grl28080-sup-0002-txts01

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Text S1
Discussion of Uncertainties:
The uncertainties reported in this work are based on measurement uncertainties from the
GRS instrument. Uncertainties vary for each GRS 5°x5° pixel due to a variety of factors. These
factors include the specific element measured, topography, and latitude [see Boynton et al., 2007
and Karunatillake et al., 2007 for detailed discussion on GRS measurement uncertainties]. On
average, the per pixel elemental concentrations used for this study have uncertainties ranging
from 3-10%.
GRS derived K concentrations have average corresponding sigmas of ±100ppm.
Likewise, GRS derived Th concentrations have corresponding sigmas of ±0.06ppm. Uranium
abundances (235U and 238U) were calculated by assigning a Th/U ratio of 3.8. This is a canonical
cosmochemical value thought to be representative of most planetary bodies and that also agrees
with analyses of most martian meteorites [McLennan, 2001; Meyer, 2003; Taylor and
McLennan, 2009]. As such, uncertainties for U are determined from Th uncertainties. Note
however, should future studies show an unexpectedly different Th/U ratio, heat production and
heat flow values would need to be adjusted accordingly.
The Neumann et al., [2004] crustal thickness model presents a reasonable average crustal
thickness of 45 km. The heat flow estimates presented here would need to be scaled
appropriately for future models suggesting a different average crustal thickness.
Taylor et al., [2006a,b] argued that if surface concentrations measured by GRS were
representative of the entire crust, as much as 50% of the total planetary budget of heat producing
elements could have been sequestered into the crust. This estimate is based on the
cosmochemical models of Dreibus and Wanke, [1985] and Wanke and Dreibus, [1988] for a
bulk chemical composition of Mars. Taylor et al., [2006a,b] does not quantify the uncertainty for
this estimate. Also in this paper, some values are reported as “approximate” if the uncertainties
are not easily quantified – for example, estimates for heat flow at the time of formation for
certain regions or locations where the age of the feature is poorly constrained.
References
Boynton, W. V. et al. (2007), Concentration of H, Si, Cl, K, Fe, and Th in the low and mid
latitude regions of Mars, J. Geophys. Res., 112, doi: 10.1029/2007JE002887.
Dreibus, G. and H. Wänke (1985), Mars, a Volatile-Rich Planet, Meteor. Planet. Sci., 20, 367-381.
Karunatillake, S. et al. (2007) Chemical compositions at Mars landing sites subject to Mars Odyssey
Gamma Ray Spectrometer constraints, J. Geophys. Res., 112, doi:10.1029/2006JE002859
Taylor, G. J. et al. (2006a), Causes of Variation in K/Th on Mars, J. Geophys. Res., 111,
doi:10.1029/2006JE002676.
Taylor, G. J. et al. (2006b), Bulk Composition and Early Differentiation of Mars, J. Geophys.
Res., 111, doi: 10.1029/2005JE002645.
Wänke, H. and G. Dreibus (1988) Chemical-Composition and Accretion History of Terrestrial Planets,
Philos. Trans. R. Soc. London, 325, 545-557.
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