# Supplementary Material (ESI) for Chemical Communications # This journal is © The Royal Society of Chemistry 2004 Towards Flexible Inorganic Mesomaterials: One-Pot Low Temperature Synthesis of Mesoporous Nanocrystalline Titania Sönke Haseloha, Sung Yeun Choia, Marc Mamaka, Neil Coombsa, Srebri Petrova, Naveen Choprab, and Geoffrey A. Ozina* Chemistry Department, University of Toronto, Canada; E-mail: gozin@chem.utoronto.ca 70 %T 60 50 b 40 a (C-H) (C-O-C) 30 3500 3000 2500 2000 1500 1000 500 -1 Wavenumber (cm ) Fig. S1. IR spectra obtained from a thin film of mesoporous nanocrystalline titania before (a) and after (b) UV extraction. Typical bands from organic templates (P123) disappeared after UV irradiation. Spectra were obtained from pellets consisting of KBr and scraped meso-nc-TiO2 thin films. 1 # Supplementary Material (ESI) for Chemical Communications # This journal is © The Royal Society of Chemistry 2004 Fig. S2. SEM image of film surface obtained from meso-nc-TiO2 thin film deposited on PEN substrate after template removal with UV irradiation. 2