ENERGY RECOVERY FROM BIOGAS GENERATED FROM FISH PROCESSING PLANTS EFFLUENTS Author(s): Sindra Lutchmee Summoogum, Research Centre for Energy, University of Newcastle, Australia Vikram Seebaluck, University of Mauritius Abstract This article reveals the potentials and opportunities of methane recovery from biogas generated from effluent wastewater in fish processing plants for use as an energy product. It focuses on a commercial scale tuna processing factory whereby the methane gas recovered could be potentially used to satisfy part of the internal energy requirement of the plant, thereby displacing significant amount of heavy fuel oil. Indeed, methane gas is a combustible that can be converted to other energy forms and can be used as a fuel for steam production, electricity generation, in spark-ignition engines or for cooking purposes. In this study, three potential applications were considered namely heat and steam production, electricity generation, and compression and liquefaction of the gas for alternative utilizations such as a fuel for vehicle. Biogas is primarily composed of methane and carbon dioxide but its composition depends on the type of material fermented, the design and efficiency of the anaerobic reactor. Typical values of methane (CH4) and carbon dioxide (CO2) lie in the range of 55-65 % and 35-45 % respectively. Hydrogen sulphide (H2S) is usually reported in ppm and varies significantly depending mostly on the substrate. The tuna processing plant, where the study was conducted, had a maximum flow rate of 74.6 m3/hr of biogas derived from its wastewater having a maximum chemical oxygen demand of 4080 kg/day. The biogas generated was analyzed and found to have an average concentration of 63.5 % methane, 16.7 % carbon dioxide, 1.9 % oxygen and 17.9 % of other gases which contained 367 ppm carbon monoxide and 2500 ppm hydrogen sulphide. The first scenario, methane recovery for heat and steam production for the internal use of the plant, necessitated the existing two boilers of 10 tonnes steam/hr in the plant to be revamped to accommodate gas burning in the boiler house. This required the rotary burner to be retrofitted to a 669 kW dual burner with an increase in capacity of the forced draft fan from 23 W to 12 kW. The usual arrangement is to have a fuel oil supply available on site, and to fire it in the boiler when gas is not available. Due to the lower calorific value of biogas (28.89 MJ/kg, equivalent to 26 MJ/ m3) compared with heavy fuel oil (40.7 MJ/kg), 680 kg/hr of biogas was required to displace the 563.6 kg/hr of HFO for the production of 10 tonnes/hr of steam. However, the maximum flow rate of biogas that could be produced was 67.1 kg/hr (74.6 m3/hr) such that the percentage of HFO that could be displaced by biogas was found to be 9.9 %. The capital investment needed for this set-up was around 22 million MUR which could be paid off in 5.05 years. Moreover, a net present value of around 29 million MUR and an internal rate of return (31.4 %) greater than the discount rate (10 %) were obtained. Based on these findings, it was suggested that the fish processing plant could implement this set-up in the short term given that this option was technically and economically feasible. In the other proposed two scenarios for energy recovery from biogas, hydrogen sulphide gas needed to be removed to prevent formation of sulphuric acid, given that it has a high tendency for causing equipment corrosion. A 15m 3 biological filter was proposed to be used which could achieve a 99 % H2S reduction, thus decreasing its concentration from 2500 ppm to a value as low as 10 ppm. The resulting biogas could then be combusted with an air to fuel ratio of 100:1 in an open gas turbine. The turbine and thermal efficiency were found to be 85 % and 31.4 % respectively, with an electricity generation potential of 0.38 MWh of electricity. For this set-up, a total capital investment of 75 million MUR was required with an estimated unit production cost of around Rs 3/kWh. In Austria, a similar estimated unit production cost of around Rs 4/kWh was obtained (€0.103/kWh). A higher investment was required compared to the first scenario and this was due to the additional cost of the desulphurization unit and the gas turbine. However, electricity generation from biogas was found to be the second best option for energy recovery from biogas. The breakeven cost of unit production of electricity was found to be around Rs 2/kWh which could be achieved if appropriate measures are adopted to optimise the biogas plant. For the liquefaction process, further purification was essential and carbon dioxide (CO 2) was proposed to be eliminated by water scrubbing technique. Subsequently, the sweet biogas could be compressed and liquefied from 824.3 m3/hr to 3.3 m3/hr at a pressure of 250 bars and a temperature of -161°C. Based on a cost benefit analysis, a capital investment of 181 million MUR and an exorbitant unit product cost of Rs 22,615/ m 3, compared to a cost price of Rs 890/ m 3 to Rs 1373/m3 in the United States. Hence, this option was not found to be appropriate at current time. In light of this study, it was found that biogas derived from fish processing plant effluents could be used for energy recovery either as steam or electricity. A number of other substrates exist where biogas could be derived such as oats, wheat, and barley. In Mauritius, potential sources where biogas could also be tapped are for instance the existing breweries where the by-product obtained from the anaerobic digestion of the wastewater, rich in organic matter, could be recovered for steam or electricity production. Application of such techniques and strategies for energy recovery could help in reducing the country’s reliance on imported fossil fuels and at the same time improve the production cost and competitiveness of product manufactured. Keywords: Fish processing plant, biogas, methane, energy.