Chapter 3 - MATTER-PROPERTIES AND CHANGES Definitions of Properties Physical properties can be SEEN without CHANGING matter. Chemical properties describe how a SUBSTANCE REACTS with other SUBSTANCES. Examples of Properties Physical properties Chemical properties MALLEABILITY REACTIVITY DENSITY COMBUSTIBILITY COLOR FLAMMABILITY SOLUBILITY ACIDITY MASS Phases of Matter Solids - DEFINITE shape & DEFINITE volume particles PACKED TOGETHER Liquids - INDEFINITE shape & DEFINITE volume particles have ROOM to MOVE Gases - INDEFINITE shape & INDEFINITE volume particles FAR APART Types of Changes Physical change -NO CHANGE in IDENTITY of substance Chemical change-ONE or more NEW substances produced Phase changes are PHYSICAL CHANGES. Freezing point— LIQUID to SOLID Melting point— SOLID to LIQUID FREEZING point = MELTING point Boiling point— LIQUID to GAS Condensation point— GAS to LIQUID Sublimation point— SOLID to GAS Examples of Changes Physical Changes Chemical Changes TEARING COMBUSTION CRUSHING PRODUCTION OF ACID RAIN PHASE CHANGE SUBLIMATION Law of Conservation of Mass—Mass CANNOT be CREATED OR DESTROYED. The Chemistry Quiz CR1.C CR2.D 1.C 2.A 3.D 4.C 5.B Physical Properties INTENSIVE properties depend upon the nature of the substance and are INDEPENDENT of the amount of matter present. Examples are COLOR, DENSITY, MELTING POINT, and FREEZING POINT EXTENSIVE properties describe only the amount of material. Examples are LENGTH, VOLUME, MASS, AREA MALLEABLE means the substance (metal) can be hammered into thin sheets. DUCTILE means the substance (metal) can be pulled into thin wire. Separating by physical means DISTILLATION is a physical change that uses boiling point differences to separate a mixture (usually liquids). PETROLEUM is separated into its components FRACTIONATION column. using a http://www.wwnorton.com/chemistry/tutorials/ch12.htm EVAPORATION is a physical change from a liquid to a gas. In DISSOLVING the solute seems to disappear but has actually broken down into pieces too small to be seen. CRYSTALLIZATION is a separation technique that results in the formation of pure solid particles of a substance from a solution containing the dissolved substance. The solid that comes out of solution is called a PRECIPITATE. CHROMATOGRAPHY is a technique that separates the components of a mixture (called the MOBILE phase) on the basis of the tendency of each to travel or be drawn across the surface of another material (called the STATIONARY phase). http://antoine.frostburg.edu/chem/senese/101/matter/chromatography.shtml http://www.rpi.edu/dept/chem-eng/Biotech-Environ/CHROMO/chroanim.html FILTRATION- the techniques that uses a porous barrier to separate a solid from a mixture. Chemical changes (reactions) In a CHEMICAL change a new with different properties is formed. http://cwx.prenhall.com/bookbind/pubbooks/petrucci8/medialib/media_portfolio/01.html Some signs of a chemical change are: 1. A COLOR change. substance 2. A ENERGY change.(HOT, COLD, LIGHT) 3. The formation of a PRECIPITATE. (substance that CRYSTALLIZES out of solution) 4. The formation of BUBBLES. (GAS produced) ELECTROLYSIS is a chemical change that uses electricity to separate a compound into its elements. Water can be separated into OXYGEN and HYDROGEN by electrolysis. In a CHEMICAL REACTION one or more substances CHANGE into one or more DIFFERENT substances. The starting substances are called REACTANTS. The new substances are called PRODUCTS. When an iron and sulfur mixture is heated it turns into iron sulfide. The reactants are IRON AND SULFUR and the product is IRON SULFIDE. The reaction can be written as iron + sulfur iron sulfide REACTANTS PRODUCT Fe + S FeS In a chemical reaction the mass is always CONSERVED. The mass of the REACTANTS will equal the mass of the PRODUCTS. This is known as the Law of the CONSERVATION of MASS. The Law is attributed to the French scientist ANTOINE LAVOISIER. When mercury(II) oxide is heated in air it decomposes into mercury and oxygen. The sum of the masses of the products EQUALS the sum of the masses of the reactants. The word equation is: MERCURY OXIDE MERCURY + OXYGEN 216 g = 200 g + 16 g Mass of REACTANTS = mass of PRODUCTS http://cwx.prenhall.com/bookbind/pubbooks/petrucci8/medialib/media_portfolio/01.html The Law of Conservation of Mass has been changed slightly to account for changes between MASS and ENERGY. Law of CONSERVATION of MASS and ENERGY mass and energy-The sum of the energy and mass is CONSTANT E = mc2 (c = 3 x 108 m/s) Energy can change into MASS and mass can change into ENERGY but the total massenergy is CONSTANT. Types of Matter Element - PURE substance - ONE kind of ATOM ONE or MORE letter symbol HELIUM (He) 90 elements occur naturally Compound - TWO or more ELEMENTS CHEMICALLY combined -represented by CHEMICAL FORMULA - example: WATER (H2O) -H2O DECOMPOSES into HYDROGEN GAS and OXYGEN GAS. -COMBINES in same PROPORTION Episode 202 Mixture - TWO or more substances PHYSICALLY COMBINED do not COMBINE in same PROPORTION heterogeneous mixture - not UNIFORM homogeneous mixture (solution) - UNIFORM alloy - SOLUTION of two or more METALS Pure SUBSTANCES are HOMOGENEOUS. Matter PURE SUBSTANCE ELEMENT MIXTURE HETEROGENEOUS COMPOUND HOMOGENEOUS E = element S = homogeneous mixture/solution C = compound HE = heterogeneous mixture hydrogen peroxide C carbon E carbon dioxide C carbon monoxide C pizza HE steel S salad dressing HE calcium E rust C lead E apple juice S The Chemistry Quiz CR1._____ CR2._____ 1._____ 2._____3._____ 4._____ 5._____ CHARACTERISTICS OF SOLUTIONS (homogeneous) The part of the solution that is dissolved is called the SOLUTE. The SOLVENT is the part of the solution that does the dissolving. s o l solute e n t Characteristics of solutions 1. Do NOT SCATTER (DIFFUSE) light. 2. Do NOT SETTLE on standing. (suspensions do – muddy water) 3. UNIFORM throughout. (homogeneous) 4. Particles too SMALL to be seen even under an ordinary MICROSCOPE. (atoms, ions or molecules) 5. VARIABLE composition. (they’re mixtures) 6. Could be made of GASES, SOLIDS OR LIQUIDS. (any combination) 7. Can NOT be separated by FILTRATION. (see #4 above) ALLOYS are metal solutions. Ex. BRASS, BRONZE, STEEL [skip a few lines here] MATTER HOMOGENEOUS Uniform SUBSTANCE Definite composition ELEMENT 1 kind of atom HETEROGENEOUS Variable HOMOGENOUS MIXTURE Variable composition 1 phase HETEROGENEOUS MIXTURE Variable composition More than 1 phase aka SOLUTION Uniform COMPOUND Can be chemically broken down to elements More than 1 kind of ATOM Separating Mixtures The components of a mixture may be separated based on the physical properties of: MAGNETISM DENSITY (An instrument that uses this property to separate mixtures when tiny solid particles are dissolved in a liquid is called a CENTRIFUGE.) Some techniques used to separate the components of a mixture are: FILTRATION-used to separate liquids and solids EVAPORATION of solvent, solute remains (eg. Salt crystallizes) DISTILLATION using differences in boiling points to separate liquids Observation Explanation 1.ice cube on left floated ice - less dense than liquid ice cube on right sank -ice more dense than liquid2. Episode 203 2. Egg sank on the left Egg floated on the right 3. Regular soda sank Diet soda floated -more dense than liquid -less dense than liquid -more dense than water -less dense than water Review: The Law of the CONSERVATION of MASS. In a chemical reaction the mass is always CONSERVED. The sum of the masses of the REACTANTS EQUALS the sum of the masses of the PRODUCTS. Use for HW #50-53 p94 Ex #1. From a laboratory process designed to separate water into hydrogen and oxygen gas, a student collected 10.0 g of hydrogen and 79.4 g of oxygen. How much water was originally involved in the process ? massreactants = mass products water hydrogen + oxygen masswater = masshydrogen + massoxygen masswater = 10.0 g + 79.4 g masswater = 89.4 g Ex #2. A student carefully placed 15.6 g of sodium in a reactor supplied with an excess quantity of chlorine gas. When the reaction was complete, the student obtained 39.7 g of sodium chloride. How many grams of chlorine gas reacted? massreactants = masssodium + masschlorine = mass products masssodium chloride The Law of Definite Proportion & Percent by Mass The LAW of DEFINITE PROPORTIONS states that a compound is always composed of the same elements in the same proportion by mass. The percentage by mass of each element in a compound is always the SAME. % by mass = mass of ELEMENT X 100 mass of COMPOUND The mass of the compound = the SUM of the MASSES of its ELEMENTS Ex #1. Magnesium combines with oxygen to form magnesium oxide. If 10.57 g of magnesium reacts completely with 6.96 g of oxygen, what is the percent by mass of oxygen in magnesium oxide? 1. Write out word equation mass magnesium + mass oxygen = mass magnesium oxide 2. Plug in values to get mass of compound 10.57 g + 6.96 g = mass magnesium oxide = 17.53 g 3. solve for percent by mass percentoxygen by mass = (mass oxygen/mass magnesium oxide) X 100 = 6.96 g x 100 = 39.7% 17.53 g The Law of Multiple Proportions The LAW of MULTIPLE PROPORTIONS states that when different compounds are formed by combination of the same elements, different masses of one element combine with the same relative mass of the other element in a small whole number ratio. Copper and chlorine combine to make two different compounds with different properties. Compoun %Cu %Cl Mass of Mass of Mass ratio d I 64.20 35.80 II 47.27 52.73 1.793 g = 2.00 2:1 0.896 g 1 Cu in 100 g of compoun d Cl in 100 mass Cu g of mass Cl compoun d 64.20g 35.80g 35.80g 35.80g 1.793g Cu 1 g Cl 47.27g 52.73g 0.896g Cu 1 g Cl 52.73g 52.73g A small-whole number ratio http://cwx.prenhall.com/bookbind/pubbooks/petrucci8/medialib/media_p ortfolio/text_images/003_MULTIPLEPROP.MOV http://wps.prenhall.com/esm_brown_chemistry_9/0,4647,169061,00.html