MINERALS, ROCKS, AND VOLCANOES Geology is the study of the structure, composition, processes and history of the Earth. The outer layer of the Earth is called the crust and is composed of minerals and rocks. A mineral is a naturally occurring, inorganic substance that possesses a definite chemical composition and a distinctive set of physical characteristics. Minerals such as diamonds or rubies can be very valuable as are gold and silver ore. Minerals found in sand or limestone, however are not valuable. Your body needs minerals. These minerals are generally found as compounds in food and can actually be toxic if taken in amounts that are too large. The most common minerals found in the Earth's crust are the silicates which are compounds containing silicon and oxygen. Silicon dioxide or silica is the fundamental silicon-oxygen compound. It actually exists as an SiO4 tetrahedron, but oxygen atoms are shared so that the actual ratio of oxygen to silicon atoms is 2 to 1. Most rocks contain aluminum, calcium, sodium or potassium in addition to silicon and oxygen. Feldspars which contain calcium or sodium are said to be plagioclase. If potassium is present instead, it is called orthoclase. Nonsilicates compose less than 10% of the mass of the Earth's crust. They include pure elements such as gold or silver, gemstones, and ores of iron, copper, nickel and tin. Carbonates (CO3-2) such as calcium carbonate, oxides (O-2) such as iron oxide, and sulfides (S-2) such as galena which is lead sulfide, are the most common non silicate groups. Classification of minerals is based on physical and chemical properties because this method distinguishes among different form of the same element or compound. Graphite, charcoal and diamond are all composed of carbon but have very different properties and value. Some of the main properties used to identify minerals follow. Crystal form refers to the size and shape assumed by the crystal faces when a crystal is given time and space to grow. Small pieces of sodium chloride are observed to be shaped like boxes and calcite crystals are shaped like boxes that have been distorted from their normal rectangular shape. Hardness refers to the ability of a mineral to resist scratching. Minerals are arranged in order of hardness on the Mohs' scale which has representative minerals in order from 1(softest) to 10(hardest). Talc is the softest mineral on the Mohs' scale and Diamond is the hardest. Cleavage is the ability of a mineral to break along definite smooth planes. Minerals can have definite cleavage along one or more planes or no cleavage. Fracture refers to the way a mineral breaks. It may splinter, break into rough, irregularly shaped pieces, or break into shell shaped forms known as conchoidal. Color is determined by the frequencies of light reflected by the mineral. Color may vary within samples of the same mineral. Streak is the color of a powder of a mineral. Color of streak will not change from sample to sample thus showing the mineral's true color. Luster is the shininess of a mineral's surface. It can range from the appearance of a polished piece of metal to none at all such as clay. Specific gravity refers to a mineral's density compared to the density of water. Each mineral has a characteristic specific gravity that does not vary among pure samples. Rocks A rock is defined as a solid, cohesive natural aggregate of one or more minerals. The three major categories of rocks are igneous, sedimentary and metamorphic. Igneous rocks are formed by the solidification (freezing) of magma. Igneous rocks may be formed deep under the Earth's surface from magma. If the magma reaches the surface of the Earth we say the rocks are formed from lava. Sedimentary rocks are formed at the Earth's surface by compaction and cementation of layers of sediment. They are aggregates of 1. Rock fragments resulting from the weathering of older rocks. 2. Minerals precipitated from a solution. 3. Altered remains of plants or animals. Metamorphic rocks are formed when existing rock is changed by pressure, temperature, and/or a change in chemical components. Metamorphism occurs below the surface of the Earth but above the depths at which rock is melted. The Rock Cycle is a description of the processes by which rocks are formed, broken down, reformed and recycled into the Earth's magma. The idea that these processes have been the same throughout the history of the Earth is called uniformitarianism. This idea was developed by an 18th century geologist named James Hutton. He is called "the father of geology" for his development of these two ideas that are the foundation of modern geology. Igneous Rocks Igneous rocks constitute about 80% of the Earth's surface. There are two main classifications of igneous rock. When magma makes its way to the surface, as in a volcanic eruption, the rock that is formed is said to be extrusive. If the magma solidifies underground, the resulting rock is said to be intrusive. When one is studying volcanoes, it is important to understand plate tectonics, the idea that the surface of the Earth is composed of many large pieces that are moving past, over, and under each other. Volcanoes are mostly found along converging plate boundaries. When plates converge, one must move under the other in an area called a subduction zone. The melting of rock and vaporization of water in these regions causes pressure to build up and eventually volcanic eruptions. The Pacific Rim is sometimes called "the ring of fire" because of all the volcanoes surrounding the Pacific Ocean. Igneous rocks are classified in terms of their texture (grain size) and mineral composition. Grain size is determined primarily by the rate at which molten material cools to form rock. Material exposed to the atmosphere cools quickly and only small grains have time to form. Material that is deep under the surface of the Earth loses heat more slowly and much larger crystals have time to form. Granite generally forms at some depth and has large crystals that are easily seen. Basalt forms near or at the surface and has much smaller crystals that are difficult to see. Obsidian forms from lava shot into the air and cools so rapidly that practically no crystals form. This gives obsidian its characteristic glassy appearance. Plutons are defined as intrusive igneous rocks formed by the solidification of magma. They are classified according to their size and shape and their orientation with respect to the surrounding rock. Discordant means the pluton cuts across the grain of the surrounding rock and concordant means it lies in the same direction as the grain of the surrounding rock. A batholith is a discordant pluton of enormous size. The minimum size for a batholith is 103 square kilometers. Dikes are discordant plutons formed when magma fills a vertical fracture in existing rock. A dike will be thin in one dimension and large in the other two. A sill is similar to a dike but is concordant. A laccolith is a concordant pluton shaped like a blister. It forms from intrusive magma. A volcano is a hill or mountain formed from lava and rock fragments ejected through a vent in the surface of the Earth. There are three products of volcanic eruptions. 1. Gasses such as steam, carbon dioxide, and hydrogen sulfide make up 99% of the gasses. Steam accounts for almost 90%. 2. Lava that can be very fluid or nearly solid depending on the temperature and the composition of the lava. The more fluid lava which is mainly basaltic is very hot and has a low silica content. Cooler, high silica lava is called rhyolitic or andesitic and moves much more slowly. 3. Solid material ranging from the size of dust particles to boulders may be expelled. Collectively these particles are called tephra. Volcanoes may erupt peacefully or explosively. The Hawaiian volcanoes tend to erupt peacefully since the very fluid lava allows gasses to escape. Other volcanoes like Mount St Helens tend to explode since the viscous lava blocks the escape of gasses and allows pressure to build up. There are three types of volcano classifications by structure. 1. Shield - a shield volcano is built up from many fluid lava flows over time. Its sides are relatively gently sloping and it forms a low, mounded profile. Mauna Loa in the Hawaiian chain is a shield volcano. 2. Stratovolcano - a stratovolcano or a composite cone volcano is built up from a combination of lava and tephra to form a more steeply sloping profile. Examples are Mount Fuji and Mount St Helens. 3. Cinder Cone - a cinder cone volcano is composed almost entirely of tephra with very little lava flow. The profile of a cinder cone shows very steep sides. Many volcanoes have a large central depression called a caldera. This roughly circular area will be surrounded by steep walls and results from the collapse of the peak of the volcano when the underlying lava chamber is partially emptied. Crater Lake in Oregon occupies a caldera on top of Mount Mazama. Historically significant volcanic eruptions include Mount St Helens, Mount Vesuvius(Pompeii), Paricutin, Mount Pelee', Surtsey, and Tambora. The eruption of Tambora was the largest in written history. Mt Pelee' was the most deadly with 40,000 deaths. Sedimentary Rock The initial idea of the nature of sedimentary rock is credited to James Hutton, a Scottish geologist also known as the "Father of Geology" who lived in the late eighteenth century. He surmised that rock fragments, sand, and other material would be deposited as layers of sediment in rivers, lakes and on the seafloor. These layers would then be naturally cemented together to form sedimentary rock. The layers in sedimentary rock are called strata. The idea of superposition (new material is the top layer, older material is the bottom layer) was developed before Hutton. The change of sediment into rock is called lithification. During this process, weight from top layers forces the water out of the lower layers. Silica, calcium carbonate, and/or iron oxides which are dissolved in groundwater precipitate out and form bonds with the sediment. This is the cementing process that results in solid sedimentary rock. Detrital sediments are composed of solid fragments derived from preexisting rock. Shale is composed of fine particles from mud. Sandstone is composed of larger particles that typically are found as sand. Conglomerate is made from rounded, pebble sized rocks embedded in silica, calcium carbonate or iron oxide. Breccia is similar to conglomerate but the component pebbles are not rounded. Chemical sediments are composed of minerals that originally were in solution and precipitated out to form rock. They can be organic or inorganic. Organic limestone consists of seashell material that has been lithified. They are sometimes known as chalk deposits and consist primarily of calcium carbonate. Bituminous coal (soft coal) is considered an organic sedimentary rock since it consists of partly decayed plant remains. Anthracite (hard coal) is considered to be a metamorphic rock since it is formed from bituminous coal. Remember that our coal supply is limited. We will eventually use up this source of energy and will need to find other ways to satisfy our energy needs. Inorganic rock forms when water evaporates and dissolved inorganic material precipitates out to form rock. Rock salt and gypsum are examples of rock formed in this manner. Cave dripstone or stalactites and stalagmites are formed when water drips from the ceiling in a cave and evaporates. Bedding, or stratification, describes the layers that develop at the time sediment is deposited. Normally the layers are close to horizontal and concordant. Sometimes the layers are tilted with respect to each other. This is called cross-bedding and occurs most often at the mouth of a river or stream. Fossils are found in sedimentary rock. A fossil consists of the remains or traces of a prehistoric organism. It may be an imprint in the rock or lithified remains of a living organism. Metamorphic Rock Metamorphism is the process during which the structure and/or mineral content of a rock are changed while the rock remains solid. Igneous, sedimentary and metamorphic rocks can undergo metamorphism. Heat, pressure and chemically active fluids are the agents of metamorphism. Limestone to marble is an example of metamorphism that involves a structural change but no chemical change. The appearance of marble is much different from limestone, but chemically they are the same. An example of metamorphism that involves a chemical change as well as a physical change is shale to slate to schist to gneiss. There are three types of metamorphism. Contact metamorphism occurs mainly because of heat with very little pressure. This occurs in surface rock located near fissures where magma makes its way to the surface. Shear metamorphism occurs mainly because of pressure and occurs in active fault zones. When one side of the fault slides past the other, very large forces cause changes in the crystal structure of the rock in contact. Regional metamorphism occurs when pressure and heat cause changes in the nature of the rock. It seems to affect large areas and be associated with mountain building. Metamorphic rock may be foliated. When the grains that make up the rock are aligned in a direction perpendicular to the compressive forces causing the metamorphism, the rock is said to be foliated. Distinct layers are visible and may even lead to cleavage as in slate.