Chemical Reaction Demonstrations Answer Key The One With The Egg & Vinegar WE: acetic acid + calcium carbonate → calcium acetate + water + carbon dioxide BCE: 2HC2H3O2(aq) + CaCO3(s) → Ca(C2H3O2)2(aq) + H2O(l) + CO2(g) The One With The Two Iron Balls WE: aluminum + iron(III) oxide → iron + aluminum oxide BCE: 2Al(s) + Fe2O3(s) → 2Fe(s) + Al2O3(s) The One With The Pop Can WE: aluminum + copper(II) chloride → copper + aluminum chloride BCE: 2Al(s) + 3CuCl2(aq) → 3Cu(s) + 2AlCl3(aq) The One With The Precipitate WE: copper(II) chloride + sodium carbonate → sodium chloride + copper(II) carbonate BCE: CuCl2(aq) + Na2CO3(aq) → 2NaCl(aq) + CuCO3(s) The One With The Two Balloons Reaction 1: Production of Ethyne WE: calcium carbide + water → ethyne + calcium hydroxide BCE: CaC2(s) + 2H2O(l) → C2H2(g) + Ca(OH)2(s) -the calcium hydroxide has a low solubility (the white solid formed) although some will be in a dissolved state (dissolved Ca2+ and OH- ions) Reaction 2: Combustion of Ethyne The combustion that produced no or very little soot is more of a complete combustion: WE: ethyne + oxygen → carbon dioxide + water BCE: 2C2H2(g) + 5O2(g) → 4CO2(g) + 2H2O(g) The combustion that produced a lot of soot is incomplete combustion: Possible WE: ethyne + oxygen → carbon soot + carbon monoxide + carbon dioxide + water Possible BCE: 4C2H2(g) + 5O2(g) → 4C(s) + 2CO(g) + 2CO2(g) + 4H2O(g) The One With Sulfur WE: sulfur + oxygen → sulfur dioxide sulfur dioxide + oxygen → sulfur trioxide sufur trioxide + water → sulfuric acid BCE: S(s) + O2(g) → SO2(g) -sulfur exists as S8 molecules but for simplicity S is commonly used 2SO2(g) + O2(g) → 2SO3(g) SO3(g) + H2O(l) → H2SO4(aq) The One With “Swag” - the blue flame indicated that the ethanol underwent more of a complete combustion WE: ethanol + oxygen → carbon dioxide + water BCE: C2H6O(l) + 3O2(g) → 2CO2(g) + 3H2O(g) The One With Poor Ol’ Mr. Gummie Bear Reaction 1: Decomposition of Potassium Chlorate WE: potassium chlorate → potassium chloride + oxygen BCE: 2KClO3(s) → 2KCl(s) + 3O2(g) Reaction 2: Combustion of Glucose For simplicity, we will assume that only glucose underwent combustion and that the combustion was complete. Due to the presence of other combustible, carbon-containing chemicals present in the gummie bear, it was evident in class that incomplete combustion occurred. WE: glucose + oxygen → carbon dioxide + water BCE: C6H12O6(s) + 6O2(g) → 6CO2(g) + 6H2O(g) The One With The Pringles Can Reaction 1: Production of Hydrogen and Zinc Chloride WE: zinc + hydrochloric acid → hydrogen + zinc chloride BCE: Zn(s) + 2HCl(aq) → H2(g) + ZnCl2(aq) Reaction 2: Combustion of Hydrogen WE: hydrogen + oxygen → water BCE: 2H2(g) + O2(g) → 2H2O(g) The One With Sodium Reaction 1: Production of Hydrogen and Sodium Hydroxide WE: sodium + water → hydrogen + sodium hydroxide BCE: 2Na(s) + 2H2O(l) → H2(g) + 2NaOH(aq) Reaction 2: Combustion of Hydrogen WE: hydrogen + oxygen → water BCE: 2H2(g) + O2(g) → 2H2O(g)