Ciência sem Fronteiras (Science Without Borders) PhD Project Template: PI name & contact details: Prof Noel Buckley noel.buckley@UL.ie Department Physics and Energy http://www.energy.ul.ie/ Has project been agreed with head (or nominee) of proposed registration school? Yes Research Centre / group affiliation: Materials and Surface Science Institute (MSSI) Research group / centre website: http://www.ul.ie/mssi PI website / link to CV: http://www.energy.ul.ie/people/faculty/prof-d-n-noelbuckley Brief summary of PI research / research group / centre activity (2 or 3 lines max): Professor Buckley is a Past-President of the Electrochemical Society http://www.electrochem.org and has over 30 years experience of electrochemistry and materials and their application to technology. His areas of research include electrochemical nanotechnology, electrochemical energy storage and thin films and nanostructures for electronic and photonic applications. Title & brief description of PhD project (suitable for publication on web): The influence of substrate grain orientation on intrinsic stress in electrodeposited metal nanofilms. Electrodeposited metal nano-films are used in numerous technologies such as the IC industry and in decorative platings. As the deposited film dimensions decrease, size-effects such as delamination and variations in film properties become more prevalent. This project aims to develop an understanding of the links between substrate grain orientation and intrinsic stress in electrodeposited metal nanofilms. In-situ stress and in-situ AFM investigations will be used to study the evolution of stress and morphology during film growth. These techniques will be combined with atomic scale modelling to determine the effect of substrate orientation on subsequent film deposition, in particular on the evolution of stress in the deposited nanofilm. Unique selling points of PhD project in UL: The University of Limerick (UL) with over 11,500 students and 1,300 staff is an energetic and enterprising institution with a proud record of innovation and excellence in education, research and scholarship. It is widely recognized for the outstanding student experience it offers to all its students, the excellence of its research and the impact it is making on our society and our economy. In 2011 UL, was independently evaluated by the international university rating agency QS Stars and was awarded the maximum 5-star rating in 6 categories namely, teaching, engagement, internationalization, innovation and knowledge transfer, infrastructure, and employability of UL graduates. UL's Materials and Surface Science Institute is an internationally recognized center of excellence. Name & contact details for project queries, if different from PI named above Please indicate the graduates of which disciplines that should apply: Physics, Chemistry, Materials Science & Engineering, Electrical, Mechanical, or Chemical Engineering Please indicate whether students can apply for: Sandwich programme only Full PhD programme only Either of the above x Ciência sem Fronteiras / Science Without Borders Priority Area: Please indicate the specific programme priority area under which the proposed PhD project fits- choose only one (tick box): Engineering and other technological areas Pure and Natural Sciences (e.g. mathematics, physics, chemistry) Health and Biomedical Sciences Information and Communication Technologies (ICTs) Aerospace Pharmaceuticals Oil, Gas and Coal Renewable Energy Minerals Biotechnology Nanotechnology and New Materials x Technology of prevention and remediation of natural disasters Biodiversity and Bioprospection Marine Sciences Creative Industry New technologies in constructive engineering