Station 1 - Properties of Water pH pH is the measure of how acidic/basic water is. Water molecules have a tendency to ionize. They separate into ions, which are charged particles, hydrogen ions (H+) and hydroxide ions (OH-). In pure water a very small number of water molecules form ions in this way. A neutral solution contains an equal number of hydroxide ions and hydrogen ions. A solution with a greater concentration of hydrogen ions (H+) is said to be acidic. A solution with a greater concentration of hydroxide (OH-) ions is said to be alkaline or basic. So pH litmus papers can measure how acidic/basic a sample of water is. The range for a pH scale goes from 0 - 14, with 7 being neutral. pHs of less than 7 indicate acidity, whereas a pH of greater than 7 indicates a base. Since pH can be affected by chemicals in the water, pH is an important indicator of water that is changing chemically. pH affects many chemical and biological processes in the water. For example, different organisms flourish within different ranges of pH. Materials: 4 beakers with samples of distilled water, tap water, pond water and reef salt water, 4 strips of litmus paper and a pH scale Directions: Dip one of the strips of litmus paper into the beaker of distilled water for a few seconds, then lay the strip on a paper towel. Repeat using a new strip of litmus paper for each water sample. Compare the strips color to the pH scale and record the estimated pH value for each sample of water. Which sample had a high or more basic pH value? Which sample had the lowest or more acidic pH value? Did any of the samples show to have a neutral pH near 7? Clean up: Place the used litmus papers in the indicated beaker. Leave everything else the way it was. Station 2 – Properties of Water Universal Solvent Scientists often call water the “universal solvent” because water can dissolve more substances than any other liquid. Some substances, like common table salt (sodium chloride, NaCl), dissolve in water very easily. When placed in water, sodium chloride molecules fall apart. The positively charged sodium ion (Na+) binds to oxygen, while the negatively charged chloride ion (Cl-) attaches to hydrogen. This makes a very stable “salty” water molecule. This property of water allows for the transport of nutrients vital to life in animals and plants. A drop of rainwater falling through the air dissolves atmospheric gases. When rain reaches the earth, it affects the quality of the land, lakes and rivers. Materials: 2 test tubes with rubber stoppers, water, isopropyl alcohol, salt, and small measuring spoon Directions: Test tube 1: There are samples of water in test tube 1, add five full scoops of salt to one of these test tubes. Place the rubber stopper firmly into the top of the test tube and vigorously shake the test tube to mix the salt and water. Let the solution settle a few seconds then record your observations. Test tube 2: There is a sample of isopropyl alcohol in test tube 2, add five full scoops of salt to one of these test tubes. Place the rubber stopper firmly into the top of the test tube and vigorously shake the test tube to mix the salt and alcohol. Let the solution settle a few seconds then record your observations. Which test tube (1 or 2) had more salt left at the bottom of the test tube? Which liquid did the salt dissolve in better? Clean up: Pour out the contents of your used test tubes into the sink. Carefully rinse out the 2 test tubes and place in the used test tube rack. Rinse the rubber stoppers and put back where they started. Station 3 – Properties of Water Cohesion and Adhesion Cohesion—Water molecules are attracted to more water molecules so they stick to each other. This is due to the hydrogen bonds among the molecules. Water molecules like to stay close together. If you spill a cup of water on the floor it will stay together in a puddle. Water will “bead up” or form into a spherical shape when on a non-polar surface because the molecules are sticking to each other. Adhesion—Water molecules are attracted and stick to other substances. Water will stick to other polar surfaces like glass. You can see this property when water creeps up the inside of a drinking glass. Think of a sponge or a paper towel used to “soak up” spilled water. This is how water makes things wet. Materials: One small piece of wax paper, one glass slide, beaker of water and one pipette Directions: Using the pipette place three drops of water on top of one another onto the small piece of wax paper. Draw the drop of water viewed from the side. Then place three drops of water on top of one another onto the glass slide. Draw the drop of water viewed from the side. Is the bead of water on the wax paper higher or lower in height than the bead of water on the glass slide? Now carefully lift the wax paper and tilt it side to side. How does the water move along the wax paper? Then carefully lift the glass slide and tilt it side to side. How does the water move along the glass slide? Which surface do you think the water is more adhesive to? On which material do you see water’s cohesive property is stronger than its adhesive property? Why? Clean up: Put your used wax paper and glass slide in the indicated bowl. Dry off any wet surfaces on the counter. Station 4 – Properties of Water Surface Tension Surface Tension - Water molecules at the surface have a stronger attraction to each other than for the molecules in the air above. So the water molecules cling tightly to each other forming what’s like a skin or invisible film at the surface. Water’s surface tension can hold weight that would normally sink. You can carefully float a paper clip on top of the water. Some aquatic insects such as the water strider or pond skater rely on surface tension to walk on water. Surface tension is essential for the transfer of energy from wind to water to create waves. Waves are necessary for rapid oxygen diffusion in lakes and seas. Next to mercury, water has the highest surface tension of all commonly occurring liquids. Materials: One beaker of water, one beaker of soapy water (one drop of Dawn dish soap in water), one beaker of isopropyl alcohol, 3 forceps (labeled to only be used with specified container of liquid), and 3 unused rubber bands Directions: Carefully place one rubber band in each beaker of liquid. Record observations. Which liquid(s) did the rubber band float on? Why? Why did it sink in the other liquid(s)? Clean up: Carefully remove the rubber bands making sure to use the correct forceps that corresponds to the correct container. (Do not mix the liquids) Place the used rubber bands in the used rubber band container. Place the forceps back in the same location. Station 5 – Properties of Water Capillary Action Capillary action is important for moving water (and all of the things that are dissolved in it) around. It is defined as the movement of water within the spaces of a porous material due to the forces of adhesion, cohesion, and surface tension. Capillary action occurs because water is sticky, thanks to the forces of cohesion (water molecules like to stay close together) and adhesion (water molecules are attracted and stick to other substances). Adhesion of water to the walls of a vessel will cause an upward force on the liquid at the edges and result in a meniscus, which turns upward. The surface tension acts to hold the surface intact. Capillary action occurs when the adhesion to the walls is stronger than the cohesive forces between the liquid molecules. When you use a paper towel to clean up a spilled liquid, the liquid adheres itself to the paper fibers and the liquid moves to the spaces between and inside of the fibers This can also be seen as blood moves through our capillaries, carrying nutrients to each cell within our body. Plants and trees couldn't thrive without capillary action. Plants put down roots into the soil, which are capable of carrying water from the soil up into the plant. Water, which contains dissolved nutrients, gets inside the roots and starts climbing up the plant tissue. One of the tallest plants is the redwood tree. Water moves from its roots to its leaves, more than 310 feet above the ground. As a plant loses water through pores in the leaves, more water moves up from roots and stems to replace the lost water. Materials: Beaker of water, pencil, strip of filter paper, black and purple marker Directions: About 3 cm from the bottom of the filter paper mark a black and then a purple dot about 1 cm in diameter on the filter paper. Roll the other end onto a pencil (or have someone hold it) and lower it into the water making sure the water level is below the black and purple dots. Record observations. What did the water do as it traveled up the filter paper? Clean up: Dispose of your used filter paper and dry up any spilled water on the counter top. Station 6 – Properties of Water Reading Properties of Water Like all matter, water is made up of atoms. Atoms attach together, or bond, to form molecules. Two hydrogen atoms bonded to an oxygen atom form a water molecule. Water has several properties that make it a very unique substance. It has the formula H2O. When oxygen and hydrogen combine (H-O-H) they form a v-shaped triangular molecule. While water molecules are electrically neutral, the oxygen atom holds a small negative charge and the two hydrogen atoms hold small positive charges. Water molecules are attracted to each other, creating hydrogen bonds. These strong bonds determine almost every physical property of water and many of its chemical properties too. A large part of the mass of most organisms is simply water. In human tissues the percentage of water ranges from 20% in bones to 85% in brain cells. The water content is greater in embryonic and young cells and decreases as aging occurs. About 70% of our total body weight is water; as much as 95% of jellyfish or certain plants is water. Water is not only the major component of organisms but also one of the principal environmental factors affecting them. Many organisms live within the sea or in freshwater rivers, lakes, and puddles. The physical and chemical properties of water have permitted living things to appear, to survive, and to evolve on this planet. Water is the solvent, the medium and the participant in most of the chemical reactions occurring in our environment. Polarity - When electrons are not shared equally in a covalent bond, the molecule is described as polar. Water molecules are polar. This means that while water molecules are neutral as a whole, one end of the water molecule tends to have a positive charge while the other has a negative charge. The oxygen end has a slight negative charge while the hydrogen end has a slight positive charge. Each end of a water molecule is attracted to the opposite charged end of another water molecule. Water's polarity is responsible for the "stickiness" or cohesion between the molecules. States of Matter - Water is the only known substance that exists naturally in all three states of matter on Earth: gas, liquid, and solid. It exists in its liquid state in water bodies such as oceans and lakes. It exists in its solid state in the Polar Regions and in glaciers. It exists in its gaseous state in the air in the form of vapor and also clouds. Water makes up more than two-thirds of the Earth's surface. One phase can change into another. For example, water can evaporate to form water vapor or freeze to form ice. No matter the phase of the water—solid, liquid or gas—the chemical composition of each molecule is always H2O. The water molecules do not break up. The difference is in way the water molecules are arranged and the speed at which they move. Keep in mind that water molecules are always in constant motion, even in ice. • In the solid phase—as ice—the molecules are packed tightly together. They move slowly. • In the gas phase—as water vapor—the H2O molecules are farther apart. They move very fast and spread quickly. • In the liquid phase, they behave somewhere in between. Thermal Properties Water absorbs or releases more heat than many substances for each degree of temperature increase or decrease. Because of this, it is widely used for cooling and for transferring heat in thermal and chemical processes. Differences in temperature between lakes and rivers and the surrounding air may have a variety of effects. For example, local fog or mist is likely to occur if a lake cools in the surrounding air enough to cause saturation—small water droplets are suspended in the air. Large bodies of water, such as the oceans or the Great Lakes, have a profound influence on climate. They are the world’s great heat reservoirs and heat exchangers and the source of much of the moisture that falls as rain and snow over adjacent landmasses. When water is colder than the air, precipitation is curbed; winds are reduced, and fog banks are formed. These properties of water are crucial in stabilizing temperatures on earth. Specific Heat—Water has a high specific heat. The amount of energy required to raise the temperature of water by one degree Celsius is quite large. Because so much heat loss or heat input is required to lower or raise the temperature of water, the oceans and other large bodies of water have relatively constant temperatures. Thus, many organisms living in the oceans are provided with a relatively constant environmental temperature. The high water content of plants and animals living on land helps them to maintain a relatively constant internal temperature (Ours is about 98.6oF). The specific heat of water is 5 times greater than of sand. On a hot summer day, beach sand may quickly warm to the point that it is too hot to stand on while ocean water warms only a little. During the evening the temperature of sand will decrease while the temperature of the ocean remains relatively constant. Heat of Vaporization—Water has a high heat of vaporization. Water absorbs heat as it changes from a liquid to a gas; the human body can dissipate excess heat by the evaporation of its sweat. A leaf can keep cool in the bright sunlight by evaporating water from its surface. Water’s high heat conductivity makes possible the even distribution of heat throughout the body. Boiling and Freezing—Pure water at sea level boils at 100C (212F) and freezes at 0C (32F) Water density--Water is most dense at 4C and then begins to expand again (becoming less dense) as the temperature decreases further. This expansion occurs because its hydrogen bonds become more rigid and ordered. As a result, frozen water (ice floats) upon the denser cold water. The expansion of water takes place even before it actually freezes. This explains why a pond freezes from the surface down, rather than from the bottom up. As water temperature drops, the colder water (0-4C) where it is less dense— rises to the pond surface. It freezes to form a lid of ice. This ice insulates the water below from the wintry chill so that it is less likely to freeze. Organisms that inhabit the pond are able to survive the frigid winter below the icy surface.