AP Chemistry Syllabus AP Program Two-period, 90-minute block session, time generally allocated to scientific inquiry based laboratory work. Three standard, 45-minute recitation-oriented class periods. One weekend session, 120-minute Early-morning,15 minutes sessions each class meeting day Ten students are enrolled in the 2010-2011 AP Chemistry section, and work in three or four student groups during classes involving laboratory-based scientific inquiry, or requiring collaborative learning. Teaching Strategies For most students a course in AP Chemistry will provide some of the greatest intellectual challenges of their high school and early college career. This course is taught with two goals in mind: Students will learn more chemistry than they did in their first-year course and build upon their understanding of chemical concepts. Students will prepare to take AP Exam in May. Text Masterton, William L., and Cecile N. Hurley. Chemistry: Principles and Reactions. Pacific Grove, CA: Brooks/Cole Thomson Learning. Theoretical Chemistry Emphasis The revised “College Board AP Chemistry Course Description, Effective Fall 2010” states in relevant part: “The importance of the theoretical aspects of chemistry has brought about an increasing emphasis on these aspects of content of general chemistry courses. Topics such as the structure of matter, kinetic theory of gasses, chemical equilibria, chemical kinetics, and the basic concepts of thermodynamics are now being presented in considerable depth.” Laboratory The AP Chemistry Laboratory has been restructured to do 32 experiments, including each and every one among the 22 experiments recommended by the College Board. The content falls into categories that reflect the appropriate balance between theoretical chemistry and traditional general chemistry content: States of Matter and Molecular Interactions (6 experiments) Heats of Fusion and Vaporization Exploring Gas Laws Determination of Molar Mass by Vapor Density Determination of the Molar Volume of a Gas Separation by Chromatography Molecular Interaction Between Molecules Quantities and Reactions (11 experiments) Determination of the Formula of a Compound Determination of the Percentage of Water in a Hydrate Determination of Mass and Mole Relationship in a Chemical Reaction Separation and Qualitative Analysis of Cations and Anions Synthesis of a Coordination Compound and its Chemical Analysis Analytical Gravimetric Determination Determination of Electrochemical Series Measurements Using Electrochemical Cells and Electroplating Synthesis, Purification and Analysis of an Organic Compound Conductometric Titration The Breathalyzer Test for Alcohol Solutions (5 experiments) Determination of Molar Mass by Freezing-Point Depression Standardization of a Solution using a Primary Standard Determination of Concentration by Acid Base Titration Determination of Concentration by Oxidation Reduction Titration Determination of Appropriate Indicators for Various Acid Base Titration Chemical Thermodynamics (2 experiments) Determination of Enthalpy Change Associated with a Reaction Heats of Fusion and Vaporization Light and Matter (2 experiments) Absorption Spectra Colorimetric Analysis Kinetics and Equilibrium (6 experiments) Determination of Kas of a Multiprotic Acid Determining Ka by Half Titration of a Weak Acid Determination of Solubility Product Constant Preparation and Properties of Buffer Solutions Determination of the Rate of a Reaction and its Order Determination of the Equilibrium Constant for a Chemical Reaction LABORATORY REPORTS Passing the AP Chemistry Examination is to many University Chemistry Departments not in itself sufficient evidence that a student has completed the equivalent of a college general chemistry course. A robust course must include a strong laboratory science component as described above, and the student must document the requisite laboratory work in an experiment portfolio. In consonance with that need, students purchase a 31 Tab portfolio at the start of the course and are required to maintain that portfolio by entering both (1) Laboratory Reports and (2) Cogent material from the Laboratory Notebook. (1) Laboratory Reports. Formal typed laboratory reports, one-by-one as they are performed, graded and returned, written in an objective, technical form using the passive past tense. The report must include: Title/Source/Partner Name/Date: Abstract: Write short paragraphs, using simple declarative sentences that briefly summarize the purpose and procedure of the experiment, including a brief description of the results. The procedure must note significant departure from what was originally planned and documented in the lab notebook. What actually happens is sometimes a departure from the original plan. Results and Discussion: State the results of the experiment and list any results from evaluation methods used (i.e. Pasco probe-type instruments and ancillary data studio application software ). Compare the results with standard values and list the percent error (when applicable). State whether the results were unexpected and hypothesize sources of error related to the data you collected that would have caused these experimental results. Propose what might be changed to avoid these errors. Answers to Questions: Rewrite the analysis/conclusion questions from the lab sheet and then answer each question . References: Cite reference material, if applicable. If it’s a handout from your teacher, simply list it as a handout from the instructor. (2) Laboratory Notebook. Notebook excerpts must include: Chemical Reaction: List the balanced chemical reactions involved in the experiment, if applicable. List of Materials: Include a list of materials needed to complete the experiment. Procedure: In your own words, write the directions for the experiment in a numbered step-by-step list. Write the procedures with enough detail that experiments could be reproduced from what is written. Do not include the detailed procedures involved in calibrating and preparing probe-type instruments. Data Table(s) and Graphs. The required information from the experiment, including the tables completed while conducting the lab, including units for all measurements, as well as the printouts of graphs generated by the Data Studio application software, using information collected via the scientific probes. LAB MANUAL & RELATED INSTRUMENTATION PASCO Scientific’s Advanced Chemistry Lab Manual & Probeware In an AP Chemistry course, classroom time is a precious commodity. For that and other good reasons, including the importance of making theoretical Chemistry related measurements, the AP Chemistry Lab is now equipped with Pasco precision drop counters, absolute pressure sensors, temperature and pH probes, colorimeters, visible, UV and IR light sensors, conductivity probes, and probes to detect various gasses, such as carbon dioxide, and dissolved oxygen. US Government sponsored studies show significant improvements in learning when students have access to this class of equipment. Probe output to automatic digital and analog data processing hardware, allows inputs from up to 5 probes at a time to be processed and output to interactive display software. In addition to time saving, this automation takes the drudgery out of lab work, allowing students to focus on the science as opposed to data recording, manipulation, and plotting. COURSE OUTLINE UNIT-1 Review of Prerequisite Concepts (2.5 weeks) Students lack the recommended prerequisite year of high school chemistry and collateral chemistry lab experience in use of instruments and scientific inquiry. Assessment of prior knowledge Physical attributes of matter Chemical attributes of matter AMUs, Moles & Avogadro’s Number UNIT-2 Atoms, Molecules & Ions (3 weeks, 5.5 total) Early Development of the Atomic Theory of the Atom The Periodic Table of the Elements Molecules and Ions Ionic Compounds & Formulas Naming Conventions UNIT-3 Stoichiometry ( 2 weeks, 7.5 total) Mass Relations in Chemical Formulas Mass Relations in Chemical Reactions UNIT-4 Reactions in Aqueous Solutions (2 weeks, 9.5 total) Solute Concentration and Molarity Precipitation Reactions Acid-base Reactions Oxydation-Reduction Reactions UNIT-5 Gasses (2 weeks, 11.5 total) Measurements on Gasses The Ideal Gas Law Gas Law Calculations Stoichiometry of Gaseous Reactions Partial Pressures and Mole Fractions of Gas Mixtures Real Gasses: Deviation from the Ideal Gas Law UNIT -6 Electronic Structure and the Periodic Table (2.5 weeks, 14 total) Light, Photon Energies and the Atomic Structure The Hydrogen Atom &Mathematical Derivation of the Bohr Model Quantum Numbers Atomic Orbitals Shapes & Sizes Orbital Diagrams of Atoms Electron Arrangements in Monatomic Ions UNIT-7 Covalent Bonding (3 weeks, 17 total) Lewis Structures & The Octet Rule Molecular Geometry Polarity of Molecules Atomic Orbitals: Hybridization UNIT-8 Thermochemistry (3 weeks, 20 total) Principles of Heat Flow Measurement of Heat Flow: Calorimetry Enthalpy Thermochemical Equations Enthalpies of Formation Bond Enthalpy The first Law of Thermodynamics The Second Law of Thermodynamics, Gibbs Free Energy ‘G’ and Spontaneous Reactions UNIT-9 Liquids and Solids (1.5 weeks, 21.5 total) Liquid-Vapor Equilibrium Phase Diagrams Intermolecular Forces Network Covalent, Ionic and Metallic Solids Crystal Structures UNIT-10 Solutions (2 weeks, 23.5 total) Concentration Units Principles of Solubility Colligative Properties of Non-electrolytes Colligative Properties of Electrolytes UNIT-11 Rate of Reaction (2.5 weeks. 26 total) Reactant Rate and Concentration Concentration and Time Reaction Rate Models Reaction Rate and Temperature Catalysts Reaction Mechanisms UNIT-12 Gaseous Chemical Equilibrium (2 weeks, 28 total) The N2O4-NO2 Equilibrium System The Equilibrium Constant Expression Determination of K Application of the Equilibrium Constant Effect of Changes in Conditions on an Equilibrium System UNIT-13 Acids and Bases (2.5 weeks, 30.5 weeks = 1 May 2011) Bronsted-Lowry Acid-Base Model The Ion Product of Water pH and pOH Weak Acids and their Equilibrium Constants Weak Bases and their Equilibrium Constants Acid-Base Properties of Salt Solution