Chemistry - End of Third Trimester Exam Review (Chapters 11 – 13) Chapter 11 – Chemical Reactions 11.1 To write a word equation, write the names of the reactants to the left of the arrow separated by plus signs; write the names of the products to the right of the arrow, also separated by plus signs. To write a skeleton equation, write the formulas for the reactants to the left of the yields sign and the formulas for the products to the right. After writing the skeleton equations, use coefficients to balance the equation so that is obeys the law of conservation of mass. 11.2 The five general types of reactions are combination, decomposition, single-replacement, double-replacement, and combustion. The number of elements and/or compounds reacting is a good indicator of possible reaction type and thus possible products. In a combination reaction, there is always a single product. A decomposition reaction involves the breakdown of a single compound into two or more simpler substances. In a single-replacement reaction, both the reactants and the products are an element and a compound. A double-replacement reaction generally takes place between two ionic compounds in aqueous solution. A combustion reaction always involves oxygen as a reactant. 11.3 A net ionic equation shows only those particles involved in the reaction and is balanced with respect to mass and charge. You can predict the formation of a precipitate by using the general rules for solubility of ionic compounds. Vocabulary: Balanced Equation Combustion Reaction Net Ionic Equation Catalyst Complete Ionic Equation Single-Replacement Reaction Chemical Equation Decomposition Reaction Skeleton Equation Coefficients Double-Replacement Reaction Spectator Ion Combination Reaction Chemistry - End of Third Trimester Exam Review (Chapters 11 – 13) Chapter 12 – Stoichiometry 12.1 A balanced chemical equation provides the same kind of quantitative information that a recipe does. Chemists use balanced chemical equations as a basis to calculate how much reactant is needed or product is formed in a reaction. A balanced chemical equation can be interpreted in terms of different quantities, including numbers of atoms, molecules, or moles; mass; and volume. Mass and atoms are conserved in every chemical reaction. 12.2 In chemical calculations, mole ratios are used to convert between moles of reactant and moles of product, between moles of reactants, or between moles of products. In a typical stoichiometric problem, the given quantity is first converted to moles. Then the mole ratio from the balanced equation is used to calculate the moles of the wanted substance. Finally, the moles are converted to any other unit of measurement related to the unit mole. 12.3 In a chemical reaction, an insufficient quantity of any of the reactants will limit the amout of product that forms. The percent yield is a measure of the efficiency of a reaction performed in the laboratory. Vocabulary: Actual Yield Mole Ratio Excess Reagent Percent Yield Limiting Reagent Stoichiometry Theoretical Yield Chapter 13 – States of Matter 13.1 Particles in a gas are considered to be small, hard spheres with an insignificant volume. The motion of the particles in a gas is rapid, constant, and random. All collisions between particles in a gas are perfectly elastic. Gas pressure is the result of simultaneous collisions of billions of rapidly moving particles in a gas with an object. The Kelvin temperature of a substance is directly proportional to the average kinetic energy of the particles of the substance. Chemistry - End of Third Trimester Exam Review (Chapters 11 – 13) 13.2 The interplay between the disruptive motions of particles in a liquid and the attractions among the particles determines the physical properties of liquids. During evaporation, only those molecules with certain minimum kinetic energy can escape from the surface. In a system at constant vapor pressure, a dynamic equilibrium exists between the vapor and the liquid. The rates of evaporation and condensation are equal. At a temperature at which particles throughout a liquid have enouch kinetic energy to vaporize, the liquid begins to boil. 13.3 The general properties of solids and the shapes of crystals reflect the orderly arrangement and the fixed locations of particles within the solids. 13.4 Sublimation occurs in solids that have vapor pressures that exceed atmospheric pressure at or near room temperature. Conditions of pressure and temperature at which two phases exist in equilibrium are indicated on a phase diagram by a line separating the two regions representing the phases. Vocabulary: Allotrope Glass Sublimation Amorphous Solid Kinetic Energy Triple Point Atmospheric Pressure Kinetic Theory Unit Cell Barometer Melting Point Vacuum Bioling Point Normal Boiling Point Vaporization Crystal Pascal (Pa) Vapor Pressure Evaporation Phase Diagram Gas Pressure Standard Atmosphere