[OH - ] < 1.0 x 10

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Name ____________________________________________ Date _________________________ Period__

Sample Problems for Chapter 14: Acids and Bases

14.5 Ionization of Water

(Read pgs. 455-458 in the chemistry textbook)

1. (a) What does amphoteric mean?

(b)

TRUE / FALSE

Water is amphoteric.

(circle one)

2. (a) Write the chemical equation for the

ionization of water

as it reacts with itself to form both

an acid and a base.

(b) How is this reaction commonly "shortened"?

3. (a) In PURE WATER, the what is the concentration of hydronium ion, [H

3

O

+

]?

(b) In PURE WATER, what is the concentration of hydroxide ion, [OH

-

]?

(c) What is the meaning of the square brackets around the symbols?

1

4. (a) If

[OH ] = [H + ]

the solution is ________________________________

(b) If

[OH

-

] > [H

+

]

the solution is ________________________________

(b) If

[H

+

] > [OH

-

]

the solution is ________________________________

5. (a) If

[OH ] = 1.0 x 10 -7 M

the solution is ________________________________

(b) If

[OH ] > 1.0 x 10 -7 M

the solution is ________________________________

(b) If

[OH ] < 1.0 x 10 -7 M

the solution is ________________________________

6. (a) If

[H + ] = 1.0 x 10 -7 M

the solution is ________________________________

(b) If

[H + ] > 1.0 x 10 -7 M

the solution is ________________________________

(b) If

[H + ] < 1.0 x 10 -7 M

the solution is ________________________________

7. If [H

+

] = 1.0 x 10

-3

M, is the solution acidic, basic, or neutral? Explain.

8. If [H

+

] = 1.0 x 10

-9

M, is the solution acidic, basic, or neutral? Explain.

9. If [OH ] = 1.0 x 10 -9 M, is the solution acidic, basic, or neutral? Explain.

10. If [OH

-

] = 1.0 x 10

-3

M, is the solution acidic, basic, or neutral? Explain.

2

11. Indicate whether each of the following solutions are acidic, basic, or neutral.

(a) [H + ] = 2.0 x 10 -5 M

(b) [H

+

] = 1.4 x 10

-9

M

(c) [OH

-

] = 8.0 x 10

-3

M

(d) [OH

-

] = 3.5 x 10

-10

M

(e) [H

+

] = 6.0 x 10

-12

M

(f) [H

+

] = 1.4 x 10

-4

M

(g) [OH

-

] = 5.0 x 10

-12

M

(h) [OH

-

] = 4.5 x 10

-2

M

3

12. (a) What is the

ion product constant

of water?

(b) What is the symbol of the ion product constant for water? ________________________________

(c ) What units are used for the ion product constant of water?

________________________________

(d) Calculate the ion product constant for pure water (neutral).

13. (b) If NaOH(s) is added to pure water

[H + ] / [OH ] increases.

(circle one)

(b) If HCl (aq) is added to pure water

[H + ] / [OH

(circle one)

] increases.

14. (a) If H

2

CO

3

(aq) is added to pure water

[H + ] / [OH ] increases and the solution will

(circle one)

be

ACIDIC / BASIC.

(circle one)

(b) ) If NH

3

(aq) is added to pure water

[H + ] / [OH ] increases and the solution

(circle one)

will be

ACIDIC / BASIC.

(circle one)

15. What is the equation to be used when [H

+

] or [OH

-

] need to be calculated for ANY solution?

4

16. (a) A vinegar solution has [H

+

] = 2.0 x 10

-3

M. Calculate the [OH

-

] of the vinegar solution?

(b) Is this solution acidic, basic, or neutral? Explain.

17. (a) What is the [H

+

] of an ammonia cleaning solution with an [OH

-

] = 4.0 x 10

-4

M?

(b) Is this solution acidic, basic, or neutral? Explain.

18. Calculate the [H

+

] of each aqueous solution with the following [OH

-

].

(a) Coffee, 1.0 x 10

-9

M

5

18. Continued:

(b) Soap, 1.0 x 10 -6 M

(c) Cleanser, 2.0 x 10 -5 M

(d) Lemon juice, 4.0 x 10 -13 M

19. Calculate the [H

+

] of each aqueous solution with the following [OH

-

].

(a) NaOH, 1.0 x 10

-2

M

6

19. Continued:

(b) aspirin, 1.8 x 10

-11

M

(c) milk of magnesia, 1.0 x 10

-5

M

(d) seawater, 2.0 x 10

-6

M

20. Calculate the [OH

-

] of each aqueous solution with the following [H

+

].

(a) vinegar, 1.0 x 10 -3 M

7

20. Continued:

(b) urine, 5.0 x 10 -6 M

(c) ammonia, 1.8 x 10

-12

M

(d) NaOH, 4.0 x 10 -13 M

8

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