Year 10 Syllabus Revision– Suggested Answers 15-22 CHEMISTRY 15. Describe an appropriate model that has been developed to describe atomic structure. Give characteristics of an appropriate model that has been developed to describe atomic structure. The modern day model of the atom is one that has been developed over about 200 years of experimentation and discovery. The widely accepted model of the atom has the following features: (a) an extremely small and very dense, positively charged nucleus containing protons and neutrons. The positive charge is attributed to the protons (neutrons are neutral in charge). For interest: atoms range in size from about 1 – 5 angstroms (Å) – 10-10m. On this scale the nucleus would be 10-4 Å (10-14m). since protons and neutrons are about 2000 times the mass of an electron over 99.9% of the mass of the atom is found in the nucleus. In density terms this would equate to approximately 1013 – 1014g/cm3 (or 1 matchbox full of nuclear material weighing over 2½ billion tons). The charge of a proton is +1.602 x 10-19C (C = coulombs – unit of charge) (b) the rest of the atom is mostly empty space in which the electrons orbit the nucleus in electron shells (energy levels). The electrons of an atom are arranged in their respective shells in a particular order. This is known as electronic configuration. There is a basic mathematical expression that can be used to determine the maximum number of electrons that each shell can hold, ie. Max.No. electrons = 2n2 (where n = shell number) Shell 1 = 2 x 12 = 2 Shell 2 = 2 x 22 = 8 Shell 3 = 2 x 32 = 18 Shell 4 = 2 x 42 = 32 NOTE: for the first 20 elements the third shell will only hold a maximum of 8 electrons. This is known as octet stability. For interest: to get an idea of the vastness of this empty space in an atom picture the Sydney Cricket Ground. A cricket ball in the centre would represent the size of the nucleus. The playing area would represent the overall size of the atom and fruit flies would be electrons. Diagrammatically the atom can be represented as follows: A sodium atom Protons = 11 (P) Neutrons = 12 (N) Electrons = 11 – 2,8,1 ( nucleus 11P 12N ) electron shells 16. Describe features of and the location of protons, neutrons and electrons in the atom. Give the characteristic features of and the location of protons, neutrons and electrons in the atom. All atoms are made up of three subatomic particles known as protons, neutrons and electrons. The main features of these subatomic particles and their location in the atom are: Particle Charge Relative Mass Proton Positive (+ve) 1 A.M.U Neutron Electron Neutral (no charge) 1 A.M.U Negative (-ve) 1/2000 A.M.U Location Nucleus Nucleus Electron shells NOTE: A.M.U = Atomic Mass Unit 17. Identify the atom as the smallest unit of an element and distinguish between atoms and molecules. Recognise the atom as the smallest unit of an element and use this characteristic to highlight the differences between atoms and molecules. 18. By definition an element is a: “pure substance composed of only one type of atom”. Elements are essentially indivisible in that they cannot be broken down into simpler or different substances. By this reasoning the element gold would only consist of gold atoms, the element oxygen would only consist of oxygen atoms, the element sodium would only consist of sodium atoms and so on. Some elements are capable of existing as single atoms (although impossible to see). This individual atom would therefore show the characteristic properties of that element. However, some elements cannot exist as a single atom. Instead they will combine with like atoms to form molecules. A molecule is defined as: “the simplest part of a chemical substance that can exist by itself and display the unique properties of that substance”. When elements exist as molecules they are said to be diatomic – two similar atoms. Eg. Hydrogen (H2), oxygen (O2), nitrogen (N2), fluorine (F2), chlorine (Cl2), bromine (Br2), iodine (I2). Sometimes compounds also form molecules. These molecules differ from diatomic elements in that they have combinations of different elements. Molecules of compounds are represented by molecular formulas. Eg. Water (H2O), methane (CH4), carbon dioxide (CO2), hydrogen peroxide (H2O2), ethanol (C2H6O). Distinguish between elements, using information about the numbers of protons, neutrons and electrons. Highlight differences between elements, using information about the numbers of protons, neutrons and electrons. There are around 100 different elements known to exist with about 92 of these occurring naturally. Every element differs from the others in terms of the numbers of subatomic particles that make up each atom of that element. The main particle that determines each different element is the proton. No two elements have the same number of protons. The number of protons in the nucleus of an atom of any element is known as its atomic number. The Periodic Table lists all the known elements in order of increasing atomic number. All atoms are neutral in charge. This is achieved by the fact that the number of electrons (-ve charge) is equal to the number of protons (+ve charge). The number of neutrons in an atom of a particular element is not a fixed value. The sum of the protons and neutrons in the nucleus of an atom of any element is known as its atomic mass or mass number. Some atoms of the same element may have different numbers of neutrons. Such atoms are known as isotopes. Eg. Carbon has three main isotopes – 12 6 C, 13 6 C, 14 6 C. In the atomic symbol the top number is the atomic mass and the bottom number is the atomic number. To determine the number of protons you simply subtract the atomic number form the atomic mass, ie. 12 6 C – number of neutrons = 12 – 6 = 6 13 6 C – number of neutrons = 13 – 6 = 7 14 6 C – number of neutrons = 14 – 6 = 8 For this reason the atomic mass for most elements is not a whole number. The value is calculated as an average of the masses of the different isotopes for that element. 19. Identify that a new compound is formed by rearranging atoms rather than by creating matter. Recognise and show that a new compound is formed by rearranging atoms rather than by creating matter. In the 1700s a French scientist by the name of Antoine Lavoisier conduct a set of carefully controlled experiments about masses in chemical reactions. The results of his experiments showed that the total mass of all substances present after a chemical reaction (products) was equal to the total mass of the substances before the reaction (reactants). This important fact became known as the Law of Conservation of Mass (or Matter), which states that: “matter (atoms) can neither be created nor destroyed only change during chemical processes”. This means that during a chemical reaction the total number and type of any atom present before the reaction must be the same as after the reaction. As such new compounds formed during a chemical reaction are only rearrangements of atoms already present in the reaction mixture. For example, it is commonly known that two molecules of hydrogen will react with one molecule of oxygen to produces two molecules of water as shown in the following chemical equation: 2H2 + O2 2H2O By careful inspection it can be seen that both sides of this equation contain 4 atoms of hydrogen and 2 atoms of oxygen and that water is simply a rearrangement of these atoms from their initial gaseous molecules. Other examples include: Hydrochloric acid + sodium hydroxide sodium chloride + water HCl + NaOH Atoms Before Reaction H=2 Cl = 1 Na = 1 O=1 NaCl + H2 O Atoms after reaction H=2 Cl = 1 Na = 1 O=1 Sulfuric acid + aluminium carbonate aluminium sulfate + carbon dioxide + water 3H2SO4 + Al2(CO3)3 Atoms Before Reaction Al2(SO4)3 + Atoms after reaction 3CO2 + 3H2O H=6 S=3 O = 21 Al = 2 C=3 H=6 S=3 O = 21 Al = 2 C=3 In all cases matter is conserved and products are rearrangements of the atoms from the reactants. 20. Classify compounds into groups based on common chemical characteristics. Arrange compounds into appropriate groups based on common chemical characteristics. There are two main types of compounds. These are ionic and covalent (or molecular) compounds. A comparison of the chemical properties of these two types of compounds includes: Ionic Compounds Form when metals and non-metals bond together. Involve the transfer of electron/s from one atom to another. Results in ions forming crystal structures of arrays of oppositely charged ions. Strong forces of electrostatic attraction between ions makes them solid at room temperature and have relatively high melting and boiling points. Covalent Compounds Form when non-metals bond together. Involve the sharing of pairs of electrons between the two atoms. Results in the formation of molecules that have weak forces of attraction between them. Weak forces of attraction between molecules means that they can be gas, liquid or low melting point solids at room temperature. Common examples of these compounds include: - Ionic sodium chloride (NaCl) magnesium oxide (MgO) copper sulfate (CuSO4) aluminium sulfide (Al2S3) calcium carbonate (CaCO3) potassium iodide (KI) - Covalent carbon dioxide (CO2) water (H2O) ammonia (NH3) methane (CH4) ethanol (C2H6O) sucrose (sugar) (C12H22O11) 21. Identify a range of common compounds using their common names and chemical formulae. Recognise a range of common compounds using their common names and chemical formulae. Common name Salt Sugar Alcohol Water Vinegar Bicarb soda Carbon dioxide Ammonia Methane Hydrochloric acid Sulfuric acid Nitric acid Rotten egg gas Copper sulfate Sodium hydroxide Formula NaCl C12H22O11 C2H6O H2O CH3COOH NaHCO3 CO2 NH3 CH4 HCl H2SO4 HNO3 H2S CuSO4 NaOH Chemical name Sodium chloride Sucrose Ethanol Dihydrogen oxide Acetic (ethanoic) acid Sodium bicarbonate Carbon dioxide Nitrogen trihydride Carbon tetrahydride Hydrogen chloride Dihydrogen sulfate Hydrogen nitrate Dihydrogen sulfide Copper sulfate Sodium hydroxide 22. Describe the role of indicators. Provide an outline of the role of indicators. Chemical indicators are substances that change colour in different solutions to indicate whether the solution is acidic or basic/alkaline (and sometimes neutral). Most indicators will only change between two colours, ie. one colour in acids and a different colour in bases (alkalis). However, indicators like universal indicator may go through several colour changes as the solution goes from strongly acidic through neutral to strongly basic. Indicators like universal can also give the pH of a solution. The pH scale gives a numerical value as to the strength of an acidic or alkaline solution. The pH scale is as shown below: Strongly Acidic 0 1 Weakly Acidic 2 red 3 4 5 orange Neutral 6 7 Weakly Basic 8 9 yellow green green/blue (colour of universal indicator) Strongly Basic 10 11 blue 12 13 purple Some common indicators and their colour changes include: Indicator Litmus Phenolphthalein Bromothymol blue Methyl orange Phenol red Colour in Acid Red Colourless Yellow Red Yellow Colour in Base Blue Red Blue Yellow Red 14