Republic of Zambia ZAMBIA HIGH SCHOOL EDUCATION SCIENCE HIGH SCHOOL SYLLABUS GRADES 10 – 12 Prepared by: Curriculum Development Centre P.O. Box 50092 LUSAKA © Curriculum Development Centre All rights are reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying recording or otherwise, without the prior consent of the copyright owners. i CONTENT Preface.................................................................................................................................................................... Acknowledgements................................................................................................................................................ Introduction ........................................................................................................................................................... v vi vii 1 Unit 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 GENERAL PHYSICS ......................................................................................................... Length and time ..................................................................................................................... Speed, velocity and acceleration ............................................................................................ Mass and weight .................................................................................................................... Density ................................................................................................................................... Forces ..................................................................................................................................... Simple Machines .................................................................................................................... Energy work and power ......................................................................................................... 1 1 1 2 2 3 3 Unit 2.0 THERMAL PHYSICS ......................................................................................................... 2.1 Simple kinetic theory of matter.............................................................................................. 2.2 Thermal properties ................................................................................................................ 2.3 Transfer of thermal energy ................................................................................................... 5 5 5 6 Unit 3.0 PROPERTIES OF WAVES ................................................................................................ 3.1 General wave properties, including light and sound .............................................................. 3.2 Light ....................................................................................................................................... 7 7 7 ii Unit 4.0 4.1 4.2 4.3 4.4 4.5 4.6 ELECTRICITY AND MAGNESTISM ............................................................................ Simple phenomena of magnetisms ....................................................................................... Electricity............................................................................................................................... Electric circuits ...................................................................................................................... Practical electric circuits ........................................................................................................ Electromagnetic effects .......................................................................................................... Introductory ............................................................................................................................ 8 8 8 8 8 9 9 Unit 5.0 ATOMIC PHYSICS ............................................................................................................ 5.1 Radioactivity .......................................................................................................................... 5.2 The nuclear atom ................................................................................................................... 11 11 11 Unit 6.0 PARTICULATE NATURE OF MATTER ....................................................................... 6.1 Matter ..................................................................................................................................... 6.1 Kinetic .................................................................................................................................... 12 12 12 Unit 7.0 EXPERIMENTAL TECHNIQUES .................................................................................. 7.1 Measurement ......................................................................................................................... 7.2 Purity ..................................................................................................................................... 13 13 13 Unit 8.0 ATOMS, ELEMENTS AND COMPOUND ...................................................................... 8.1 Atomic structure and the periodic table ................................................................................. 8.2 Bonding, the structure of matter ............................................................................................ 8.3 Formulae and equations ........................................................................................................ 14 14 14 15 Unit 9.0 9.1 9.2 16 16 16 ACIDS, BASES AND SALTS ............................................................................................ Acids and bases ..................................................................................................................... Types of oxides ..................................................................................................................... iii Unit 10.0 THE PERIODIC TABLE .................................................................................................. 10.1 Periodic trends .................................................................................................................... 10.2 Group properties ................................................................................................................. 10.3 Noble gases ......................................................................................................................... 17 17 17 17 Unit 11.0 11.1 11.2 11.3 METALS ............................................................................................................................. Properties of metals .............................................................................................................. Reactivity series ................................................................................................................... Extraction and uses of metals .............................................................................................. 18 18 18 18 Unit 12.0 AIR AND WATER ........................................................................................................... 12.1 Water ................................................................................................................................... 12.2 Air ........................................................................................................................................ 19 19 19 Unit 13.0 13.1 13.2 13.3 13.4 13.5 13.6 13.7 13.8 21 21 21 21 21 21 21 21 21 ORGANIC CHEMISTRY ................................................................................................. Name of compounds ............................................................................................................ Homologous series ............................................................................................................... Fuels ..................................................................................................................................... Alkenes ................................................................................................................................ Alkenes ................................................................................................................................ Alcohol ................................................................................................................................ Acids .................................................................................................................................... Macromolecules ................................................................................................................... iv PREFACE The review of this Syllabus was necessitated by the need to improve the quality of education at High School Level as stipulated in the national policy document “Educating Our Future - 1996”. Quality education raises the standard of living for all. This leads to sustainable national development. The syllabus also addresses issues of national concern such as Environmental Education, Gender and Equity, Health Education and HIV/AIDS, Family Life Education, Human Rights, Democracy, Reproductive Health, Population Education, Entrepreneurship and Vocation Skills, Life and Values Education. Another reason for revising this syllabus was to fully localize the High School Examinations which were formerly set by University of Cambridge Local Examinations Syndicate, UK. It is hoped that this syllabus will provide the users with a sound premise on the basis of which meaningful and effective learning experiences will be developed in order to provide a good foundation for further study of this subject area. James Mulungushi (Dr.) PERMANENT SECRETARY MINISTRY OF EDUCATION LUSAKA-ZAMBIA v ACKNOWLEDGEMENTS The Curriculum Development Centre wishes to pay tribute to various people, committees, institutions and organizations such as the Ministry of Environment and Natural Resources through the Environmental Education Programme for Awareness (EEPA) for giving much valuable time and generous financial support to facilitate the production of this syllabus. vi INTRODUCTION This syllabus is designed for Grades 10-12. It is intended for pupils not taking Chemistry and Physics as separate subjects. General Aims The syllabus aims at providing, through well designed studies of experimental and practical science, a worthwhile educational experience for all the pupils taking the course, whether or not they go on to study science beyond High School level, thereby, contributing to pupils’ general education by using the impact of known applications of science concepts and principles on society. This is intended to enable pupils acquire adequate understanding and knowledge so that they can: become confident citizens in a technological world, able to make appropriate decisions in scientific matters; recognise the usefulness and limitations of the scientific method and, furthermore, appreciate its applicability in everyday life; suitably prepare for studies beyond High School level in Science. The course also aims at developing the following in the pupils: abilities and skills that - are relevant to the course and practice of science; - are useful in everyday life; - encourage efficient and safe practice; - encourage effective communication; - attitudes relevant to science; for example accuracy and precision; objectivity; integrity; enquiry; initiative; and inventiveness. vii Furthermore, the course aims at stimulating interest in and care for the environment and promotes an awareness that the: study and practice of science are co-operative and cumulative activities that are subject to social, economical, technological, ethical and cultural influences and limitations; applications of science can be both beneficial and detrimental to the individual, to the community, society and the environment. In addition to the content objectives, objectives under the following should be achieved by pupils: Knowledge with understanding They should demonstrate knowledge and understanding in relation to the following: - Scientific phenomena, facts, laws, definitions, concepts, theories; Scientific vocabulary, terminology, conventions; symbols, quantities and units; Scientific instruments and apparatus, including techniques of operations and aspects of safety; Scientific quantities and their determination; Scientific and technological applications with their social, economic and environmental implications. Handling information and solving problems In words or using symbolic, graphical and numerical forms they should be able to: - locate, select, organise and present information from a variety of sources; translate information from one form to another; manipulate numerical and other data; use information to identify patterns, reports trends and draw inferences; present reasonable explanations for phenomena, patterns and relationships; make predictions and propose hypotheses; and solve problems. viii Experimental skills and investigations As the pupils study Science they should be able to: - follow a sequence of instructions; use techniques, apparatus and materials; make and record observations, measurements and estimates; interpret and evaluate observations and experimental results; plan an investigation, select techniques, apparatus and materials; and evaluate methods and suggest possible improvements. General Structure of the syllabus This syllabus is divided into 13 units. The sequence of the Units is not intended to suggest a teaching order. It is hoped that teachers will be flexible when planning their lessons. Each of the units is described under the headings of “Content”, “Objectives” and “Notes”. The column headed “Notes” is intended as an extension and illustration of the objectives and is not to be regarded as exhaustive. The teacher can extend it by relating the factual contents and objectives of the syllabus to social, economic and industrial life at both national and local levels as appropriate as possible. It is envisage that an experimental approach will be adopted and that pupils spend adequate time on individual experimental work. Mathematical Requirements The study of Science through this syllabus strengthens the applications of mathematical skills. It is assumed that the pupils are competent in the following mathematical techniques: taking accurate accounts of numerical work and handling calculations so that significant figures areneither lost unnecessarily nor carried beyond what is justified; making approximate evaluation of numerical expressions; ix formulating simple algebraic equations as mathematical models and be able to solve them; changing the subject of a formula; expressing small changes or errors as percentages; calculating areas of various shapes; dealing with vectors in all simple forms; plotting results graphically after selecting appropriate variables and scales; interpreting, analysing and translating graphical information; making calculations involving additions, subtraction, multiplication and division of quantities; expressing small fractions as percentages and vice versa; calculating an arithmetic mean; transforming decimal notation to power of ten notation (standard form); use tables or calculators to evaluate logarithms (for calculations), squares, square roots and reciprocals; changing the subject of an equation. (these may involve simpler operations that may include positive and negative indices and square roots); substituting physical quantities into an equation using consistent units so as to calculate one quantity (e.g. the units of a rate constant K); solving simple algebraic equations; comprehending and using the symbols/notations; testing tabulation pairs of values for direct proportionality by graphical method or by constancy of ratio; Examination Assessment objectives will be weighed as follows: knowledge with understanding, approximately 65% and recall approximately 30% of the marks; Handing information, approximately 35% of the marks. x Learners are expected to enter for Paper 1, 2 and 3 Paper Type of Paper Duration Mark 1 Multiple-choice 1 hr 40 2 Theory (Physics) 1 hr 15 min 65 3 Theory (Chemistry) 1 hr 15 min 65 Paper 1 (h; 40 marks) Paper 1 will contain forty multiple-choice questions. These will cover approximately equal parts of the Physics and Chemistry Sections of the syllabus. Paper 2 (11/4h; 65 marks) Section A of this paper will contain a number of compulsory short-answer and structured questions. Section B of this paper will contain three free-response questions of 10 marks each (Candidates will answer any two of these questions). Part 3 (11/4h; 65 marks) Section A of this paper will contain a number of compulsory short-answer and structured questions. Section B of this paper will contain three free-response questions of 10 marks each (Candidates will answer any two of these questions). xi 1.0 GENERAL PHYSICS CONTENT OBJECTIVES (Pupils should be able to) 1.1 Length and 1.1.1 state the basic unit for length and time. time 1.1.2 use rules, micrometers, vernier scales and callipers to determine lengths. 1.1.3 describe how to use rules, micrometers, vernier scales and callipers to determine lengths. 1.1.4 use clocks and other devices for measuring an interval of time, including the period of pendulum. 1.1.5 describe how to use clocks and other devices for measuring an interval of time. NOTES Refer to metre and the second (SI units, symbols their abbreviation; length, m, time, t). 1.2 Speed, velocity 1.2.1 state what is meant by distance, displacement, and speed, velocity and acceleration. acceleration 1.2.2 recognise motion for which acceleration is constant. 1.2.3 recognise motion for which the acceleration is not constant. 1.2.4 interpret graphical representation of distance, displacement, speed, velocity and acceleration. 1.2.5 recognise from the shape of a speed-time graph when a body is: (i) at rest; (ii) moving with constant speed; (iii) moving with constant acceleration. 1.2.6 solve problems of motion from first principles and graphs. 1.2.7 use the three basic equations of uniformly accelerated motion. Include simple equations limited to uniform acceleration (SI units, symbols; s, x, d, u, v, w, c, a, g, -m, ms-1, ms-2. Use of ticker-tape timer to show uniform and none uniform motion. 1 Refer to length, m; time, s use of clocks, millisecond timers including time intervals of the pendulum. Knowledge of graphical representations. Both uniform and non uniform motions. Refer to solutions. numerical problems and graphical CONTENT OBJECTIVES (Pupils should be able to) 1.3 Mass and 1.3.1 Explain that mass is a measure of the amount of weight substance in a body. 1.3.2 Explain the concept of weight. 1.4 Density 1.3.3 Demonstrate understanding that two weights, and therefore masses, may be compared using a balance. 1.3.4 use appropriate balances to measure mass and weight. 1.3.5 determine centre of mass of an object. 1.3.6 describe qualitatively the effect of the position of the centre of mass on the stability of an object. 1.4.1 Measure volume of liquids. 1.4.2 Measure volume of regular and irregular solids. 1.4.3 Determine densities of various substances including air polluted substances. 1.4.4 Calculate densities of various substances including air. 1.5 Forces 1.5.1 State that a force may produce a change in size and shape of a body. 1.5.2 Plot, draw and interpret extension-load graphs, and describe the associated experimental procedure. 1.5.3 Explain mass as a measure of inertia. 1.5.4 Describe the ways in which a force may change the motion of a body. 1.5.5 Derive the relationship between force, mass and acceleration. 1.5.6 Describe the effects of friction on the motion of the body. 2 NOTES Refer to W and N. As the effect of gravitational field on mass. Explain clearly the difference between mass and weight.. By using measuring cylinder, pipette and burette for liquids (SI units, Vv, m3). Using displacement and calculation methods. Use of density bottles. Refer to change of density of polluted substances e.g. air and water. Qualitative treatment leading to equation F = ma. Refer to methods of friction reducation. CONTENT OBJECTIVES (Pupils should be able to) 1.5.7 Describe qualitatively the motion in a curved path due to a perpendicular force. 1.5.8 Describe the moment of a force in terms of its turning effect and give everyday examples. 1.5.9 Perform and describe an experiment to verify the principle of moments. 1.5.10 Make calculations involving the principle of moments. 1.6 Simple machines 1.6.1 Explain what is meant by a machine. 1.6.2 Describe the different types of simple machines NOTES F = MV2 is not required. r As many examples as possible. Include levers, pulleys, inclined planes and gear wheels. 1.6.3 Calculate mechanical advantage (MA), velocity ratio (V.R) and efficiency of machines. 1.7 Energy, work and power 1.7.1 Explain qualitatively and quantitatively the terms gravitational potential and kinetic energy including the conservation of energy. 1.7.3 Give examples of energy in different forms, its conservation and conservation, and apply the principles of energy conservation to simple examples. 3 Include example from everyday life on work done by and against force Work (W) = f x d (J), energy (E) (J) PE (J), KE (J), Power (P) = E/t (W). CONTENT OBJECTIVES (Pupils should be able to) 1.7.3 Describe and express a qualitative understanding of processes by which energy is converted from one form to another , including reference to: (i) chemical/fuel ( a re-grouping of atoms), NOTES Refer to the release of toxic fuels on the environment. (ii) hydro-electric generation (emphasising the mechanical Refer to Kariba and Itezhi-tezhi and effects energies involved), on the environment. (iii) Solar energy (nuclei of atoms in the sun), (iv) nuclear energy. Refer to constant exposure to radiation (v) geothermal energy. Refer to SADC countries. (vi) wind energy. Refer to wind. Include green house effect and deforestation. 1.7.4 Discuss the effects of the use of energy sources on Numerical problems involving mg and 1/2 the environment. mv2. 1.7.5 Describe the effect of nuclear energy on human Refer to nuclear materials like uranium. beings. 4 2.0 THERMAL PHYSICS 2.1 CONTENT Simple kinetic theory of matter OBJECTIVES (Pupils should be able to) 2.1.1 Explain the assumption of the kinetic theory. 2.1.2 Describe qualitatively the molecular model of matter. 2.1.3 Apply assumptions of the kinetic theory to explain rates of diffusion, Brownian motion, evaporation and cooling effect of evaporation. 2.1.4 Apply assumptions of the kinetic theory to explain gas pressure. 2.1.5 Demonstrate the effect of varying pressure on volume leading to Boyle’s law. 2.2 Thermal properties 2.2.1 Describe qualitatively the thermal expansion of solids, liquids and gases. 2.2.2 Identify and explain some of the everyday applications and consequences of thermal expansion. 2.2.3 Explain how a physical property which varies with temperature may be used for the measurement of temperature and state examples of such properties. 5 NOTES Structure of solids, liquids and gases in terms of forces, motion and arrangement of molecules (States of matter). Applications of the kinetic theory. Demonstrate experimentally diffusion and Brownian motion. Include relative rates in liquids and gases. Include the dangers of diffusion of toxic wastes from manufacturing industries. Refer to the dangers of explosions of waste gas carnisters (cylinders under pressure e.g. spray cans fire extinguishers). Verify Boyle’s law (PV = Const). experimentally. Refer to linear, area and volume expansion. Volcanoes and their impact on environment, avalanches, road and building collapses in Lusaka. Change in density and convection currents. Effects of expansion of water on aquatic life. Volume increase and weight remain constant. e.g. mercury and alcohol. Dangers of spilled mercury and safer disposal. - Refer to spilt mercury from mercury thermometers. - Proper disposal of mercury. CONTENT 2.2.4 2.2.5 2.2.6 2.2.7 2.2.8 OBJECTIVES (Pupils should be able to) NOTES Recognise the need for, and identify, fixed points. Show understanding of sensitivity and range. Describe the structure and action of liquid-in-glass Refer to laboratory and clinical thermometers. thermometers. Deduce the relationship between temperature and volume. Verify Charles law (V = Constant) T Explain the Kelvin scale from the relationship between By graphical extrapolation. temperature and volume. 2.2.9 Apply the ideal gas equation to solve simple numerical PV/T = Constant problems. 2.3 Transfer of thermal energy 2.3.1 Describe experiments to distinguish good from bad conductors of heat. 2.3.2 Relate convection in fluids to density changes and describe experiments to illustrate convection. 2.3.3 Describe experiments to distinguish between good and bad emitters and good and bad absorbers of infra-red radiation. 2.3.4 Identify and explain some of the everyday applications and consequences of conduction, convection and radiation. 2.3.5 Discuss the effect of radiations on human population. 6 Refer to ozone depletion-global warming. Refer to global warming and ozone depletion. Refer to natural currents which causes seasons. Refer to radiations. 3.0 PROPERTIES OF WAVES CONTENT 3.1 General wave properties including light and sound OBJECTIVES (Pupils should be able to) 3.1.1 Describe what is meant by wave motion. NOTES Refer to vibrations in ropes, strings. Carry out experiments using a ripple tank. 3.1.2 Give the meaning of speed, frequency, wave length and amplitude and use the equation c = fʎ 3.1.3 Describe an experiment to determine the speed of sound in Refer to sound pollution as emitted air and make necessary calculations. by planes. 3.2 Light 3.2.1 Perform and describe experiments to illustrate the laws of reflection. 3.2.2 Describe an experiment to find the position of an optical image formed by a plane mirror. 3.2.3 Use the law i = r in reflection. 3.2.4 Perform simple constructions, measurements ad calculations. 3.2.5 Describe and perform experiments to demonstrate refraction of light through glass blocks. 3.2.6 Use the terminology for the angles i and r in refraction and describe the passage of light through parallel-sided transparent material. 3.2.7 Use the equation sin i/sin r = n (refractive index). 3.2.8 Give meaning of refractive index. 3.2.9 Describe the action of a thin converging lens on a beam of light. 3.2.10 Describe the main components of the electromagnetic Refer to harmful effects of E.M. waves. spectrum and state that all e.m. waves travel with the same high speed in a vacuum and state the magnitude of this speed. 7 4.0 ELECTRICITY AND MAGNETISM CONTENT 4.1 Simple phenomena of magnetism 4.2 Electricity 4.3 Electricity circuits OBJECTIVES (Pupils should be able to) NOTES 4.1.1 State the properties of magnets. 4.1.2 Give an account of induced magnetism. Refer to dangers of lightening. 4.1.3 Distinguish between magnetic and non-magnetic materials. 4.1.4 Distinguish between the magnetic properties of iron and steel. 4.1.5 Distinguish between the design and use of permanent magnets and electromagnets. 4.2.1 Demonstrate that there are positive and negative charges. 4.2.2 Explain that unlike charges attract and that like charges repel. 4.2.3 Show understanding that a current is a rate of flow of charge and is measured in amperes. 4..2.4 Use the equation I = Q/t. 4..2.5 Use and describe the use of an ammeter. 4.2.6 Use the concept that the e.m.f. is measured by the energy dissipated by a current in driving charge round the complete circuit. 4.2.7 Show appreciation that the volt is given by J/C. 4.2.8 Explain that the potential difference across a circuit component is measured in volts. 4.2.9 Use and describe the use of voltmeter. 4.2.10 State that resistance = p.d./current and use the equation R=V T 4.3.1 Draw and interpret circuit diagrams containing sources, switches, resistors (fixed and variable), ammeter, voltmeters. 4.3.2 Explain that the current at every point in a series circuit is the same. 4.3.3 Use the fact that the sum of the p.d.’s in a series circuit is equal to the p.d. across the whole circuit. 8 CONTENT 4.3.4 4.3.5 4.4 Practical electricity circuits 4.4.1 4.4.2 OBJECTIVES (Pupils should be able to) Calculate the combined resistance of two or more resistors in series and in parallel. Use the fact that the current from the source is the sum of the currents in the separate branches of a parallel circuit, the current from the source being larger than the current in each branch. Describe the uses of electricity in heating and lighting. State the hazards of: NOTES Refer to dangers of farming along high voltage power lines. 4.4.3 4.4.4 4.5 Electromagnetic effects 4.4.5 4.4.6 4.4.7 4.5.1 4.5.2 4.5.3 4.5.4 (i) damaged insulation (ii) overheating of cables (iii)damp conditions Explain the use of fuses and fuse ratings. Explain the need for earthing metal cases and for double insulation. Give the meaning of the terms: live, neutral and earth. Wire, and describe how to wire a mains plug. Give the reasons for switches and fuses in live leads. Describe an experiment which shows that a changing magnetic field can induce an e.m.f. in a circuit. State the factors affecting the magnitude of the induced e.m.f. Show that the direction of the induced e.m.f. opposes the change producing it. Describe a simple form of generator. 4.5.5 Sketch a graph of voltage output against time for a simple a.c. generator. 4.5.6 Describe the structure and principle of operation of a basic iron-cored transformer. 9 Refer to damages caused by electrical fires. Refer to, rotation coil or rotating magnet and the use of slip rings. Refer to voltage transformer. CONTENT 4.6 Introductory electronics OBJECTIVES (Pupils should be able to) 4.6.1 Explain that electrons are emitted from hot metals. 4.6.2 Describe the deflection of electrons in electric and magnetic fields. 4.6.3 Distinguish between the flow of electrons and conventional current. 4.6.4 Describe in outline the basic structure and action of cathode ray oscilloscope (CRO). 4.6.5 se and describe the use of CRO. 10 NOTES Include thermionic emission. Include display wave forms, measurement of p.d. and time-intervals. 5.0 ATOMIC PHYSICS CONTENT 5.1 Radioactivity 5.2 The nuclear atom OBJECTIVES (Pupils should be able to) NOTES 5.1.1 Describe the detection of a - particles ß - particles and r - rays. 5.1.2 State for radioactive emissions: (i) their nature (ii) their relative ionising effects. (iii)Their relative penetrating powers. 5.1.3 Describe radioactive decay in the composition of the Use equations (involving nucleus when particles are emitted. represent changes. 5.1.4 Use the term half-life in simple calculations which might involve information in tables or decay curves. 5.1.5 Describe how radioactive materials are handled, used, stored and disposed of in a safe way. 5.1.6 Discuss the effects of radioactive materials on the environment. 5.2.1 Describe the structure of an atom in terms of a nucleus and electrons. 5.2.2 Describe the composition of the nucleus in terms of protons and neutrons. 5.2.3 Use the term nucleon number (mass number), A. 5.2.4 Use the term proton number (atomic number), Z. 5.2.5 Use the term nuclide and nuclide rotation A X Z 11 symbols) to 6.0 PARTICULATE NATURE OF MATTER CONTENT 6.1 Matter OBJECTIVES (Pupils should be able to) 6.1.1 Define matters. NOTES Refer to anything that has mass and occupies spaces. 6.1.2 State the basic unit of matter. 6.1.3 Discuss the three states of matter. 6.2 Kinetic theory 6.2.1 Describe diffusion and dilution. Refer to the diffusion of toxic gases and effluents. 12 7.0 EXPERIMENTAL TECHNIQUES CONTENT OBJECTIVES (Pupils should be able to) 7.1 Measurement 7.1.1 Name and use appropriate apparatus for the measurement of time, temperature, mass and volume, including burettes, pipettes and measuring cylinders. 7.1.2 Design arrangements of apparatus, given information about the substances involved. 7.2 Purity 7.2.1 Describe and use paper chromatography and interpret chromatograms. 7.2.2 Identify substances and test their purity by melting point and boiling point determination and by paper chromatography. 7.2.3 Describe and use methods of purification by the use of suitable solvent, filtration, crystallisation, distillation. 7.2.4 Suggest suitable purification techniques, given information about the substances involved. 13 NOTES Refer to fractional distillation of crude oil, liquid air and fermented liquor include description but not use of fractional distillation. 8.0 ATOMS, ELEMENTS AND COMPOUNDS CONTENT OBJECTIVES (Pupils should be able to) 8.1. Atomic structure and 8.1.1 State the relative charges and approximate relative masses the periodic table of protons, neutrons and electrons. 8.1.2 Define proton number (atomic number) and nucleon number (mass number). 8.1.3 Use and interpret such symbols as 12C 6 8.1.4 Use proton (atomic) number and the simple structure of atoms to explain the Periodic Table, with special reference to the elements of proton (atomic) number 1 to 20. 8.1.6 Describe the build-up of electrons in ‘shells’ and explain the significance of valency electrons and the noble gas electronic structures. 8.2 Bonding: the structure 8.2.1 Describe the difference between elements, compounds and of matter mixtures and between metals and non-metals. 8.2.2 Describe alloys, such as brass, as a mixture of a metal with other elements. 8.2.3 Describe the information of ionic bonds between metallic and non-metallic elements, e.g. in Na CI, Ca CI2. 8.2.4 Describe the formation of covalent bonds as the sharing of pairs of electrons leading to the noble gas configuration. 8.2.5 Deduce the electron arrangement in other covalent molecules. 8.2.6 Construct ‘dots and cross’ diagrams to show the valency electrons in covalent molecules. 8.2.7 Describe the differences in volatility, solubility and electrical conductivity between ionic and covalent compounds. NOTES The ideas of the distribution of electrons in sand p-orbital and in d-block elements are not needed. Refer to H2, CI2, HCI, H20, CH4, CO2. Refer to dangers of toxic, volatile, inflammable and combustible substances. CONTENT 8.3 Formulae and equations. OBJECTIVES (Pupils should be able to) 8.3.1 State the symbols of the elements and formulae of compounds. 8.3.2 Deduce the formula of a simple compound from the relative numbers of atoms and vice versa. 8.3.3 Determine the formula of an ionic compound from the charge on the ions present and vice versa. 8.3.4 Construct equations with state symbols, including ionic equations. 8.3.5 Deduce, from experimental results of the identity of the reactants and products, the balanced chemical equation for a chemical reaction. 8.3.6 Define relative atomic mass, Ar. 8.3.7 Define relative molecular mass, Mr. 8.3.8 Perform calculations concerning reacting masses using simple proportions. 15 NOTES Calculations are not required. Calculations involving the mole concept are not required. 9.0 ACIDS, BASES AND SALTS CONTENT 9.1 Acids and bases 9.2 Types of oxides OBJECTIVES (Pupils should be able to) 9.1.1 Describe the meaning of the terms acid and alkali in terms of the ions they contain or produce in aqueous solution. 9.1.2 Describe the characteristic properties of acids as in their reactions with metals, bases, carbonates and their effects on indicator paper. 9.1.3 Describe the characteristics properties of bases as in their reactions with acids and with ammonium salts and their effects on indicator paper. 9.1.4 Describe neutrality and relative acidity and alkalinity in terms of pH, measured using Universal Indicator.. 9.1.5 Describe and explain the importance of controlling acidity in soil. 9.2.1 Classify oxides as either acidic , basic, or amphoteric related to metallic or non-metallic character. 9.2.2 Describe the preparation, separation and purification of salts. 9.2.3 Suggest a method of preparing a given salt from suitable starting materials, given appropriate information. 16 NOTES Refer to whole numbers only. Include the action of acids with insoluble bases, and acids with insoluble carbonates. 10.0 THE PERIODIC TABLE CONTENT OBJECTIVES (Pupils should be able to) NOTES 10.1 Periodic trends 10.1.1 Describe the Periodic Table as a method of classifying elements and its use to predict properties of elements. 10.1.2 Describe change from metallic to non-metallic character across a period. 10.1.3 Describe the relationship between Group number, number of valency electrons and metallic or non-metallic character. 10.2 Group properties 10.2.1 Describe lithium, sodium and potassium in Group I as a Refer to the alkali metals. collection of relatively soft metals showing a trend in melting point and in reaction with water and with chlorine. 10.2.2 Predict the properties of other elements in Group I, given data, where appropriate. 10.2.3 Describe chlorine, bromine and iodine in Group VII as a Refer to ozone layer depletion by halogens collection of diatomic non-metals showing a trend in and their compounds. colour, state, and in their displacement reactions with Group I halides. 10.2.4 Predict the properties of other elements in Group VII, given data, where appropriate. 10.2.5 Identify trends in other Groups given information about the elements concerned. 10.3 Noble gases 10.3.1 Describe the noble gases as being unreactive. 10.3.2 Describe the uses of the noble gases in providing an inert atmosphere. 17 Refer to argon in lamps, helium for filling balloons. 11.0 METALS CONTENT 11.1 Properties of metals 11.2 Reactivity series 11.1.1 11.1.2 11.1.3 11.2.1 11.2.2 11.2.3 11.3 Extraction and uses of metals 11.3.1 11.3.2 11.3.3 11.3.4 OBJECTIVES (Pupils should be able to) NOTES Describe the general physical properties of metals. Explain why metals are often used in the form of alloys. Identify representations of metals and alloys from diagrams of structures. Place in order of reactivity calcium, copper, hydrogen, iron, magnesium, potassium, sodium and zinc by reference to the reactions, if any, of the metals with water (or steam) and dilute hydrochloric acid. Account for the apparent unreactivity of aluminium in terms of the presence of an oxide layer which adheres to the metal. Deduce an order of reactivity from a given set of experimental results. Describe the ease in obtaining metals from their ores by relating the elements to the reactivity series. Describe the essential reactions in the extraction of iron Refer to toxic gases and effluents from iron from haematite. and copper extraction. Describe the idea of changing the properties of iron by the controlled use of additives to form alloys called steels. State the uses of mild steel and stainless steel. Refer to disposal of scrap metal as contributing to land pollution. Controlled use of additives to form alloys called steels. Refer to bodies, machines, chemical plant and cutlery, 18 CONTENT 11.3.5 11.3.6 11.3.7 11.3.8 11.3.9 OBJECTIVES (Pupils should be able to) Describe the extraction and purification of copper from its ore. State the uses of copper related to its properties. State the uses of aluminium in air craft and food containers. State the uses of zinc for galvanising and for making brass (with copper). Describe the effect of aluminium on human beings. 19 NOTES Refer to land degradation due to mining and other hazards. Refer to electrical wiring. Refer to its strength weight, density and resistance to corrosion. Refer to effect on reasoning capacity. 12.0 AIR AND WATER CONTENT 12.1 Water 12.1.1 12.1.2 12.1.3 12.1.4 12.2 Air OBJECTIVES (Pupils should be able to) Describe the formation of hydrogen as a product of the reaction between: (i) reactive metals and water. (ii) metals and acids. Describe the identification of hydrogen using a lighted splint (water being formed). Explain the use of hydrogen in the manufacture of ammonia, and of margarine, and as a fuel in rockets. Explain the effects of water pollutants. 12.1.5 Suggest ways of reducing water pollution. 12.1.6 Describe in outline the purification of water supply in terms of filtration and chlorination. 12.1.7 State uses of water in industry and in the home. 12.1.8 Describe, in simple terms, the ideas of respiration, combustion and rusting. 12.2.1 Describe the volume composition of clean air in terms of 79% nitrogen, 20% oxygen, with the remainder being noble gases (with argon as the main constituent), carbon dioxide and variable amounts of water vapour. 12.2.2 Describe the identification of oxygen using a glowing splint. 12.2.3 Describe the identification of carbon dioxide using lime water. 12.2.4 Name common pollutants of air. 20 NOTES Refer to explosive nature of hydrogen. Refer to sewage, oil spills, water weed and chemical effluents. Refer to correct quantity of chlorine even at household level. Equations are not required. Refer to Carbon monoxide, sulphur dioxide, oxides of nitrogen, lead compounds, asbestor and cement dust. CONTENT 12.2.5 12.2.6 12.2.7 12.2.8 12.2.9 12.2.10 12.2.11 12.2.12 12.2.13 12.2.14 12.2.15 OBJECTIVES (Pupils should be able to) State the sources of each of the following pollutants: (i) carbon monoxide. (ii) sulphur dioxide. (iii)oxides of nitrogen and lead. State the adverse effects of acidic pollutants on buildings and plants, and of carbon monoxide and lead compounds on health. Name the uses of oxygen in making steel, oxygen tents in hospitals, and with acetylene (a hydrocarbon) in welding. Describe methods of rust prevention. Identify processes involving addition of oxygen as oxidation. Define oxidation and reduction in terms of oxygen or hydrogen gain or loss. Describe the need for nitrogen, phosphorus and potassium compounds in plant life. Explain the use of nitrogen in the manufacture of ammonia. Describe the essential conditions for the manufacture of ammonia by the haber process. Name the uses of ammonia in the manufacture of fertilisers such as ammonium sulphate and nitrate. Discuss the effect of chemical fertilizers on the soil. 21 NOTES Refer to incomplete combustion of carbon containing substances, combustion of fossil fuels which contain sulphur compounds and from car exhausts. Refer to diseases. Refer to paint and other coatings. Refer to emissions and effluents from manufacturing plants. 13.0 ORGANIC CHEMISTRY CONTENT 13.1 Name of compounds 13.1.1 13.1.2 13.2 Homologous series 13.2.1 13.3 Fuels 13.3.1 13.3.2 13.3.3 13.3.4 OBJECTIVES (Pupils should be able to) Name, and draw the structure of the unbranched alkanes, alkenes, alchohols and acids containing up to four carbon atoms. State the compound present given a chemical name, ending in –ane, -ene, -ol, and oic given moleculer structure. Describe the general characteristics of any homologous series. Name natural gas and petroleum as sources of fuels e.g. kerosene, gasoline. Name methane as the main constituents of natural gas. Describe petroleum as a mixture of hydrocarbons and its separation into useful fractions by fractional distillation. Name the uses of petroleum fractions: (i) petrol (gasoline) (ii) paraffin (kerosene) (iii)diesel (iv) oils (v) bitumen 13.4 Alkanes 13.4.1 Describe the properties of alkanes (exemplified by methane) as being generally unreactive. 13.5 Alkenes 13.5.1 Describe the manufacture of alkanes and hydrogen by cracking. 13.5.2 Describe the properties of alkenes in terms of burning, addition reactions with hydrogen and steam. 22 NOTES (Not cis –trans). Refer to volatile and inflammable fuels. Refer to petrol as fuel in cars, paraffin for oil stoves and aircraft fuel; diesel, for fuel in diesel engines; oils for lubricants and making waxes and polishes; bitumen, for making roads. Refer to burning and substitution reactions. Refer to substitution reactions products as sources poison and responsible for ozone layer depletion. CONTENT 13.6 Alcohol 13.7 Acids OBJECTIVES (Pupils should be able to) 13.5.3 Distinguish between saturated and unsaturated hydrocarbons: (i) from molecular structures. (ii) by using aqueous bromine. 13.5.4 Describe the formation of poly (ethane) as an example of addition polymerisation of monomer units. 13.5.5 Name some uses of poly (ethane) as a typical plastic. 13.6.1 Describe the formation of ethanol by fermentation and by the catalytic addition of steam to ethane. 13.6.2 Describe the properties of ethanol in terms of burning and oxidation. 13.6.3 Name the uses of ethanol as a: (i) solvent. (ii) constituent of wine and beer. (iii) fuel. 13.7.1 Describe the formation of ethanoic acid by the oxidation of ethanol by: (i) the action of atmospheric oxygen. (ii) an oxidizing agent. 13.7.2 Describe ethanoic acid as an acid. 13.7.3 Describe the reaction of ethanoic acid with ethanol to give an ester (ethyl ethanoate). 13.8 Macromolecules 13.8.1 Describe macromolecules in terms of large molecules built up from small units, different macromolecules having different units and/or different linkages. 23 NOTES Refer to plastic bags. Refer to ethanol (alcohol) as one of the most abused drugs. Refer to oxidising agents such as potassium dichromate and potassium permanganate. Refer to characteristic fruity smell of esters. CONTENT OBJECTIVES (Pupils should be able to) 13.8.2 Distinguish between synthetic and natural macromolecules (polymers). 13.8.3 Deduce the structure of the polymer product from a given alkene and vice versa. 13.8.4 Describe the formation of nylon ( a polyamide) and Terylene (a polyester) by condensation polymerisation. NOTES the structure of nylon represented as and the structure of Terylene (Details of manufacture and mechanisms of these polymerisations are not required.) 13.8.5 Name some typical uses of man-made fibres such as nylon and Terylene, e.g. clothing. 13.8.6 Describe the pollution problems caused by nonbiodegradable plastics. 13.8.7 Name proteins, fats and carbohydrates as natural polymers and as the main constituents of food. 13.8.8 Describe proteins as possessing the same (amide) linkages as nylon but with different units. 13.8.9 Describe the hydrolysis of proteins to amino acids. 13.8.10 Describe fats as esters possessing the same linkages as Terylene but with different units. 13.8.11 Describe soap as a product of hydrolysis of fats. 24 Structure and names not required. CONTENT OBJECTIVES (Pupils should be able to) 13.8.12 Describe the carbohydrate starch as a macromolecule. NOTES Represented as: -O- -O- -O- -O- being formed by the condensation polymerisation of smaller carbohydrate units called sugars, represent as: HO - - OH 13.8.13 Describe the acid hydrolysis of carbohydrates such as starch to give simple sugars. 13.8.14 Describe the fermentation of simple sugars to produce Learners will not be expected to give the ethanol, carbon dioxide and its importance to brewing and molecular formulae of sugars. wine-making. 25