Henan Experimental High School Sino-Canadian Program Chemistry 11 Test 2 Unit 1: Stoichiometry Time: 50 minutes __________________________________________________________________________ GENERAL INFORMATION Name: Teacher’s Name: Student Number: Date: Instruction: Read the questions carefully. Use the answer sheet to answer all the questions. Section A Molecular Formula Problem # 1 A 100 gram sample of a compound has the following composition by mass: 60.0 % C, 12.0 % H and 28.0 % N. 1. How many grams of hydrogen and nitrogen are present in the sample? a. b. c. d. H- 12 g, N- 18 g H- 12.5 g, N- 20 g H- 12 g, N- 28 g H- 60 g- N- 28 g 2. What is the empirical formula of the compound? a. b. c. d. C5H11N3 C5H12N2 C4H12N C5H12N4 3. If this compound has a molar mass of 300 g/mol, what is its molecular formula? a. b. c. d. C15H38N6 C15H36N6 C14H36N6 C14H34N6 Section B Stoichiometry Calculations Problem # 2 Given the following reaction: N2O4 + 2N2H4 → 3N2 + 4H2O 92.02 g 64.12 g 84.06 g 72.08 g 4. How many grams of N2H4 react with 75.62 g of N2O4? a. b. c. d. 52.69 g N2H4 50.30 g N2H4 55.60 g N2H4 54.36 g N2H4 www.bananateachersworld.wikispaces.com Chemistry 11 TEST 5. How many mol of H2O are produced by reacting 7.5 mol of N2H4? a. b. c. d. 13 mol H2O 12.5 mol H2O 15 mol H2O 17 mol H2O 6. How many grams of N2O4 are needed to react with 3.65 mol of N2H4? a. b. c. d. 167.9 g N2O4 157.5 g N2O4 162.7 g N2O4 169.8 g N2O4 7. How many molecules of N2O4 are needed to react with 58.65 g of N2H4? a. b. c. d. 5.5 X 1022 molecules N2O4 6.5 X 1023 molecules N2O4 5.5 X 1023 molecules N2O4 5.0 X 1023 molecules N2O4 Section C Limiting Reagent Problem # 3 Given the following reaction: P4 1 mol 123.88 g 47.35 g + 5O2 → 5 mol 160 g 123.45 P4O10 1 mol 283.88 g ? 8. According to the above chemical reaction, what is the maximum mass of P4O10 that can be made? a. b. c. d. 100.5 g P4O10 115.5 g P4O10 108.5 g P4O10 101.5 g P4O10 9. Which of the following statements about the limiting reagent and the excess reagent of the above chemical reaction is true? a. b. c. d. P4 is the limiting reagent, O2 is the excess reagent O2 is the limiting reagent, P4 is the excess reagent The above chemical reaction is an example of decomposition reaction The mass of reactant in excess is twice larger than the mass of the limiting reagent. 10. How many grams of the reactant that is in excess will be left over unreacted? a. b. c. d. 65.3 g 55.3 g 62.3 g 60.3 g www.bananateachersworld.wikispaces.com Chemistry 11 TEST Section D Percent Yield Problem # 4 Given the reaction: 2H2 + 2 mol 4.04 g O2 1 mol 32 g 2H2O 2 mol 36.04 g 11. What is the theoretical yield of H2O if 16 grams H2 reacts with 10 grams of O2? a. 10.26 g H2O b. 13.26 g H2O c. 12.26 g H2O d. 11.26 g H2O 12. What is the % yield of H2O if 138 g H2O is produced from 16 g H2 and excess O2? a. 97.5% b. 95.7% Problem # 5 The electrolysis of water forms H2 and O2 c. 90% 2H2O 36.04 g d. 96.7% 2H2 + O2 4.04 g 32 g 13. What is the % yield of O2 if 12.3 g of O2 is produced from the decomposition of 14.0 g H2O? a. 98.95% b. 97.95% c. 99.95% d. 96.95% Problem # 6 Ammonia is produced from combining hydrogen and nitrogen: 3H2 + N2 2NH3 6.06 g 28.02 g 34.08 g 14. What is the theoretical yield of NH3 if 40.4 g H2 reacts with excess N2? a. 127.2 g NH3 b. 200.2 g NH3 c. 227.2 g NH3 d. 230.2 g NH3 15. What is the % yield of NH3 if 40.5 g NH3 is produced from 40.4 g H2 and excess N2? a. 17.83 % b. 20.83 % c. 19.83 % d. 16.83 % Section E Avogadro’s Hypothesis and Mole Concept Applied to Gases 16. What volume will 0.750 moles of nitrogen gas occupy at STP? a. 16.8 liters b. 15 liters c. 14.8 liters www.bananateachersworld.wikispaces.com d. 17.5 liters Chemistry 11 TEST 17. Calculate how many methane (CH4) molecules are there in 4.48 dm3 of the gas at STP? a. 2.8 X 1023 b. 1.8 X 1023 c. 1.2 X 1023 d. 1.5 X 1023 Problem # 7 Methanol (CH3OH) can be used as fuel in a fondue burner. CH3OH has to react with O2 in air to produce H2O and CO2. __CH3OH + __O2 __H2O + __CO2 18. In which type of chemical reaction does the above reaction belong? a. Combination b. Decomposition c. Combustion d. Displacement 19. To balance the above equation, reactants and products should have this order of coefficients: a. 2, 3, 4, 2 b. 2, 3, 2, 2 c. 2, 3, 4, 2 d. 2,3,3,2 20. Given the above chemical reaction, what volume of oxygen at STP is needed to completely burn 0.46 mol of methanol (CH3OH)? a. 14 liters b. 15.46 liters c. 17 liters d. 16.5 liters 21. Which of the following statements about Avogadro’s hypothesis is not true? a. At STP, mole of a given gas is equal to its volume at STP divided by the molar volume of gases at STP. b. At STP, equal amount of gases occupies equal volume. c. At STP, 32 grams of O2 and 2.0 grams H2 occupies same volume. d. At STP, 32 grams of O2 and 32 grams CO2 contains same number of molecules. Section F (Write your answer to this question on the answer sheet) Give at least three reasons why actual yield is lesser than the theoretical yield. (4 marks) www.bananateachersworld.wikispaces.com Chemistry 11 TEST