Lap #2 Matter and Change Chapter 2 Essential Question: How does the study of matter help us understand the world around us? 2.1 Properties of Matter A. Properties: describe matter Extensive properties Depends on the amount of matter Mass: amount of matter Volume: how much space it occupies Intensive properties Depends on type of matter, not how much Examples: color, hardness, texture, state Sample photo Extensive = volume is 125 mL Intensive = black color, liquid B. Identifying Substances Substance: matter with a uniform and definite composition Every sample of a given substance has identical intensive properties b/c it has identical composition Intensive properties can identify a substance Example: Copper vs Gold Color Hardness Conduction of heat/electricity Malleability Physical property: quality or condition of a substance that can be observed or measured without changing the substance's composition Can be used to identify a substance What would be a colorless liquid that boils at 78 degrees C? What would be a colorless liquid that boils at 100 degrees C? C. States of Matter Physical properties include 3 states of matter: Solid, liquid, gas Solid Shape and volume fixed Shape does not depend on shape of container Volume does not depend on container Particles are packed tightly, fixed arrangement incompressible (difficult to squeeze into smaller volume) expand only slightly when heated Liquid Shape matches that of container Volume is fixed Particles are in close contact, but not in fixed arrangement Particles flow and move freely from one location to another almost incompressible, but expand slightly when heated Gas Shape matches container Volume expands to fill container Particles are far apart and move quickly Easily compressed into smaller volume and easily expands Ex: hot air balloons Gas = substance that is gas state at room temp, for ex. oxygen gas Vapor = substance that is solid/liquid at room temp, for ex. water vapor SOLID VOLUME SHAPE ARRANGEMENT OF PARTICLES MOTION OF PARTICLES LIQUID GAS A. Physical vs. Chemical Changes Physical Changes Def: During physical change, some properties of a material change, but the composition does not change Separating mixtures does not change their composition Ex: Separate iron filings from sulfur using a magnet Changing state of matter does not change the substance Ex: H2O liquid changes to H2O vapor: it is still water Physical changes can be: Reversible Freeze, melt, boil, condense Irreversible Cut, grind, crush 2.1 Section Assessment 1. Explain why all samples of a given substance have the same intensive properties. 2. In what way are liquids and gases alike? In what way are liquids and gases different? 3. Is the freezing of mercury a reversible or irreversible physical change? Explain. 4. Explain why samples of gold and copper can have the same extensive properties, but not the same intensive properties. 5. Explain why sharpening a pencil is a different type of physical change than freezing water to make ice cubes. 6. If the state of a substance can change when it is heated or cooled, what does it mean to say that a certain substance is a solid, liquid or gas? 7. Page 43: Properties of spider silk: stronger than steel, more elastic than nylon, and tougher than rubber. Biotechnology: transfer spider genes into ____________, who produce milk containing spider silk. Classifying Matter Activity 1. Add 1/2 cup tap water to each of four labeled beakers. 2. Without stirring, add 1/2 teaspoon of each solid to the corresponding, labeled beaker. 3. Observe and record any change that occurs after the solids are added in the table. 4. Stir the contents of each container for at least 45 seconds. 5. Record what you observe after stirring, in the table. Before stirring After stirring Powdered Sugar & H20 Flour & H2O Baking soda & H2O Baking powder & H2O 1. When you measured 1/2 teaspoon of each solid, were you measuring mass or volume? ____________________ Is that an intensive property or an extensive property? ____________________ Does a measurement such as 1/2 teaspoon identify the substance measured? _________ 2. What physical properties do all four substances have in common? ___________________________________________________________ 3. Which solid could you distinguish from the other three after Step 2? _______________________________ Which states of matter did you observe after this solid was added to water? _______________________________________ Do you think the substance changed its state, or do you think a chemical change occurred? ___________ 4. Can you distinguish completely among the remaining three solids based on the results of Step 4? Explain. ______________________________________________________________________________ ______________________________________________________________________________ Baking soda vs. Baking powder Both are chemical leavening agents: they react with other ingredients to produce CO2 gas which is trapped in batters and doughs to make baked goods light and fluffy instead of dense and heavy. Baking Soda = Sodium Bicarbonate = NaHCO3 an alkaline compound that needs an acid in the ingredients plus water to react, e.g. buttermilk, sour cream, yogurt, lemon juice, cocoa powder it reacts quickly, so can't let ingredients sit around too long before baking test for freshness by mixing w/vinegar (volcano eruption experiment) add too much: metallic flavor 4 times stronger than baking powder: 1/4 tsp will leaven 1 cup flour Baking Powder = Baking Soda plus starch plus two acids contains the alkaline baking soda and already has acid in it, so doesn't need an acid in other ingredients; just needs moisture plus heat double acting: reacts in presence of liquid and when heated in oven can make doughs and batters ahead of time Recipes that call for both together leaven well, produce light and airy baked goods Test for freshness: should bubble up when added to hot H2O Baking soda will produce denser more chewy cookies Baking powder will produce cake-like, puffy cookies 2.2 Mixtures A. All Matter is either: Substance or a mixture B. Classifying mixtures Mixture= physical blend of two or more components Most samples are mixtures 2 types Heterogeneous mixture Homogeneous mixture Heterogeneous mixture Composition is not uniform throughout Examples: soup, sand Two or more phases (diff things you see) Def: part of a sample that has uniform composition and particles Homogeneous mixture Composition is uniform throughout Examples: oil, kool-aid, glue, air, stainless steel One phase Also called solution (usually for liquids or gases) Can be difficult to identify as homogeneous or heterogeneous - depends upon how closely you look. Generally, particle sizes of 1 nm or less in solution = homogeneous Blood and milk are heterogeneous C. Separating mixtures Differences in physical properties can be used to separate mixtures 1. Decant Separate oil and vinegar: Pour off the oil = uses density of oil Allow mixture to cool = oil freezes before vinegar 2. Filtration Separate solid from liquid in a heterogeneous mixture 3. Distillation Separate solid dissolved in a homogeneous mixture/solution Liquid is boiled to produce vapor Vapor is moved into another tube, where it is cooled and condensed to water Solid is left in the flask 1. What type of properties can be used to separate mixtures? 2. Explain the term phase as it relates to homogeneous or heterogeneous mixtures. 3. Classify each of the following as a homogeneous or heterogeneous mixture. a. food coloring b. ice cubes in liquid water c. mouthwash d. mashed, unpeeled potatoes 4. How are a substance and a solution similar? How are they different? 5. In general, when would you use filtration to separate a mixture? When would you use distillation to separate a mixture? 6. Describe a procedure that could be used to separate a mixture of sand and table salt. 2.3 Elements and Compounds A. Elements Def: Simplest form of that has unique properties Examples: oxygen, carbon, nitrogen B. Compounds Def: Substance that contains 2 or more elements combined in a fixed proportion (recipe) Can be broken down into simpler substances by chemical means Examples: water, H2O and sucrose C11H22O11 Breaking down compounds Physical methods to separate mixtures can’t be used to break down compounds boil water ---> liquid water, not hydrogen and oxygen dissolve sugar cube in water -----> still have sugar, not C, H, and O Must use chemical changes to break down a compound Chemical change = change that produces matter with a different composition than original matter Examples: heating or electricity Properties of compounds Properties of compounds are different from individual elements Example: Sodium chloride (NaCl) or table salt White solid Sodium alone is silver solid metal Chlorine alone is yellowish gas Example: H2O, water Colorless liquid Hydrogen oxygen both gases C. Distinguishing between substances and mixtures Hard to tell if substance or homogeneous mixture If different varieties available, its probably a mixture Milk: 2%, skim, whole Gasoline: regular, premium, ultimate Rule = If composition is fixed, the material is a substance. If composition can vary, it is a mixture. Chart page 50 Conceptual problem pg 51 D. Symbols and Formulas Symbols represent elements Capital letter or Capital letter + lowercase letter Carbon = C Nitrogen = N Chlorine = Cl Sodium = Na Formulas represent compounds Use symbol for each element in compound Number subscript to show how many atoms of each element are in the “recipe” Water H2O 2 atoms of hydrogen and 1 atom of oxygen Glucose C6H12O6 6 atoms of Carbon, 12 atoms of hydrogen, and 6 atoms of Oxygen Section Assessment 2.3 1. How is a compound different from an element? 2. How can you distinguish a substance from a mixture? 3. Name two methods that can be used to break down compounds into simpler substances. 4. Classify each of these samples of matter as an element, a compound, or a mixture. a. table sugar b. tap water c. cough syrup d. nitrogen 5. Write the chemical symbol for each element. a. lead c. silver e. hydrogen b. oxygen d. sodium f. aluminum 6. Name the chemical elements represented by the following symbols. a. C b. Ca c. K d. Au e. Fe f. Cu 7. What elements make up the pain reliever acetaminophen, chemical formula C8H9O2N? Which element is present in the greatest proportion by number of particles? 8. Describe the relationship between the three items in each of the following groups. Identify each item as an element, compound, or mixture. a. hydrogen, oxygen, and water b. nitrogen, oxygen, and air c. sodium, chlorine, and table salt d. carbon, water, and table sugar Elements you need to know names and symbols for the test: Elements by atomic number: 1-20, 26, 28, 29, 30, 47, 50, 79, 80, 82 1. _____ Hydrogen 2. _____Helium 3. _____Lithium 4. _____Beryllium 5. _____Boron 6. _____Carbon 7. _____Nitrogen 8. _____Oxygen 9. _____Fluorine 10. ____Neon 11. ____Sodium 12. ____Magnesium 13. ____Aluminum 14. ____Silicon 15. ____Phosphorus 16. ____Sulfur 17. ____Chlorine 18. ____Argon 19. ____Potassium 20. ____Calcium 26. ____Iron 28. ____Nickel 29. ____Copper 30. ____Zinc 47. ____Silver 50. ____Tin 79. ____Gold 80. ____Mercury 82. ____Lead 2.4 Chemical Reactions A. Physical vs. Chemical Changes Physical Changes (review from section 2.1) Def: Some properties of a material change, but the composition does not change Separating mixtures does not change their composition Ex: Separate iron filings from sulfur using a magnet Changing state of matter does not change the substance Ex: H2O liquid changes to H2O vapor: it is still water Physical changes can be: Reversible: Freeze, melt, boil, condense Irreversible: Cut, grind, crush Chemical Changes Def: composition of matter changes Creates an entirely new type of matter Also called chemical reaction Substance present at start = reactant Substances present at end = product Reactant + Reactant Example: Fe + O2 Product FeO B. Signs of Chemical Change Transfer of energy Heat is added - endothermic Heat is released - exothermic Change in color Production of gas Formation of precipitate Def: solid forms and settle out from liquid mixture Can only be certain of a chemical change if you test the composition Some signs can occur even in physical changes C. Conservation of mass During any chemical reaction, the mass of reactants and products is always the SAME No mass is gained or lost or destroyed in a reaction You must consider the mass lost to any gas that is released D. Chemical property Describes ability of substance to undergo chemical change Examples: Reactivity Flammability Ability to combust Ability to ferment/turn sour Ability to rust Iron + Oxygen Iron Oxide Not chemical properties: Ability to dissolve in water (solubility) = physical ex: salt dissolves in water, but can reverse by evaporating water and get salt again Changes of state: boiling or freezing = physical Section Assessment 2.4 1. How does a chemical change affect the composition of matter? 2. Name four possible clues that a chemical change has taken place. 3. In a chemical reaction, how does the mass of the reactants compare with the mass of the products? 4. What is the main difference between a physical change and a chemical change? 5. Classify the following as physical or chemical changes. a. Water boils b. Salt dissolves in water c. Milk turns sour d. a metal rusts 6. According to the law of conservation of mass, when is mass conserved? 7. Hydrogen and oxygen react chemically to form water. How much water would form if 4.8 grams of hydrogen reacted with 38.4 grams of oxygen?