Chem I – Acids/Bases/Salts #1- Naming & Writing Acid - Review Name____________________ Period_________ Name the following acids: Acids are molecular compounds molecules that contain hydrogen bonded to a nonmetal or to a group of polyatomic ions. Acids can be either binary (consisting of only two elements) or ternary (consisting of more than two elements…usually polyatomic ions). Even though acids are molecules that are covalently bonded, they have properties of ionic compounds. Therefore the rules for naming and writing ionic compounds apply. 1. HNO3 2. HCl 3. H2SO4 4. H2SO3 NAMING BINARY ACIDS Hydro ______ ic acid. Example: HCl = hydrochloric acid 5. HC2H3O2 NAMING TERNARY ACIDS: 1. Identify the polyatomic ion in the formula 2. Look for the ending and change: “ate” changes to “ic” “ite” changes to “ous” 6. HBr 7. HNO2 Example: HPO4 = phosphoric acid (PO4 is phosphate therefore changed to “ic”) 8. H3PO4 3. 9. H2S 10. H2CO3 Look for polyatomic ions that contain four oxygen possibilities (ClO3-1 and IO3-1) Per_____ic greatest # of oxygen atoms (ClO4-1) _____ic greater # of oxygen atoms (ClO3-1) _____ous smaller # of oxygen atoms (ClO2-1) WRITING BINARY ACID FORMULAS: 1. Write H+1 2. Write the second element’s symbol & oxidation number. 3. Criss Cross the charges to create a neutral formula. Example: Hydrochloric acid = H Cl- = HCl Write the formulas of the following acids: 11. sulfuric acid 12. nitric acid WRITING TERNARY ACID FORMULAS: 1. Write H+1 2. Identify the polyatomic ion. 3. Change the endings by: “ic” changes to “ate” “ous” changes to “ite” 4. Write the polyatomic ions & oxidation number. 5. Criss Cross the charges to create a neutral formula. Example: sulfuric acid = H+ SO4-2 = H2S04 6. Look for prefixes such as “per” and “hypo”. They indicate the actual number of oxygen atoms in the compound. Example: perchloric acid = H+ ClO4-1 = HCl04 13. hydrochloric acid 14. acetic acid 15. hydrofluoric acid 16. phosphorous acid 17. carbonic acid 18. nitrous acid 19. phosphoric acid 1 20. hydrosulfuric acid Chem I – Acids/Bases/Salts Name_________________________ Period_______ Bronstead-Lowery Acids & Bases PART A. According to the Bronstead-Lowry theory, an acid is a proton (H+) donor, and a base is a proton acceptor. H+ Example: HCl + acid OH- → Cl- + base H2O Label the Bronsted-Lowrt acids and bases in the following reactions and show the direction of the proton transfer. Notice that the reactions are reversible, therefore label the acid and base on each side of the reaction. H+ Example: H2O + acid H+ Cl- ↔ base OH- + base 1. H2O + H2O ↔ 2. H2SO4 + OH- ↔ acid H3O+ + OH- HSO4 + H2O 3. HSO4- + H2O ↔ SO4-2 4. OH- HCl + H3O+ + H3O+ ↔ H2O + H2O 5. NH3 + H2O ↔ 2 NH4+ + OH- PART B. According to Bronstead-Lowry theory, after an acid has given up its proton, it is capable of getting back that proton and acting as a base. Conjugate base is what is left after an acid gives up a proton. The stronger the acid, the weaker the conjugate base. The weaker the acid, the stronger the conjugate base. Fill in the blanks in the table below. ACID BASE 1. H2SO4 HSO4- 2. H3PO4 ACID 11. HClO 12. Cl-1 NO2-1 3. F- 13. 4. NO3- 14. H2SO3 HBr 5. H2PO4- 15. 6. H2O 16. SO4-2 7. 17. 8. HPO4-2 18. 9. NH4+ 19. 10. H2O BASE 20. 3 CO3-2 HCN C2H3O2-1 H2CO3 HS-1 Chem I – Acids/Bases/Salts #2- Neutralization Reactions Perform the following neutralization reactions using: MAVA = MBVB *Remember to adjust the M for H2SO4, Ca(OH)2, Ba(OH)2, and Sr(OH)2. 1. How many mL of a 0.50 M HCl acid is needed to neutralize a 500. mL 0.75 M KOH solution? 2. Calculate concentration of acid if 500. mL of HI is used to neutralize a 900. mL 1.50 M NaOH solution. 3. How many mL of a 6.0 M H2SO4 acid is needed to neutralize a 1500. mL 2.50 M KOH solution? 4. Find the concentration of acid if 25.0 mL of HClO4 is needed to neutralize a 35.5 mL 2.50 M LiOH solution. 5. How many mL of a 0.500 M HNO3 acid is needed to neutralize a 575 mL 0.75 M Ca(OH)2 solution? 6. What is the concentration of base if 750 mL of NaOH is needed to neutralize a 1200. mL 1.25 M H2SO4solution? 7. Find the mL of 0.350M Ba(OH)2 needed to completely react with 45.6 mL of 1.00M HBr acid. 8. What is the concentration of HClO3 if 55.5 mL is neutralized by 25.5 mL of 0.250M Sr(OH)2? 4 Chem I – Acids/Bases/Salts #3 - pH and pOH PART A. The pH of a solution indicates how acidic or basic that solution is. pH range of 0 - 7 7 7 - 14 acidic neutral basic Since [H+] [OH] = 10-14 at 25O C. of [H+] is known, the [OH-] can be calculated and vice versa. pH = -log [H+] pOH = -log [OH-] Together, pH + pOH = 14. So if [H+] = 10-6 M, pH = 6. So if [OH-] = 10-8 M, pOH = 8 Complete the flowing chart. [H+] 1. 10-5 M pH 5 10-9 M 10-2 M 11 5. 12 6. 10-5 M 7. 10-11 M 13 9. 10. 9 10-4 M 3. 8. pOH 7 2. 4. [OH-] 6 5 Acidic or Basic Acidic Calculate the pH of the solutions below. 1. 0.01 M HCl 2. 0.0010 M NaOH 3. 0.050 M Ca(OH)2 4. 0.030 M HBr 5. 0.150 M KOH 6. 2.0 HC2H3O2 (Assume 5.0% dissociation) 7. 3.0 M HF (Assume 10.0% dissociation) 8. 0.50 M HNO3 9. 2.50 M NH4OH (Assume 5.00% dissociation) 10. 5.0 M HNO2 (Assume 1.0% dissociation) 6 Chem I – Acids/Bases/Salts #4 – pH Table *Formulas: pH + pOH = 14 pH = -log[H+] pOH = -log[OH-] [H+] = antilog (-pH) [OH-] = antilog (-pOH) *Remember to adjust the M for H2SO4, Ca(OH)2, Ba(OH)2, and Sr(OH)2 (multiply by 2) *Remember to adjust the M for weak acids and bases (multiply by the % disassociation) PART A: Complete the following table: Substance Strong or Weak Acid or Base [H+] [OH-] 0.100 M HCl 0.250 M Ca(OH)2 0.750 M HNO2 (2.50%) 0.655 M KOH 0.200 M H2SO4 0.850 M HNO3 0.910 M HNO3 0.150 M HClO4 0.850 M HC2H3O2 (3.50%) 0.555 M NaOH 0.350 M Ba(OH)2 0.200 M HClO3 7 pH pOH Acidic, Basic or Neutral PART B: Solve each problem and show work. 1. Calculate pH of a 0.0150M HCl solution. 2. Find pOH of a 0.020M hydrobromic acid, HBr, solution. 3. What is the concentration of OH- if the pH of a solution is 4.45? 4. Calculate OH- concentration of a solution with a pOH of 7.85. 5. Find concentration of acid (H30+) if the pH is 3.50. 6. Hydrochloric acid in the stomach has a pH of about 2.00. Find the concentration of HCl. 7. Find concentration of base (OH-) given an acid concentration of 1.55 x 10-3M. 8. Find acid concentration given a base concentration of 6.35 x 10-2M. 9. Calculate pH of 1.44 x 10-1M of acetic acid. (2.50% dissociation) 10. Calculate concentration of acid given 0.250M of ammonia (base). (5.00% dissociation) 8 Chemistry I pH Scales of Indicators: #5 Use the following color codes for each of the following indicators and color in the pH scales based on the indicator. 1. Phenolphthalein: pH: 0-9: colorless, 9-14: pink. Distinct division of color. 2. Malachite Green: pH: 0-2 yellow, 2-11.6 green, 11.6-13.8 blue, 13.8-14 colorless. Distinct division. 3. Methyl Orange: pH: 3.0-4.4. Red to orange to yellow. Gradual division between colors. 9 Chemistry I Titration Problem Set #6 PART I: *MAVA = MBVB, *Calculate volume of base, *Calculate volume of acid, *Put in values and solve 1. You conduct a titration using 0.500 M potassium hydroxide base (KOH) and an unknown hydrochloric acid (HCl) solution. The buret had an initial reading of 0.35 mL and a final reading of 36.89 mL for the base and an initial reading of 0.89 mL and a final reading of 47.63 mL for the acid. Calculate the molarity of the acid. b. Calculate the pH of the acid solution. c. Write an ionic and net ionic equation for the neutralization reaction. 2. You conduct a titration using 0.250 M nitric acid (HNO3) and an unknown sodium hydroxide (NaOH) solution. The buret had an initial reading of 3.56 mL and a final reading of 24.82 mL for the acid and an initial reading of 1.12 mL and a final reading of 33.56 mL for the base. Calculate the molarity of the base. b. Calculate the pH of the base solution. c. Write an ionic and net ionic equation for the neutralization reaction. Use the following titration curves to answer the question #3: 3. a. What is the pH of the equivalence point of this titration? b. Is this solution acidic, basic, or neutral? c. What is the approximate pH of the final solution? d. Describe the strength of the acid and the strength of the base that could have produced this titration curve. 10 PART II: *Strong acids + Strong bases = neutral salt water solution *Strong acids + Weak bases = acidic salt water solution *Weak acids + Strong bases = basic salt water solution 4. The following salts were created from titrating acids and bases. Determine the parent acid, parent base, rank the strength of parent acids and bases, and determine whether the final salt solution is acidic, basic, or neutral. K2CO3 Parent Acid (add H+1 to anion) Parent Base (add OH-1 to cation) Type of Solution H2CO3 (WA) KOH (SB) Basic Na2SO4 Ca(C2H3O2)2 Zn(NO3)2 Mg(ClO3)2 Ba(ClO4)2 FeCl3 CsBr 5. When titrating the following acids and bases, write balanced equations and determine whether the final solution would be neutral, acidic, or basic. a. hydrochloric acid and zinc hydroxide yield water and zinc chloride b. sodium hydroxide and hydrochloric acid yield water and sodium chloride c. barium hydroxide and acetic acid yield water and barium acetate d. sulfuric acid and magnesium hydroxide yield water and magnesium sulfate 11