(according to ⁄ 14
GefStoffV and
Directive 91/155/EEC)
Material Safety Data Sheet
fischer Injection Mortar FIS EM 390 S Article number: 93048/93049
th
th
Prepared on: 11/13 /2003 Reviewed on: 01/15 /2004 Printing date:
27.04.2006 Version: 1.1 Page: 1 of 7
1. Identification of the substance/preparation and company
1.1 Trade name: fischer Injection Mortar FIS EM 390 S
1.2 Article number:
93048, 93049
1.3 Typical application:
Heavy duty anchoring free of expansion pressure
1.4 Manufacturer/supplier: fischerwerke Artur Fischer GmbH & Co. KG
1.5 Address:
D-72178 Waldachtal, Weinhalde 14 - 18
1.6 Contact:
Mr. Werner Sch uble
1.7 Telephone:
0049 7666/902-2965
1.8 Telefax:
0049 7666/902-2929
1.9 Emergency information:
0049 7443/12-4444
2. Composition/information on ingredients
Component A:
A.2.1 Chemical characterization: Epoxy resins with anorganic fillers
A.2.2 Dangerous components:
CAS — No.
EWG-No.
Material
25068-38-6
500-033-5
Bisphenol-A-Epichlorhydrin resin
Content [%]
Symbol
< 35
Xi, N
28064-14-4
Epoxy resin
< 15
-Component B:
65997-15-1
266-043-4
Portlandcement according to TRGS 613
< 40
B.2.1 Chemical characterization: Formulation of aliphatic polyamines with anorganic fillers
EWG-No.
Material
Content [%]
CAS
— No. components:
B.2.2
Dangerous
1477-55-0
216-032-5
m-Xylylendiamine
< 40 [%]
CAS
— No.
EWG-No.
Material
Content
80-05-7
25068-38-6
65997-15-1
201-245-8
500-033-5
266-043-4
Handling and storage
28064-14-4
--
Xi, N
Xi
Symbol
4,4’-Isopropylidendiphenol
Bisphenol-A-Epichlorhydrin resin
Portlandcement according to TRGS 613
<
< 10
35
< 20
C
Symbol
XiN
Xi,
Xi
Epoxy resin
< 15
Xi, N
< 40
Xi
Content [%]
Symbol
765997-15-1
266-043-4
Portlandcement according to TRGS 613
.
3. Hazards identifaction
EWG-No.
Material
CAS — No.
R- Phrases
36/38, 43,
51/53
36/38, 43,
51/53
38, 41
R- Phrases
20/22, 34,
R- Phrases
52/53
36/38,
43, 43
36/37/38,
51/5338, 41
36/38, 43,
51/53
38, 41
R- Phrases
7.1 Handling:
20/22, 34,
3.1
Hazard description:
1477-55-0
216-032-5
m-Xylylendiamine
< 40
C
52/53
7.1.1
Information
for safe handling:
80-05-7
201-245-8
4,4’-Isopropylidendiphenol
< 10 vapour. Provide
Xi
36/37/38, 43
Avoid
contact with eyes and skin. Do not breathe
good
A Xi Irritant
A N Dangerous
for the environment
B C Corrosive
65997-15-1
266-043-4
Portlandcement
according
to TRGS
613
< 20
Xi that the
38, 41
ventilation.
If necessary
use
local exhaust ventilation.
Ensure
occupational exposure limits are kept when working with the product.
Handling and storage
7.1.2
7
Information
about protection
Observefor
theman
general
for fire prevention. Keep product away from heat
3.2 Information
pertaining
to particular dangers
andrules
environment:
.
against explosions and fires:
sources, open fires, etc., do not smoke.
B R 20/22 Harmful by inhalation and if swallowed. B R 34 Causes burns. A R 36/38 Irritating to eyes and skin. A R 41 Risk of
serious damage to eyes. A+B R7.2
43Storage:
May cause sensitisation by skin contact. A R 51/53 Toxic to aquatic organisms,
cause
7.1may
Handling:
long-term
7.2.1 adverse effects in the aquatic environment. B R 52/53 Harmful to aquatic organisms, may cause long-term adverse
be met
by
Keep cartridge tightly sealed in its original package and store in a dry, cool
effects
in theRequirements
aquatic environment.
7.1.1
Information
fortosafe
handling:
Avoid
contact
and skin. Do
not breathe vapour. Provide good
storerooms and receptables:
(max. 25
…C) with
and eyes
well ventilated
place.
ventilation. If necessary use local exhaust ventilation. Ensure that the
7.2.1
Do
not store together
acids,
alkaliwhen
or oxidizing
occupational
exposurewith
limits
are kept
workingagents.
with the product.
Rules for the mixed storage
of
chemicals:
7.1.2
Information about protection
Observe the general rules for fire prevention. Keep product away from heat
7.2.3 against explosions and fires:
sources,
open
fires,
etc., do beverages
not smoke.and animal feedstocks. Prevent from
Further
information
about
Keep away
from
foodstuffs,
4. First aid measures
storage conditions:
heat and direct sunlight.
7.2 Storage:
4.1 General
information:
Remove contaminated,
clothing immediately.
7.2.4
Storage
class:
8 accordingsaturated
to VCI guideline.
7.2.1
Requirements
to be met by
Keep cartridge
tightly sealed
in its original
package and
store in a Fibre/m_
dry, cool
Material
Content
Type
mg/m_
ppm
4.2
After inhalation:
In case of inhalation,
affected
person
be place.
moved into fresh air and kept still(F/G)
and warm.
storerooms
and receptables:
(max. 25
…C) and
well should
ventilated
[%]
CAS
—
No.
If symptoms persist, call a doctor.
7.2.1
Do not store together with acids, alkali or oxidizing agents.
1477-55-0
-Diamino-1,3-xylol,
Rules for alpha,alpha
the mixed storage
< 40
MAK
0,1
m-Phenylenbis(methylamin)
4.3
After
skin
contact:
On
contact
with
the skin, wash off immediately with soap and water. If skin irritation persists
of chemicals:
seek
80-05-7
medical advice
4,4’-Isopropylidendiphenol
< 15
MAK
5
7.2.3
Further information about
Keep away from foodstuffs, beverages and animal feedstocks. Prevent from
storage conditions:
heat and direct sunlight.
10. Stability and reactivity
7.2.4
10.1
Storage
class:
Conditions
to be avoided:
Material
according to VCI
guideline.
No8 decomposition
if used
as prescribed.
Content
Type
mg/m_
[%]
ppm
Fibre/m_
(F/G)
Material Safety Data Sheet
(according to ⁄ 14 GefStoffV and Directive 91/155/EEC) fischer
th
Injection Mortar FIS EM 390 S Article number:
th
93048/93049 Prepared on: 11/13 /2003 Reviewed on: 01/15 /2004 Printing date: 27.04.2006 Version: 1.1 Page: 2 of
7
4.4
After eye contact: On contact with the eyes, rinse immediately with plenty of water for 15 minutes and seek
medical advice.
4.5
After swallowing: If swallowed,s eek medical advice immediately and show packaging or label. DO NOT
induce vomiting.
4.6 Indications for the doctor:
None.
5. Fire-fighting measures
5.1
Suitable extinguishing media: Spray water, alcohol-resistant foam, dry powder extinguisher, carbon
dioxide (CO2).
5.2
For safety reasons unsuitable Water applied with full
jet. extinguishing media:
5.3
Special exposure hazards Fire may release: carbon monoxide (CO, nitrogen oxides (NOx), ammonia (NH3).
arising from the substance or May burn with strong soot emission. Combustion gases principially have to be
preparation itself, combustion considered as toxic substances. products, resulting gases:
5.4
Special protective equipment Use breathing apparatus with independent air
supply. for fire fighting:
5.5
Other information: Remove product off fire area. Contaminated firefighting water must not be
discharged into the drainage system.
6. Accidental release measures
6.1
Person-related
safety precautions:
Ensure adequate ventilation. Keep away sources of ignition. Use
personal protective equipment.
6.2
Measures for
environmental protection:
Do not allow to enter into soil/subsoil. Do not allow to enter
drains/surface waters/groundwater.
6.3
Measures for
cleaning/absorption:
Use-liquid-binding material (e.g. sand, dry earth) to soak up. Take up solids
by mechanical means. Fill into sealable and labelled containers and dispose
as described in chapter 13.
6.4
Information about personal protective equipment see chapter 8.
Other information:
CAS — No.
EWG-No.
Material
Content [%]
Symbol
25068-38-6
500-033-5
Bisphenol-A-Epichlorhydrin resin
< 35
Xi, N
Epoxy resin
< 15
Xi, N
Portlandcement according to TRGS 613
< 40
Xi
Content [%]
Symbol
28064-14-4
65997-15-1
-266-043-4
EWG-No.
Material
1477-55-0
216-032-5
m-Xylylendiamine
< 40
C
80-05-7
65997-15-1
201-245-8
266-043-4
4,4’-Isopropylidendiphenol
Portlandcement according to TRGS 613
< 10
< 20
Xi
Xi
CAS — No.
R- Phrases
36/38, 43,
51/53
36/38, 43,
51/53
38, 41
R- Phrases
20/22, 34,
52/53
36/37/38, 43
38, 41
Handling and storage
7
.
7.1 Handling:
7.1.1
7.1.2
Information for safe handling:
Information about protection
against explosions and fires:
Avoid contact with eyes and skin. Do not breathe vapour. Provide good
ventilation. If necessary use local exhaust ventilation. Ensure that the
occupational exposure limits are kept when working with the product.
Observe the general rules for fire prevention. Keep product away from heat
sources, open fires, etc., do not smoke.
7.2 Storage:
7.2.1
Requirements to be met by
Keep cartridge tightly sealed in its original package and store in a dry, cool
Material Safety Data Sheet
(according to ⁄ 14 GefStoffV and Directive 91/155/EEC) fischer
th
Injection Mortar FIS EM 390 S Article number:
th
93048/93049 Prepared on: 11/13 /2003 Reviewed on: 01/15 /2004 Printing date: 27.04.2006 Version: 1.1 Page: 3 of
7
8. Exposure controls and personal protection
8.1
Additional information about design of technical systems:
No further information. See chapter 7.
8.2
Components with limit values that require monitoring at the workplace:
CAS — No.
EWG-No.
Material
Content [%]
Symbol
25068-38-6
500-033-5
Bisphenol-A-Epichlorhydrin resin
< 35
Xi, N
Epoxy resin
< 15
Xi, N
Portlandcement according to TRGS 613
< 40
Xi
Content [%]
Symbol
< 40
C
28064-14-4
8.3
-65997-15-1
266-043-4
Additional information:
CAS — No.
8.4
EWG-No.
Material
1477-55-0
216-032-5
Personal
protective
equipment:m-Xylylendiamine
R- Phrases
36/38, 43,
51/53
36/38, 43,
51/53
38, 41
R- Phrases
20/22, 34,
52/53
36/37/38, 43
38, 41
80-05-7
201-245-8
4,4’-Isopropylidendiphenol
< 10
Xi
Respiratory
protection:
Respiratory
protection necessary
or20
prolonged exposure.
65997-15-1
266-043-4
Portlandcement
accordingat
tounsufficient
TRGS 613 exhaustion <
Xi
Handling and
storage
Hand protection:
Wear
suitable protective gloves made of nitrile. See EN 374. Observe the information of the
producer
7 with respect to permeability and break through time of the gloves. You should also take into account the
special
. conditions at the workplace.
Eye protection:
7.1 Handling:
Eye glasses with side protection. See EN 166 F.
Information
safeworking
handling:
Body7.1.1
protection:
Wearfor
closed
clothes.
Avoid contact with eyes and skin. Do not breathe vapour. Provide good
ventilation. If necessary use local exhaust ventilation. Ensure that the
General protective and
The usual precautionary
measures
should
be adhered
in handling
occupational
exposure
limits
are kept to
when
workingthe
with the product.
hygienic measures:
chemicals. Protect skin with protective skin cream. Do not inhale vapour. Avoid
7.1.2
contact
with skin,
eyes and
clothes.
ImmediatelyObserve
remove the
contaminated
clothes.
Wash
hands and
faceproduct
before away from heat
Information
about
protection
general rules
for fire
prevention.
Keep
breaks and on
finishing
work. Do not
drink or
smoke open
while fires,
working.
away
of food and drinks
against
explosions
andeat,
fires:
sources,
etc.,Keep
do not
smoke.
7.2 Storage:
7.2.1
9. Physical and
Requirements
chemical properties
to be met by
Keep cartridge tightly sealed in its original package and store in a dry, cool
(max. 25 …C) and well ventilated place.
storerooms and receptables:
7.2.1
Do not store together with acids, alkali or oxidizing agents.
Rules Component
for the mixed
storage
Appearance:
A Component
B Form: Paste Paste Colour: White
of chemicals:
Black Odour:
7.2.3Weak Pungent, like amines
Further information about
Keep away from foodstuffs, beverages and animal feedstocks. Prevent from
storage conditions:
heat and direct sunlight.
9.1
7.2.4
9.2
Storage class:
Material
8 according to VCI guideline.
Content
Type
[%]
mg/m_
Safety
parameters:
CAS —
No.
1477-55-0
alpha,alpha -Diamino-1,3-xylol,
MAK
0,1
Component A Component
B Method: ph - Value at ... g/l H2O; <...40
¡C Strongly
alkaline. Strongly
m-Phenylenbis(methylamin)
80-05-7
4,4’-Isopropylidendiphenol
< 15
MAK
5
alkaline. Oxidizing properties: No No Density: at 23 ¡C 1.5 — 1.6 g/cm_ 1.2 — 1.3 g/cm_ Solubility:
ppm
Fibre/m_
(F/G)
-
-
-
-
10. Stability and reactivity
10.1
Conditions to be avoided:
No decomposition if used as prescribed.
10.2 Materials to be avoided:
Dangerous reactions witth isocyanate, anhydrides, acids, oxidizing agents.
Water: at ... ¡C Not soluble Not soluble Viscosity: at 23 ¡C Approx. 100 Pa s Approx. 80 Pa s Brookfield Sp 7 10
10.3
Nitrogen oxides (N0x).
Hazardous decomposition
rpm Solventproducts:
content: < 1 % < 1 %
10.4
9.3
Further information:
--
Further
information:
-11.
Toxicological
information
11.1 Acute toxicity: LD50/LC50 values which are relevant for classification: The product has not been tested.
11.2 Specific symptoms in animal studies: The product has not been tested.
Material Safety Data Sheet
(according to ⁄ 14 GefStoffV and Directive 91/155/EEC) fischer
th
Injection Mortar FIS EM 390 S Article number:
th
93048/93049 Prepared on: 11/13 /2003 Reviewed on: 01/15 /2004 Printing date: 27.04.2006 Version: 1.1 Page: 4 of
7
CAS — No.
EWG-No.
Material
25068-38-6
500-033-5
28064-14-4
65997-15-1
-266-043-4
Content [%]
Symbol
Bisphenol-A-Epichlorhydrin resin
< 35
Xi, N
Epoxy resin
< 15
Xi, N
Portlandcement according to TRGS 613
< 40
Xi
Content [%]
Symbol
EWG-No.
Material
1477-55-0
216-032-5
m-Xylylendiamine
< 40
C
80-05-7
65997-15-1
201-245-8
266-043-4
4,4’-Isopropylidendiphenol
Portlandcement according to TRGS 613
< 10
< 20
Xi
Xi
Content [%]
Symbol
< 35
Xi, N
CAS — No.
Handling and storage
CAS — No.
EWG-No.
Material
7
. 25068-38-6
500-033-5
Bisphenol-A-Epichlorhydrin resin
28064-14-4
R- Phrases
36/38, 43,
51/53
36/38, 43,
51/53
38, 41
R- Phrases
20/22, 34,
52/53
36/37/38, 43
38, 41
R- Phrases
36/38, 43,
51/53
36/38, 43,
51/53
7.1 Handling:
38, 41
Epoxy resin
< 15
Xi, N
-65997-15-1
266-043-4
Portlandcement according to TRGS 613
< 40
Xi
7.1.1 Information for safe handling:
breathe
vapour.
Provide goodR- Phrases
EWG-No.
Material Avoid contact with eyes and skin. Do not
Content
[%]
Symbol
CAS — No.
ventilation. If necessary use local exhaust ventilation. Ensure that the
20/22, 34,
occupational exposure limits are kept when< working
with the
1477-55-0
216-032-5
m-Xylylendiamine
40
C product.
52/53
7.1.2
80-05-7
201-245-8
4,4’-Isopropylidendiphenol
< 10Keep product
Xi away from
36/37/38,
43
Information
about protection
Observe the general rules for fire prevention.
heat
against explosions
fires:
sources,
open fires,
etc., do
not smoke. < 20
65997-15-1
266-043-4 and Portlandcement
according
to TRGS
613
Xi
38, 41
Handling and storage
7
.7.2.1
7.2.1
7.1.1
7.2.3
7.2 Storage:
Requirements to be met by
storerooms and receptables:
Rules for the mixed storage
of
chemicals:
Information
for safe handling:
Further information about
storage conditions:
Keep cartridge tightly sealed in its original package and store in a dry, cool
(max. 25 …C) and well ventilated place.
Do not store together with acids, alkali or oxidizing agents.
7.1 Handling:
Avoid contact with eyes and skin. Do not breathe vapour. Provide good
ventilation.
necessary
use beverages
local exhaust
Ensure that
the from
Keep away Iffrom
foodstuffs,
andventilation.
animal feedstocks.
Prevent
occupational
exposure
heat and direct
sunlight.limits are kept when working with the product.
12. Ecological information
7.1.2
7.2.4 Information
Storage class:
8 according
VCI guideline.
about protection
Observe
theto
general
rules for fire prevention. Keep product away from heat
Material
Content
mg/m_available.ppm
Fibre/m_
explosions
and fires: (Persistence
sources, open
fires,
etc., doType
not
12.1 against
Information
on elimination:
and
degradability):
Nosmoke.
information
[%]
(F/G)
CAS — No.
7.2 Storage: Do not allow the induvidual components to enter drains/surface
12.2
Behaviour
in environmental
1477-55-0
alpha,alpha
-Diamino-1,3-xylol,
< 40
MAK
0,1
compartiments: m-Phenylenbis(methylamin)
waters/groundwater.
7.2.1
Requirements to be met by
Keep cartridge tightly sealed in its original package and store in a dry, cool
80-05-7
4,4’-Isopropylidendiphenol
<
15
MAK
5
and receptables:
(max.
25 …C) and
well ventilated
12.3 storerooms
Ecotoxicological
effects: Toxic
respectively
harmful
to aquaticplace.
organisms, may cause long-term adverse
effects in the aquatic environment..
7.2.1
Do not store together with acids, alkali or oxidizing agents.
Rules for the mixed storage
10. Stability and reactivity
12.4 of chemicals:
Further ecological information: WGK-Classification (Germany): 2; endangering water.
10.1 Conditions to be avoided:
No decomposition if used as prescribed.
7.2.3
CAS —Further
No.
EWG-No. about
Material Keep away from foodstuffs, beveragesContent
[%]feedstocks.
SymbolPrevent
R- Phrases
information
and animal
from
36/38, 43,
storage
conditions:
heat
and
direct
sunlight.
10.2
Materials to
be avoided:Bisphenol-A-Epichlorhydrin
Dangerous reactionsresin
witth isocyanate, anhydrides,
25068-38-6
500-033-5
< 35 acids, oxidizing
Xi, N agents.
51/53
7.2.4
8 according
to(N0x).
VCI guideline.
10.3 Storage class:
Nitrogen
oxides
36/38, 43,
Hazardous
decomposition
28064-14-4
Epoxy resin
< 15
Xi, N Fibre/m_
Material
Content
Type
mg/m_
ppm
-51/53
products:
(F/G)
65997-15-1
266-043-4
Portlandcement according[%]
to TRGS 613
< 40
Xi
38, 41
CAS — No.
10.4
Further information:
-1477-55-0
alpha,alpha -Diamino-1,3-xylol,
EWG-No.
Material
Content
Symbol
< 40
MAK
0,1 [%]
-R- Phrases
m-Phenylenbis(methylamin)
CAS — No.
< 15
MAK
5
- 20/22, 34,
11. 80-05-7
Toxicological4,4’-Isopropylidendiphenol
information
1477-55-0
216-032-5
m-Xylylendiamine
< 40
C
52/53
11.1
Acute toxicity:
LD50/LC50 4,4’-Isopropylidendiphenol
values which are relevant for classification: The product
not beenXitested. 36/37/38, 43
80-05-7
201-245-8
<10.
10has
Stability
and reactivity
65997-15-1
266-043-4
Portlandcement according to TRGS 613
< 20
Xi
38, 41
10.1
Conditions
to be avoided:
No decomposition if used as prescribed.
Handling
and storage
11.2 Specific symptoms in animal studies: The product has not been tested.
7
.10.2
Materials to be avoided:
Dangerous reactions witth isocyanate, anhydrides, acids, oxidizing agents.
11.3 Irritant effects: On contact with the skin or the respiratory organs irritation is possible.
10.3
Nitrogen oxides (N0x).
Hazardous decomposition
products:
7.1 Handling:
11.4 Sensitization: Sensitization possible on contact with skin. Contact with skin may induce allergic eczemas.
10.4
7.1.1
Further information:
Information
for safe handling: --
Avoid contact with eyes and skin. Do not breathe vapour. Provide good
ventilation. If
necessary
use not
localbeen
exhaust
ventilation. Ensure that the
11.5 Effects after repeated or longtime Exposition:
The
product has
tested.
11. Toxicological information
occupational exposure limits are kept when working with the product.
7.1.2
11.1 Acute
toxicity: about
LD50/LC50
values which
are relevant
for classification:
product has
notproduct
been tested.
Information
protection
Observe
the general
rules for fire The
prevention.
Keep
away from heat
Material Safety Data Sheet
(according to ⁄ 14 GefStoffV and Directive 91/155/EEC) fischer
th
Injection Mortar FIS EM 390 S Article number:
th
93048/93049 Prepared on: 11/13 /2003 Reviewed on: 01/15 /2004 Printing date: 27.04.2006 Version: 1.1 Page: 5 of
7
13.2.3 European waste code: 15 01 10; packaging containing residues of or contaminated by dangerous substances
14. Transport information #
14.1
Land transport ADR/RID/GGVS/GGVE: Classification: 8 Classification Code: C8 Warning
board 8
Hazard - No.: 80 UN - No.: 3259 Description of goods: AMINES, SOLID; CORROSIVE,
N.O.S. Remarks: LQ 24
14.2
Inland navigation ADN/ADNR:
14.3
Transport by sea IMDG/GGVSea: IMDG/GGVSea-class : 8 UN-No.: 3259 Packaging Group: III EmS: F-A,
S-B MFAG: Marine pollutant: Please observe chap. 3.2! Correct technical name: AMINES, SOLID; CORROSIVE,
N.O.S. Remarks: For limited quantities: 5 KG (Netmax. Per inner package)
14.4
Air transport ICAO/IATA: ICAO/IATA-class: 8 UN-No.: 3259 Packaging Group: III
Correct technical name: AMINES, SOLID; CORROSIVE, N.O.S.* Remarks: For limited quantities:
Y822 (5 KG Netmax. per package)
14.5
Transport/further Please contact Mr. Peter Glaser; telephone: ++49 7443/12-1535.
information Mobile: ++49 (170) 2271868
15. Regulations
15.1 Labelling according to EC Directives/Gefahrstoffverordnung:
Component A: Classification according diretive 1999/45/EG
15.1.1 Symbol(s) and indication(s) of danger:
Xi — Irritant
N - Dangerous for the environment
15.1.2 Hazard-determing component(s) for labelling:
Contains:
Bisphenol-A-Epichlorhydrine
25068-38-6 Portlandcement, CAS-Nr. 65997-15-1
15.1.3 R-Phrases:
resin,
CAS-Nr.
CAS — No.
EWG-No.
Material
Content [%]
Symbol
25068-38-6
500-033-5
Bisphenol-A-Epichlorhydrin resin
< 35
Xi, N
Epoxy resin
< 15
Xi, N
Portlandcement according to TRGS 613
< 40
Xi
Content [%]
Symbol
28064-14-4
65997-15-1
CAS — No.
-266-043-4
EWG-No.
Material
R- Phrases
36/38, 43,
51/53
36/38, 43,
51/53
38, 41
R- Phrases
20/22, 34,
1477-55-0
216-032-5
m-Xylylendiamine
< 40
C
52/53
R 43 May cause
sensitisation
by skin contact. R 51/53 Toxic to aquatic organisms,
80-05-7
201-245-8
4,4’-Isopropylidendiphenol
< 10may cause long-term
Xi
36/37/38, 43
adverse effects
in the aquatic
environment.according to TRGS 613
65997-15-1
266-043-4
Portlandcement
< 20
Xi
38, 41
Handling
and storage
15.1.4
S-Phrases:
7
.
7.1.1
S 24 Avoid contact with skin. S 26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. S 61 Avoid release to the
environment. Refer to special instructions/safety data sheets.
7.1 Handling:
Information for safe handling:
Avoid contact with eyes and skin. Do not breathe vapour. Provide good
ventilation. If necessary use local exhaust ventilation. Ensure that the
Component B: Classification according
diretive 1999/45/EG
occupational
exposure limits are kept when working with the product.
7.1.2 Symbol(s) and indication(s) of danger:
15.1.1
Information about protection
Observe the general rules for fire prevention. Keep product away from heat
against explosions and fires:
sources, open fires, etc., do not smoke.
7.2 Storage:
7.2.1
Requirements to be met by
storerooms and receptables:
Keep cartridge tightly sealed in its original package and store in a dry, cool
(max. 25 …C) and well ventilated place.
7.2.1
C — storage
Corrosive Do not store together with acids, alkali or oxidizing agents.
Rules for the mixed
of chemicals:
15.1.2 Hazard-determing component(s) for labelling:
7.2.3
Further information about
Keep away from foodstuffs, beverages and animal feedstocks. Prevent from
Contains:
m-Xylylendiamine,
1477-55-0
storage conditions:
heatCAS-Nr.
and direct
sunlight.
4,4’-Isoprpylidendiphenol, CAS-Nr. 80-05-7
7.2.4 Storage class:
8 according to VCI guideline.
Material
Content
Type
mg/m_
ppm
Fibre/m_
15.1.3 R-Phrases:
[%]
(F/G)
CAS — No.
1477-55-0
alpha,alpha
-Diamino-1,3-xylol,
R 20/22 Harmful
by inhalation
and if swallowed. R 34
Causes burns.
cause sensitization
by skin< 40
MAK R 43 May
0,1
m-Phenylenbis(methylamin)
contact. R 52/53
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
80-05-7
4,4’-Isopropylidendiphenol
< 15
MAK
5
environment.
10. Stability and reactivity
15.1.4 S-Phrases:
10.1 Conditions to be avoided:
No decomposition if used as prescribed.
S 24
Avoid contact with skin.
26
Intocase
of contact with eyes, rinse immediately with plenty of water and seek medical advice.
10.2 SMaterials
be avoided:
Dangerous reactions witth isocyanate, anhydrides, acids, oxidizing agents.
S 36/37/39
Wear suitable protective clothing, gloves and eye/face protection.
10.3 S 45
Nitrogen
oxides seek
(N0x).medical advice immediately (show the lable where
In case of accident or if you
feel unwell,
Hazardous decomposition
possible).
products:
S 61
Avoid release to the environment. Refer to special instructions/safety data sheets.
10.4 Further information:
-15.1.5 Special designations for certain preparations:
11. Toxicological
information
Contains epoxy
constituents. See information supplied by the manufacturer.
11.1
toxicity:
LD50/LC50
values which are relevant for classification: The product has not been tested.
15.2Acute
National
regulations
(Germany):
15.2.1 Indications for employment control: Observe ⁄ 22 Jugendarbeitschutzgesetz
11.2 Specific symptoms in animal studies: The product has not been tested.
15.2.2 Regulations for incidents:
11.3 Irritant effects: On contact with the skin or the respiratory organs irritation is possible.
15.2.3 Giscode:
RE 1
11.4 Sensitization:
Sensitization
possible
on contact with skin. Contact with skin may induce allergic eczemas.
15.2.4
Technical instructions
(Air):
-15.2.5 Water hazard class: 2 (VwVwS)
11.5 Effects after repeated or longtime Exposition: The product has not been tested.
15.2.6 Further regulations: -15.2.7
Limitations and
prohibition
regulations:
-11.6 Carcinogenic,
mutagenic,
teratogenic
or dangerous
effects on fertility: No.
11.7 Further toxicological information: Information concern to the main components.
13. Disposal consideration
13.1
Product:
Material Safety Data Sheet
(according to ⁄ 14 GefStoffV and Directive 91/155/EEC) fischer
th
Injection Mortar FIS EM 390 S Article number:
th
93048/93049 Prepared on: 11/13 /2003 Reviewed on: 01/15 /2004 Printing date: 27.04.2006 Version: 1.1 Page: 7 of
7
16. Other information
16.1
Further information: The above information describes exclusively the safety requirements of the product(s)
and is based on our present knowlegde. It does not represent a guarantee for the properties of the product(s) described
in terms of the legal warranty regulations. Properties of the product are to be found in the repective product leaflet.
16.2
Department issuing MSDS: Department T-C (Environment and Safety) Fischer Group of
companies, location Denzlingen
16.3
Contact: Mr. Werner Sch uble; see chapter 1
16.4
Full text of the R-Phrases in chapter 2: R 20/22 Harmful by inhalation and if swallowed. R 34 Causes burns. R
36/38 Irritating to eyes and skin. R 38 Irritating to eyes. R 36/37/38 Irritating to eyes, respiratory system and skin. R 41 Risk
of serious damage to eyes. R 43 May cause sensitisation by skin contact. R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment. R 52/53 Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
16.5
Alterations have been made in chapter: 14