Effect of several salts on ice and the environment Nick Dontje & Youssef Shukur Rsg-enkhuizen, The Netherlands Summary In the winter people got problems with slippery roads. Local congregation straw NaCl(s) over the street, which lowers the freezing point of water. Is NaCl(s) the most effective salts or have other salts more result. We’ve created a proof which we look to the effects of different salts on the amount of melting ice in ml. We took eight different salts. Four different positive ions with chloride ions, and four different positive ions with nitrate ions. We notice the amount of melting ice in ml each five minutes. Would the other salts been effective to lower the freezing point and melt much ice, just like NaCl(s) in real world, and aren’t they harmful to our environment? Introduction In order to calculate the number of moles of a matter we use the following formula: quantity of gram = number of moles x molar mass Sodium chloride 22,99+35,45=58,44 (molar mass) 58.44x0.05=2.93gram Potassium chloride 39,10+35,45=74,55 (molar mass) 74.55x0.05=3.73gram Calcium chloride 40,08+2.(35,45)=110,98 (molar mass) 110.98x0.05x2/3=3.7gram Barium chloride 137,3+2.(35,45)=208,2(molar mass) 208.2x0.05x2/3=6.94gram Sodium nitrate 22,99+14.01+3.(16)=85(molar mass) 85x0.05=4.25gram Potassium nitrate 39,10+14.01+3.(16)=101,11(molar mass) 101,11x0.05=5.06gram Calcium nitrate 40,08+14.01+3.(16)=102,09 (molar mass) 102.09x0.05x2/3=3.4gram Barium nitrate 137,3+14.01+3.(16)=199,31(molar mass) number of particles to obtain the salts will have 2 + positive ions are loaded to be multiplied by a factor of 2 / 3. The calculated number of gram calciumchloride, bariumchloride, calciumnitrate and bariumnitrate multiplied by a factor of 2 / 3. These factors are derived from the dissolution of the material equations NaCl (s) → Na + (aq) + Cl-(aq) CaCl2 (s) → Ca 2 + (aq) + 2Cl-(aq) Therefore, if one mole of NaCl (s) will resolve that 2 moles arise. If a mole CaCl2 (s) will resolve it creates 3 mol. For all salts equal Natrium / potassium chloride are not harmful because they are used as salt. Calcium chloride is a dangerous substance. Barium chloride is toxic, irritating to skin and eyes. The substances with nitrate are harmful/oxidizing. Oxidizing substances which are used in combination with a flammable substance can result in combustion or detonation. Barium nitrate is an oxidizing/harmful substance. Calcium nitrate is harmful, sodium and potassium nitrate are oxidizing substances We expect that NaCl (s) will have the best results on melting the ice, because it’s being used nowadays by the government as spread salt for slippery roads. 199.31x0.05x2/3=6.65gram Experimental procedure and approach First we weigh the salts, whether the quantities of the salts are correct. Then we use a funnel at each measuring cup. 400 grams of ice will be spread over the eight funnels (50gram per funnel). On each funnel filled with 50 grams of ice, spread the corresponding quantity of any of the above salts. Data gathering and analysis After each 5minuten that have expired, the corresponding amount of melted ice will be read per ml funnel. After every 5 minutes, you have 8 different values. You repeat the reading for every 5 minutes un till you reach 30 minutes. If all goes well, you will have 48 test values at the end of the procedure of melted ice(water) volume in ml (6 samples per salt). Results The numbers in the table are the number of ml melted ice. The following data are the average of two tests. Time in minutes 5 NaCl Kcl CaCl2 BaCl2 NaNo3 KNO3 Ca(NO3)2 Ba(NO3)2 10 6,25 2,75 7 2,01 2,75 0,4 4 0,15 15 8,3 4,9 9,7 3,15 5,5 1,6 6,7 1,45 20 10,55 6,65 12,5 6 7,45 3,7 8,8 4,55 25 13,35 8,8 14,65 8,65 10,1 6,45 10,45 7,15 30 15,95 11,65 16,85 11,35 13,1 9,2 13,05 9,8 18,5 13,55 18,45 13,6 15,4 11,4 15,15 12,2 melted ice (mL) Chlorides 20 18 16 14 12 10 8 6 4 2 0 NaCl Kcl CaCl2 BaCl2 0 5 10 15 20 time (s) 25 30 35 Nitrate 18 16 melted ice (mL) 14 12 10 NaNo3 8 KNO3 6 Ca(NO3)2 4 Ba(NO3)2 2 0 0 10 20 time (s) 30 40 Conclusion and discussion If we look critically at our research, we can’t determine exactly whether we were able to hold the variables constant in our research. The ambient temperature, the exact timing for 5min and the amount of ice will not exactly have been the same. The number of grams of salt that we have about 50 grams of ice scattered in both trials have been right. From these views, we can conclude that the differences between our data are logical. We have taken the average of two tests and with this data we were able to create the tables and the graphs. Calcium chloride and sodium chloride had the highest number of melted ice in 30 minutes. Calcium chloride and sodium chloride with 18.45ml 18.5ml, followed by sodium nitrate and calcium nitrate with 15.4 to 15.15 ml. Calcium chloride and sodium chloride are the two best salts for ice to melt. The result of natriumchloride is logical,because it is used as spread salt, just like we explained in our introduction. Calcium chloride is dangerous and harmful to our environment, so calcium chloride is not a good alternative for NaCl (s). The substances with nitrate are harmful/oxidizing, so these are no good alternatives. Two salts are remaining: potassium chloride and barium chloride. Barium chloride is toxic, irritating to eyes and skin, so the only good alternative that remains is potassium chloride. Bibliography http://nl.wikipedia.org/wiki/natriumchloride http://nl.wikipedia.org/wiki/Kaliumchloride http://nl.wikipedia.org/wiki/calciumchloride http://nl.wikipedia.org/wiki/bariumchloride http://nl.wikipedia.org/wiki/natriumnitraat http://nl.wikipedia.org/wiki/kaliumnitraat http://nl.wikipedia.org/wiki/calciumnitraat http://nl.wikipedia.org/wiki/bariumnitraat