Supplementary Information (SI) Morphology and photophysical properties of dual-emissive hyperbranched zinc phthalocyanines and their self-assembling superstructures Kun Jia a, †,*, Lin Pana, †, Zicheng Wang a, Liting Yuan a, Xufei Zhou a, Yumin Huang a, Chunhui Wu b, and Xiaobo Liu*a a Research Branch of Advanced Functional Materials, High Temperature Resistant Polymer and Composites Key Laboratory of Sichuan Province, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054, China. b Department of Biophysics, School of Life Science and Technology, University of Electronic Science and Technology of China, Chengdu 610054, China. E-mail: jiakun@uestc.edu.cn, liuxb@uestc.edu.cn; Tel: +86-28-83207326 Fig. S1 The FTIR spectra of four samples synthesized for different time Fig. S2 The XRD spectra of four HBZnPCs samples synthesized for different time Fig. S3 The DSC curves of HBZnPCs synthesized for different time of 0.5 h (A), 4 h (B), 15 h (C) and 20 h (D), respectively Fig. S4 The fluorescent emission of HBZnPCs in DMF solution with increasing concentrations from curve 0.009 mg/mL to 0.2 mg/mL. Fig. S5 The fluorescent emission of HBZnPCs in pyridine solution, shown in inset was the samples vial under 365 nm UV light illumination Fig. S6 The fluorescent emission of HBZnPCs in chloroform solution, shown in inset was the samples vial under 365 nm UV light illumination Fig. S7 The UV-Vis spectra of HBZnPCs when dispersed in DMF/H2O mixed solvent with different relative volume ratio