1 FP218 SAFTEY DATA SHEET Expel Miracle Heavy Duty Degreaser Revision Date 9th October 2012 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product Name Expel Miracle Heavy Duty Degreaser Synonyms, Trade Name Expel Miracle Heavy Duty Degreaser Application Degreaser Supplier Prime Industries Limited, Unit 2 Broughton Way, Halebank Industrial Estate, Widnes, WA8 8YX. PHONE 0151 423 0110 FAX 0151 423 0770 sales@primeindustries.co.uk Emergency Contact Number 0151 423 0110 SDS No. C2/428 2. HAZARDS IDENTIFICATION Irritant Classification R36/38 irritating to eyes and skin 3. COMPOSITION / INFORMATION ON INGREDIENTS NAME EC No. CAS-No. Classification Conc. Sodium Hydroxide 215-185-5 1310-73-2 C; R35 5-15% 68439-46-3 Xn; R22, Xi; R41 <5% C9-11 alcohol ethoxylate 6-8 moles EO Tetrasodium EDTA 200-573-9 64-02-8 Xn;R22, Xi; R41 <5% Sodium Metasillicate Pentahydrate 229-912-9 10213-79-3 C; R34, Xi; R37 <5% The Full Text For all R- Phrases Are Displayed in Section 16 4. FIRST-AID MEASURES Eye Contact Skin Contact Ingestion Inhalation Rinse thoroughly with plenty of water for several minuets Rinse affected area with water. If needed apply a cold compress to relieve irritation. If symptoms persist, discontinue use of product and seek medical advice Drink a glass of water to dilute product. Do not induce vomiting. Act immediately in order to prevent irritation to mouth, throat and stomach mucosa If symptoms persist, if persisting vomiting occurs or if blood tinged vomitus is present, seek medical advice. Go into open air and ventilate suspected area. If irritation is experienced, mouth and throat may be rinsed with water. If irritation or asthma-like symptoms persists, seek medical advice Page 1 of 4 2 FP218 5. FIRE-FIGHTING MEASURES Extinguishing Media Use: Unusual Fire & Explosion Hazards Not flammable. Use media to suit surrounding materials None Specific Hazard None Protective Measures in Fire Self contained breathing apparatus and ful protective clothing must be worn in case of fire 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Spill Cleanup Methods Observe normal standards of industrial hygiene for handling chemicals. Avoid contact with skin and eyes The material is designed for normal safe disposal to foul sewer. In the event of a spillage of a large amount of liquid, entry to surface water drainage should be avoided. Major spillage losses to surface drainage must be notified to the local waste authority Absorb with inert, absorbent material. Sweep up. Transfer to suitable labelled containers for disposal. Clean spillage area with thoroughly with plenty of water. 7. HANDLING AND STORAGE Usage Precautions Fire & Explosion Storage Precautions Avoid contact with eyes & skin. Adopt best Manual Handling consideration when handling, carrying and dispensing. Wash properly with soap and water No special measures Store in a cool dry area. External damage to containers should be avoided. Seal containers after use. Do not store product in direct sunlight. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Protective Equipment Respiratory Equipment If ventilation is insufficient, suitable respiratory protection must be provided Hand Protection Use protective gloves Eye Protection Other Protection Engineering Measures Hygiene Measures Approved glasses / goggles Overalls, wear rubber footwear Ensure well ventilated working area Wash at the end of each work shift and before eating, smoking and using the toilet. Remove contaminated clothing and wash the skin thoroughly with soap and water after work. Eating, smoking and water fountains prohibited in immediate work area. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid Colour Yellow / Clear Odour Low odour Solubility Soluble in water pH value (con) 13 Boiling point 100°C 10. STABILITY AND REACTIVITY Stability Conditions to Avoid A stable product under normal conditions Anionic Surfactants Page 2 of 4 3 FP218 Materials to Avoid Hazardous Decomposition Products Acids, Oxidizing agents Burning can produce carbon dioxide and carbon monoxide 11. TOXICOLOGICAL INFORMATION Toxic Dose 2-ld 50 770mg/kg (oral-mouse) Ingestion May cause irritation of the mucous membrane Inhalation Vapours may irritate throat and respiratory system and cause coughing Skin Contact Prolonged skin contact may cause localised irritation Eye Contact Moderate irritation 12. ECOLOGICAL INFORMATION Mobility Biodegradability Eco toxicity Mobile liquid The product is intended for wide dispersive use and is compatible with the down-the-drain route. The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. The surfactants contained within this preparation comply with the biodegradability criteria as laid down in regulation EC/648/2004 on detergents None toxic but should be prevented from entering surface water drains and water ways 13. DISPOSAL CONSIDERATIONS General Information Consumer products ending up down the drain after use. Observe safe handling precautions and local legislation 14. TRANSPORT INFORMATION Not subject to ADR / IATA / IMDG Codes 15. REGULATORY INFORMATION Labelling Contains Risk Phrases Safety Phrases Statutory Instruments Approved Code of Practice Guidance Notes Chemical safety Assessment Irritant Sodium Hydroxide R36/38 – Irritating to eyes and skin S2 – Keep out of reach of Children S24/25 – Avoid contact with eyes & skin S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection. S45 – In case of accident or if you feel unwell, seek medical advice immediately (show label whenever possible). Chemicals (Hazard information and packaging) regulations Safety data sheets of substances and preparations. Classification and labelling of substances and preparations dangerous to supply CHIP for everyone HSG (108). Workplace Exposure Limits EH40 A chemical safety assessment has to be carried out 16. OTHER INFORMATION REV. No. / REPL. SDS Generated SDS No. Safety Data Sheet Status 7th September 2011 C2/428 Page 3 of 4 4 FP218 Approved. Signature Risk Phrases in Full Safety Phrases Notes Usage 22nd May 2012 R22 – Harmful if swallowed R34 – Causes Burns R35 – Causes severe burns R37 – Irritating to respiratory system R41 – Risk of serious damage to eyes S2 – Keep out of reach of Children S24/25 – Avoid contact with eyes & skin S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection. S45 – In case of accident or if you feel unwell, seek medical advice immediately (show label whenever possible). This information relates only to the specific material designed and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of the company’s knowledge and belief, accurate and reliable as of date indicated. However, no warranty, guarantee or representation is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use. Concentrate for use with trigger spray dilute 1:30 with fresh clean water, spray on to surface and wipe with a soft clean cloth. For use on floors dilute 1:15 with clean warm water. Page 4 of 4