Číslo:
Imprint date: 03. 2005
MATERIAL SAFETY DATA SHEET in compliance with EK a EP č.
453/2010
Revision date: 08/2008
03/2011
Page 1 of 5
1: Identification of the substance and its producer
1.1
Product name: STOP SOLUTION
1.2 Approved use: Component of diagnostic kit ELISA-VIDITEST
1.3. Identification of the Safety data sheet editor/producer:
VIDIA s. r. o., Nad Safinou II č. 365, Vestec, 252 42 Jesenice u Prahy, Czech
Republic
Tel.: 0420 251 060 565
Fax:
Internet http:// www.vidia.cz
E-mail: konecny@vidia.cz
Emergency information: – Toxicological Informative Centre ČR
Na Bojišti 1, 128 08 Praha 2, tel.:+420 224 915 402;+420 224 914 575
2: Hazards identification
2.1 Hazard identificator: Xi, Irritating to eyes and skin, R 36/38
2.2 Label: Xi
irritating
R phrases: R36/38 irritating to eyes and skin
S phrases: S 24/25 Avoid contact with skin or eyes
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S27/28: After contact with skin take off immediately all contaminated clothing, and wash
immediately with plenty of water and soap.
Classification in CLP/GHS system
Eye Irrit. 2 H319 Causes serious eye irritation
Skin. Irrit. 2 H315 Causes skin irritation
Signal word: warning
2.3 Other hazards: None
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3: Composition and information on the ingredients
3.1 Substances – not refer
3.2 Mixtures:
EC number
CAS number
Index. number
Chemical nomenclature
Classification
CLP classification
231-639-5
7664-93-9
016-020-00-8
Sulfuric acid
C; R35
Skin Corr. 1A H314 GHS05; Dgr
Full text of R and H phrases in Paragraph 16
4: First aid measeures content (%)
5,3
4.1 Description of first aid measure
Inhalation: If inhaled, remove to fresh air, loosen a clothing. Seek medical advice
if needed. Show the product label or this Safety data sheet to the
physician.
Skin contact: After contact with skin take off immediately all contaminated clothing,
and wash immediately with plenty of water. Seek medical advice if
needed.
Eye contact: In case of contact with eyes, rinse immediately with plenty of water for
at least 20 minutes with open lid. Protect uninjured eye .Do not
neutralize. Remove contact lenses if any . Seek medical advice.
Ingestion: Flush mouth with plenty of water (do not swallow). Do not atempt to
neutralize or to provoke womitting. Seek medical advice immediately.
4.2 Most important delayed symptoms: not known. Irritation obviously disappear without
any sequelae.
4.3 Emergency medical care and special medical assistance: In case of persistent
discomfort seek medical advice.
5: Fire- fighting measures
5.1 Suitable extinguish media : the product is not combustible
5.2 Special exposure hazards: The product may cause local irritation, danger when eye is
contaminated: use appropriate protective tools.
5.3 Instructions for fire-fighters: No special instructions
6: Accidental release measures
6.1 Personal precautions, protective tools and emergency plan: use personal protective
tools: respirator with acid-protective filter, protective clothing and shoes, rubber
gloves.
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6.2 Environmental protective measures: not required
6.3 Methods and material for escape restriction and cleaning: Small spillages absorb with
inert, non-combustible material. Collect spillage in containers, seal securely and
deliver for disposal according to local regulations. Wash spillage site well with water
and detergent, be aware of the potential for surfaces to become slippery. Containers
with collected spillage must be properly labelled with correct contents and hazard
symbol. Dispose of as hazardous waste. Wash thoroughly after dealing with a spillage.
6.4 Other paragraph reference : none
7: Handling and storage
7.1 Do use personal protective tools. Comply with personal hygiene measures – prevent
inhalation, eye or skin contact and clothing contamination. Hamper long time or
repeated exposition.
7.2 Storage precautions: prevent contact with alkaline substances
7.3 Specific final usage: see Paragraph 1
8: Exposure control / personal protection
8.1 Control parameters (according to local authority instructions)
PEL mg.m
-3 NPK mg.m
-3
Sulfuric acid 1 2 re-counted to sulfur trioxide
DNEL and PNEC values at the time of this Safety data sheet edition were not
known
8.2 Exposure control: avoid frequent or long time contact with skin. Hands protection using rubber gloves. Eyes protection using protective glasses.
9: Physical and chemical properties
9.1 Basic information a) appearance: colourless liquid b) odour: odourless c) treshold odour value: not determined d) pH-value: (50g/l H2O, 20°C) 0,3 e) melting point / freezing point: ~ -15°C f) boiling point: ~ 310°C g) inflammation point: not applied h) evaporation rate: not determined i) flammability :fireproof j) upper/lower flammation/explosiveness limits: not applied k) steam pressure: not determined l) steam density: not determined m) relative density: 1,4 n) solubilty in H2O: 100% o) coefficient of dispersion: n-octanol/water; p) self-ignition temperature : not determined
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q) decay temerature: not determined r) viscosity: 26,9 s) explosive properties: none t) oxidative properties: none
9.2 Further information: none
10: Stability and reactivity
10.1 Reactivity: no unfavorable reaction under normal conditions
10.2 Chemical stability: stable under normal conditions when stored correctly
10.3 Possibility of dangerous reactions: reaction with strong alkalines
10.4 Conditions necessary to avoid:
10.5 Incompatibile materials: strong alkalines, ammonia, metals and alkaline earth metal
compounds
10.6 Dangerous decay products: hydrogen can develop after contact with metals
11: Toxicological information
11.1 Information on toxicological effects a) acute toxicity: The mixture components are not classified as acute toxic
LD
50
, oraly, mouse (mg.kg
-1
): 2140 (when 25% pure acid solution used)
LC
50
, inhalatory, rat, for steam and gases (mg.L
-1
): 0,5L/ 2 h (re-counted to pure sulfuric acid) b) causticity/skin irritability: skin-irritable c) serious damage/irritation of eyes: eyes-irritable d) airways/skin sensbilisation: none e) mutagenicity in germinal cells: none f) carcinogenicity: none g) reproductive toxicity : none h) specific end organ toxicity – one-shot exposure: none i) specific end organ toxicity – repeated exposure: none j) inhalation danger: none k) chronical/subchronical toxicity: no data available
12: Ecological information
12.1 Toxicity:
LC
50
24 hod., fish (mg.L
-1
) > 6,3
EC
50
24 hod., daphnia (mg.L
-1
) 29
12.2 Persistence and dissolubility: no data
12.3 Bioaccumulative potential: none
12.4 Mobility in soil: none
12.5 PBT and vPvB evaluation: does not belong to any cathegory
12.6 Other unfavorable effects: none
13: Disposal considerations
13.1 Waste manipulation methods:
Waste code : 06 01 01* sulfuric acid and sulphurous acid
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Small amount of the product dispose with the envelope. Recyclation according to national or local regulations
14: Transport information
The product is not dangerous for transport.
Pure sulfuric acid data:
14.1 OSN number (UN): 1830
14.2 OSN delivery title: transport according to Paragraph.3,4,3ADR
Sulfuric acid
IATA UN 1830 Sulfuric acid
IMGD UN 1830 Sulfuric acid
14.3 Dangerousness transport classification: 8
14.4 Envelope group :
14.5 Environmental dangerousness: none
14.6 Special safety measures for an user:
14.7 Bulk transport: attachment II MARPOL73/78 and IBC regulation:
Does not belong to sea-pollutants
15: Regulatory information
15.1 Regulations for health and environment safety/specific legal regulation regarding the
substance and its mixture:
CZ rules: no. 356/2003, 258/2000, 185/2001, NV 361/2007
Regulation EC 1272/2008, instruction no. 1999/45/ES
15.2 Chemical safety evaluation: CSR not worked up
16: Other information
Use the product in compliance with the Instruction manual of the kit. Safety precautions mentioned in the Instruction manual must be taken into account and an user should be trained for the test performance. Do not expose the product to temperature higher than 50°C
At the revision 3/2011 Safety data sheet was amended according to EC regulation no.
453/2010 and supplied with CLP- corresponding classification data.
Survay of the other R and H phrases:
R35 Cause serious etching.
H314 Cause serious etching of skin and eyes.
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