WC-11: WATER MOLECULES AND TEMPERATURE MATERIALS: 5 8OZ. CLEAR PLASTIC CUPS FOR EACH PAIR OF CHILDREN. ONE GALLON OF ROOM TEMPERATURE WATER ONE HALF GALLON OF HOT WATER ENOUGH THERMOMETERS SO EACH PAIR OF CHILDREN HAS TWO SPONGE (FOR CLEANING SPILLED WATER) WATER TRAY THERMOS (FOR ICE) SPRAY BOTTLE MATERIALS YOU NEED TO BRING FROM HOME: BAG OF ICE HOT WATER COLORED PENCILS **MAKE SURE ALL THE MATERIALS YOU NEED ARE HERE! IF THEY ARE NOT, THEN CHECK THE EXTRA SUPPLIES IN THE BOX IN THE MATERIALS ROOM PREPARE AT HOME: • One 8-oz clear plastic cup is filled with water just to the top of the masking tape line and then frozen. The other marked cup is left empty, you fill with water later in the classroom. • Fill a glass jar to the very top with water, screw the lid on tightly, and place in a heavy plastic ziplock bag. Freeze it over night. After freezing, the lid should be bent. If the jar breaks, show the children the broken glass still in the plastic bag.Transport the plastic cup with ice, the jar with frozen water (still in the bag), and some ice cubes to class in the cooler. Water Molecules & Temperature WC – 11 page 1 WATER MOLECULES AND TEMPERATURE WC – 11 Summer 2000 Jane Hall/ Ralph Johnson OBJECTIVES: To study the water molecule and the three physical phases of water and to learn about atoms and molecules GRADE LEVELS: 3 – 6 FOCUS WORDS: Hydrogen, oxygen, atom, molecule, element, crystal, cohesion, adhesion, H2O latent heat, standard atmosphere (pressure of 76 cm of mercury and 15 ° C) BACKGROUND INFORMATION: Heat is a form of energy and is usually measured in calories. One calorie is the quantity of heat that will rise one gram of water one degree Celsius. (The energy in food is called calories, but those calories are actually kilo-calories.) It is heat energy that runs our automobiles and is even responsible for our own physical strength. The sun radiates its heat to the earth to supply the energy of life. Temperature is a measure of the intensity of heat. It is measured in degrees Celsius. A sewing needle that is red hot and has a temperature is 550° C contains less heat (calories) than a bucket of ice at 0° C. Heat can be added to water without raising its temperature. This happens when ice melts and when water vaporizes. This phenomenon is called latent heat. When water freezes the heat given up is called the latent heat of fusion. It requires 80 calories to freeze/or thaw one gram of water. When water boils we have the latent heat of vaporization, and it takes 539 calories to vaporize one gram of water at standard pressure. When it condenses it gives back that 539 calories. Water cannot change state, from ice to liquid or from liquid to vapor, without the addition or removal of heat. When steam condenses to water, and when water freezes to ice, the heat is given back. While water is boiling on the stove and the burner is on full, the water will remain at 100° C until it is ALL evaporated. When ice is melting in a pan on the stove the temperature will remain at 0° C until ALL the ice is melted. If you could take a drop of water and divide it up until you have the smallest possible water particle, you would have one molecule of water. If you continue to break the molecule into smaller pieces it would no longer be water. You would end up with 2 pieces of hydrogen and 1 piece of oxygen. These pieces are called atoms. Now, if you put the two pieces or hydrogen and one piece of oxygen back together again, you have your water molecule back. Of course, we cannot do this experiment because a molecule is so small it would take millions and millions of them to make a drop big enough to see. Water is a molecule, made up by the mutual attraction of three atoms; two atoms of hydrogen and one of oxygen. (Chemically it is written as H2O.) Water Molecules & Temperature WC – 11 page 2 Water is our natural air conditioner. It stores heat in the summer and releases it in the winter (latent heat). Frozen water, ice, floats on liquid water. A layer of ice on the water's surface is a good heat insulator. It tends to trap the heat in the water below it. If this did not happen the entire supply of water would freeze to the bottom of the ocean, and there could be no life on earth. The ocean is our reservoir of the earth's most precious commodity, water. Water moves from the ocean to land through the air. There it falls as rain to nourish all terrestrial life. Heat from the sun warms the oceans. When the surface becomes warm enough the energy from the sun evaporates the water into a vapor where it rises into the air and is carried over land by the wind. The vapor rises, and as it does it chills and gives up its latent heat. The rain supplies the flowing streams and rivers, and fills lakes. The most common state of water is the liquid state. Liquid water is held together by the mutual attraction of its molecules. This attraction is called cohesion. Each molecule of water in the liquid state is free to move around freely; this is true of molecules in any liquid. In their random motion the molecules bump into each other and knock each other around. As water is heated, the molecules move faster, and thus bump harder. Those molecules near the surface might be knocked so hard that they are knocked right out of the water and into the air. There they float freely, and move with the wind. As the temperature rises more, the molecules bump so hard that they overcome their cohesion and separate into bubbles of vapor (steam) which rises to the surface and escapes into the air. When water molecules are in the air, they are in a gaseous state and they mix with all the other gasses in the atmosphere. As the vapor cools the molecules can again cohere to form drops. When the drops get big enough they fall back to the earth as rain. While they are growing into rain drops we can see them as clouds. BACKGROUND INFORMATION:(continued) On the earth's surface if the temperature continues to drop, the movement of water molecules in the liquid state move slower and get closer together. In a body of water the cooler water becomes more dense and sinks to the bottom allowing the warmer, less dense water to rise to the surface. When all of the liquid water in an area has reached the same cold temperature. and heat is still being lost, the molecules will start to lock themselves into crystals of ice. In doing this they spread apart and are less dense than the liquid. They then float to the surface to form a layer of ice. When the ice gets thick enough we can go skating on the surface, and the fish under the ice can continue to swim. Water Molecules & Temperature WC – 11 page 3 THREE PHASES OF WATER — VAPOR, LIQUID & ICE H Hydrogen ( H2) H Oxygen (O2) O Water (H2 O) Other molecules in the air Water vapor in the air shown in this balloon Water surface Interlocking Crystals of Ice Water molecules escaping cup by evaporation Water molecules in a cup Notice that the molecules as shown here area million or more times larger than they actually are. Water Molecules & Temperature WC – 11 page 4 ACTIVITIES: TIME REQUIRED: 20 minutes Water is everywhere. It is in our oceans, our lakes and streams, in the polar ice caps and mountain glacier, and it is in the air. Water is a liquid, it is a solid, and it is a gas (called vapor) depending on its temperature. Can you imagine how water looks if you could see its smallest form? How small can water get and you can still see it? What if we could pretend that you could see the smallest form of water – a molecule – how would that look? ASK: RESPONSE: What is an element? An element is a substance which cannot be broken up into a substance different from itself. It is made up of one type of atom only. ASK: What is an atom? RESPONSE: An atom is the smallest whole particle of matter that you can have. ASK: What is an element? RESPONSE: An element is a substance that consists of only one type of atom. ASK: What is a molecule? RESPONSE: When atoms of different types are attracted together to form a substance, different from the element of any of those atoms, the smallest particle of that substance is a molecule. ASK: What is water? RESPONSE: Oxygen is an element and so is hydrogen. Each are gasses in their natural state. When these two elements combine, by the oxygen atom attracting two hydrogen atoms, they form one molecule of water. EXPLAIN: Scientists have shorthand ways of identifying chemical substances. They identify water with the symbol "H2O." This symbol says that there are 2 hydrogen atoms (H2) with 1 oxygen atom (O) to form 1 molecule of water, H2O. SHOW The models of water molecules. Can the children figure out how many atoms of hydrogen and oxygen make up the molecule? Are the molecules attracted to eachother? COLOR THE MOLECULE EXERCISE CAN BE USED WITH YOUNG CHILDREN (3RD ): DO: Give each child a copy of the "Color the Water Molecule" sheet. Also give them each one blue and one yellow crayon DO: Have the children color the two hydrogen atoms, in the upper diagram on the right hand side, yellow, and the oxygen atom blue. EXPLAIN: The two hydrogen atoms have not yet combined with the oxygen atom. DO: Have the children color the two hydrogen atoms in the bottom diagram yellow, and then color the entire molecule blue. EXPLAIN: The three atoms have now joined to form a molecule of water. The change of color of the hydrogen atoms from yellow to green indicates that they are no longer free atoms, but are now a part of the water molecule. ASK: Water's natural state is liquid; what is a liquid? RESPONSE: A substance that is neither solid nor gaseous. See the diagram of "Water in a Cup” ASK: What keeps the molecules in the cup? RESPONSE: The mutual attraction of each molecule to all of its neighbors. ASK: Can the molecules move around among the other molecules in the liquid? RESPONSE: Yes. That is what makes a liquid flow. Water Molecules & Temperature WC – 11 page 5 ASK: RESPONSE: ASK: RESPONSE: ASK: RESPONSE: ASK: RESPONSE: ASK: RESPONSE: ASK: RESPONSE: ASK: RESPONSE: DO: ASK: RESPONSE: ASK: RESPONSE: ASK: RESPONSE: ASK: RESPONSE: DO: EXPLAIN: ASK: RESPONSE: ASK: RESPONSE: DO: ASK: RESPONSE: ASK: What is steam? Steam is water in a gaseous form, also called water vapor. What is a gas? A gas is a substance that will fill the whole container no matter how little or how much of the substance there is. See the diagram of the balloon filled with gasses. Do the molecules in steam have an attraction for each other? Yes. Then why do they not gather together into a liquid? Because they have too much heat energy. They bump together so hard that they bounce apart. What happens when the molecules of a water vapor lose some of their energy? Their mutual attraction can bring them together to form drops of liquid water. What happens when those drops get big enough? It rains. What is a solid? A solid is a piece of matter that does not need a container to hold it together. Remove some ice from the cooler, place on a tray or paper towel Is ice a solid? Yes. Is ice water? Yes. It is water in the solid state. What is a crystal? A group of molecules that lock themselves together in some geometric form. See the diagram of crystals of water. Why does ice float in liquid water? Ask a child to place some ice in a cup of water. When water forms into the crystal, ice, the molecule must spread apart. This makes the ice less dense than the liquid water. A level container of ice weighs less than the same size level container of liquid water, so it must float. Take the plastic cup of ice with the masking tape band around it to display to the class. Have the other plastic cup (with masking tape) filled to the top of the masking tape with liquid water. Last night I filled this just to the top of the masking tape, then I put it in my freezer until I put it in the cooler to bring to class. Does the cup seem fuller now? Compare to the cup with liquid water. The molecules of ice are farther apart than they were when it was water. What would happen if I filled a glass jar full of water, screwed the lid on tight, and then put it in the freezer until it was frozen solid? The ice would take up more space in the jar, probably causing the top to bend to make more room for itself. If it could not find enough space by bending the lid, it could break the glass. Take the plastic bag containing the glass jar out of the cooler and have the children examine it. Even if the jar is not broken, do not remove it from the bag. Why is the jar in the bag? To catch the glass if it breaks. Why do I not take the unbroken jar out of the bag? Water Molecules & Temperature WC – 11 page 6 RESPONSE: ASK: RESPONSE: ASK: Because the glass is under a heavy strain by the expanding ice, and it might break with handling. What would happen if a rock on a mountain had a crack in it that was full of water and then the weather got so cold that the water froze? The freezing ice would have enough strength to break the rock. This is a part of the erosion process that wears down the mountains. What would happen if ice was not lighter than liquid water, but heavier? Imagine ice cubes, icebergs, ice on top of ponds, lakes or streams. MAKE SURE TO PUT THE JAR OF ICE WITH LID AND ICE IN CUP WITH MASKING TAPE BACK IN THE COOLER IMMEDIATELY AFTER SHOWING THEM. THIS WILL ENSURE THAT THEY STAY FROZEN BETWEEN GROUP ROTATIONS. Water Molecules & Temperature WC – 11 page 7 COLOR THE WAT ER MOLECULE HYDROGEN HYDROGEN OXYGEN MOLECULE OF WATER ( H 2 O) H H Color the hydrogen atoms yellow and the oxygen atoms blue ( H 2 O) Color the 2 hydrogen atoms yellow, then color all 3 atoms blue. The resulting green represents how the combining of the 3 atoms results in a molecule that is not oxygen or hydrogen, but a different substance, water. Water Molecules & Temperature WC – 11 page 8