225 C H5N Complete the following multiple choice questions by choosing the best answer. 17. There are _____ paired and _____ unpaired electrons in the Lewis symbol for a phosphorus atom. 2 paired (1 pair) and 3 unpaired 18. Based on the octet rule, magnesium most likely forms a _____ ion. a. Mg2+ 19. Which ion below has a noble gas electron configuration? b. Be2+ 20. Which of the following would have to gain two electrons in order to achieve a noble gas electron configuration? O Sr Na Se Br d. O & Se 21. Elements from opposite sides of the periodic table tend to form ____________. b. ionic compounds 22. How many single covalent bonds must a silicon atom form to have a complete octet in its valence shell? b. 4 23. Compounds consisting entirely of nonmetals ____________. d. are molecular 24. A double bond consists of _____ pairs of electrons shared between two atoms. b. 2 25. What is the maximum number of double bonds that a hydrogen atom can form? a. 0 26. The central atom in _____ violates the octet rule. a. ClF3 27. The Lewis structure of the CO2 molecule has ____ double bond(s). c. 2 28. The basis of the VSEPR model of molecular bonding is ____________. d. electron pairs in the valence shell of an atom will arrange themselves so as to minimize repulsions 29. The electron-domain geometry of _____ is tetrahedral. a. CBr4 (tetrahedral) b. PH3 (trigonal pyramidal—from tetrahedral) c. CCl2Br2 (tetrahedral) d. XeF4 (exception to octet rule—square planar) e. all of these except XeF4 30. The molecular geometry of the SF2 molecule is __________. b. bent Fill in the missing name or formula: Name Formula calcium chloride ________CaCl2_____________ barium nitride ______Ba3 N2______________ silver oxide ____Ag2O_____________ iron(II) oxide _____FeO______________ lithium sulfate ______Li2SO4____________ barium nitrate ______Ba(NO3)2_________ dinitrogen pentoxide _______N2O5_________ calcium acetate ______Ca(C2H3O2)2_____ water ______H2O______ ammonia _______NH3________ magnesium sulfate ______MgSO4__________ ___calcium phosphide_________ Ca3P2 __carbon tetrabromide__________ CBr4 __potassium chloride_________ KCl _____sodium carbonate______ Na2CO3 _____aluminum oxide _________ Al2O3 _____iron (II) bromide_________ FeBr2 _____Tin (IV) chlorate______ Sn(ClO3)4 _____nitrogen dioxide_______ NO2 ______silver bromide_______ AgBr ________sodium nitrate_______ NaNO3 ______copper (II) chloride____ CuCl2 Find the molar mass of the following compounds: lithium sulfate Li2SO4 2 Li(6.94g)+ 1 S(32.1g) + 4O(16g)=109.98g barium hydroxide Ba(OH)2 Ba (137g)+ 2O(16g)+ 2H(1 g)= 171 g magnesium acetate Mg(C2H3O2)2 1 Mg(24.3g)+ 4C(12g)+6H(1g)+ 4 O(16g)= 142.3 g