Practice: Moles and Stoichiometry 1. Ans: A m = 8.5 g of NaNO3 M = (22.99 + 14.01 + 3x16.00) = 85g/mol of NaNO3 n = m/M n = 8.5g/85g/mol n = 0.1 mol of NaNO3 molar ratio: 1 molecule of NaNO3 for every 1 molecule of HNO3 so 0.1mol of NaNO3 : 0.1mol of HNO3 n = 0.1 mol of HNO3 M = (1.01 + 14.01 + 3x16.00) = 63.02g/mol of HNO3 m=nxM m = 0.1mol x 63.02g/mol m = 6.3g of HNO3 2. Ans: B 3. Ans: 31.43g/mol of AgNO3 m = 2 g of Ag M = 107.87g/mol of Ag n = m/M n = 2g/107.87g/mol n = 0.0185 mol of Ag molar ratio: 2 molecule of Ag for every 2 molecule of AgNO3 so 0.0185mol of Ag : 0.0185mol of AgNO3 n = 0.0185 mol of AgNO3 M = (107.87 + 14.01 + 3x16.00) = 169.88g/mol of AgNO3 m=nxM m = 0.0185mol x 169.88g/mol m = 31.4278g of AgNO3 4. Ans: C n =m/M m = 10g M = (22.99 + 16.00 + 1.01) = 40g/mol of NaOH n = 10g / 40g/mol = 0.25 moles of NaOH m = 73g M = (22.99 + 35.45) = 58.44g/mol of NaCl n = 73g / 58.44 g/mol = 1.25 moles of NaCl m = 126g M = (1.01 + 14.01 + 3x16.00) = 63.02g/mol of HNO3 n = 126g / 63.02 g/mol = 2.00 moles of HNO3 m = 140g M = (200.59 + 79.91) = 280.5g/mol of HgBr n = 140g / 280.5 g/mol = 0.5 moles of HgBr 5. Ans: 116.66g of Mg(OH)2 Molar Ratio: 2 molecules of HCl for every 1 molecule of Mg(OH)2 So 4 moles of HCL : 2 moles of Mg(OH)2 n = 2 moles of Mg(OH)2 M = (24.31 + 2x16.00 + 2x1.01) = 58.33g/mol of Mg(OH)2 m=nxM m = 2 mol x 58.33g/mol m = 116.66g of Mg(OH)2 6. Ans: 27.23g of CaSO4 C = n/V C = 1.0mol/L of Na2SO4 V = 200ml = 0.2L n=CxV n = 1.0mol/L x 0.2L n = 0.2 moles of Na2SO4 Molar Ratio: 1 molecule of Na2SO4 for every 1 molecule of CaSO4 So 0.2 mol of Na2SO4 : 0.2 mol of CaSO4 n = 0.2 moles of CaSO4 M = (40.08 + 32.06 + 4x16) = 136.14g/mol of CaSO4 m=nxM m = 0.2 mol x 136.14 g/mol m = 27. 23 g of CaSO4 7. Ans: E ** We did not learn this in class, so you do not need to complete it however, here is how you would do the question. Soft drink pH = 3 pOH = 14 – 3 = 11 3 = - log [H+] -1 -1 11 = - log [OH-] -1 -1 3 = log [H+] 11 = log [OH-] 10-3 = [H+] 10-11 = [OH-] 8. Ans: C m = 80g of CH4 M = (4x1.01 + 12.01) = 16.05g/mol n = m/M n = 80g/16.05g/mol n = 4.984 moles of CH4 ~ 5 moles 9. Ans: 16.65g of CaCl2 n = 0.15 moles of CaCl2 M = (40.08 + 2x35.45) = 110.98 g/mol m=nxM m = 0.15mol x 110.98g/mol m = 16.647 g of CaCl2 10. Ans: 16.8kg of NaOH m = 924g of CO2/day M = (12.01 + 2x16.00) = 44.01g/mol n = m/M n = 924g/44.01g/mol n = 20.995 moles of CO2 Molar Ratio: For every 1 molecule of CO2 we get 2 molecules of NaOH So 20.995 moles of CO2 : 41.99 moles of NaOH n = 41.99 moles M = (22.99 + 16.00 + 1.01) = 40g/mol m=nxM m = 41.99mol x 40g/mol m = 1679.6g of NaOH /day Amount for ten days = 1679.6g/day x 10days = 16.8 kg of NaOH 11. Ans: D ** We have not gone over properties of states of matter yet; however the substance that occupies the most volume is the substance in the gaseous state. The molecules in a gas are more spaced out and therefore occupy a greater volume with the same number of moles as a liquid or a solid. This means that 70g of chlorine (g) will have the greatest volume. 12. Ans: C 13. Ans: A 3CuO + 2NH3 N2 + 3Cu + 3H2O n = 9 mol of Cu Molar Ratio: For every 3 molecules of Cu you have 2 molecules of NH3 So 3 : 2 9 mol : X (9)(2) = 3(X) (9)(2)/(3) = X X = 6 moles of NH3 Cross multiply