Unit 5: Chemical Bonds and Reactions 2015 1 Stevens Unit 5: Chemical Bonds & Reactions Notes Packet VOCABULARY: Term Chemical Bonds Valence Electron Definition Electron in the outermost shell of an atom that determines the atoms chemical properties Ionic Bond Covalent Bond Metallic Bond A bond formed by the attraction between positively charged metal ions and the electrons around them Molecule Compound Substance made up of atoms of two or more different elements joined by chemical bonds Chemical Reaction Chemical Equation Representation of a chemical reaction that uses symbols to show the relationship between reactants and products Reactant Product Coefficient Subscript Catalyst Small number in a chemical equation that comes after a certain element and tells you how many atoms of that element you have Example Unit 5: Chemical Bonds and Reactions 2015 2 Stevens Inhibitor Endothermic Rxn Exothermic Rxn Rxn in which energy is released to the surrounding environment as heat Decomposition Rxn Synthesis Rxn Combustion Rxn Oxidation rxn of an organic compound where heat is released Single Replacement Rxn Double Replacement Rxn Rxn in which a gas, solid, or compound forms from the exchange of atoms or ions between two compounds Nuclear Reaction Photosynthesis Cellular Respiration Section 1: Key Ideas: • Vocabulary: • • • • What kinds of bonds form in chemical reactions? Chemical bonds Valence electrons Ionic bonds Covalent bond - Molecule - Compound - Metallic Bond Unit 5: Chemical Bonds and Reactions 2015 3 Stevens How do atoms (like H2O) stay together? Chemical Bonds o A force of _____________ that holds two atoms together o Has a significant effect on chemical and physical properties of compounds o Involves the _______________ Valence Electrons: the electrons in the outermost energy level of an atom that ______________________________________________________________ Counting Valence Electrons (Draw and Label each picture) Determining the Number of Valence Electrons by Using the Periodic Table *Atoms of elements in Groups 1 and 2 have the same number of valence electrons as their group number (so 1 or 2) *Atoms of elements in Group 3-12 do not have a general rule relating their valence electrons to their group number. However, they typically have between 1 or 2 valence electrons. *Atoms of elements in Groups 13-18 have 10 fewer valence electrons than their group number. (Exception - helium atoms have only 2 valence electrons, even though they are in group 18) How Many Valence Electrons? How do you know? Hydrogen Lead Xenon Sulfur Rubidium The Octet Rule ___________________________________________________________________________ ___________________________________________________________ Atoms with less than 4 electrons tend to ______ electrons. Atoms with more than 4 electrons tend to _______ electrons. Atoms with exactly 4 electrons tend to ____________ electrons. There are always exceptions! • What happens with an atom like Hydrogen, who only has 1 electron, and only needs 2 to fill its outer shell? ________________________________________________________ ________________________________________________________________________ Unit 5: Chemical Bonds and Reactions 2015 4 Stevens The Octet Rule In Action – Draw and describe how Sodium and Chlorine combine. Lewis Structure - (Electron Dot Diagram) o A way of drawing the outer energy level electrons (valence) of an atom o The symbol for the element surrounded by as many dots as there are electrons in its outer energy level (valence) Examples: Draw Al, N and Mg. How many valence electrons does each have? 3 Types of Chemical Bonds What can you describe about each of these types of bonds just by looking at the name? Ionic:____________________________________________________ Covalent: _________________________________________________ Metallic: __________________________________________________ IONIC BONDS o ________________________________________________________________________ o ________________________________________________________________________ o Forms between atoms of _______________ and atoms of ___________________ o Resulting compounds have a name that usually ends in _______ o ____________ not ______________! o Example: ________________________________________________________ COVALENT BOND o ________________________________________________________________________ ________________________________________________________________________ o Each pair of shared electrons creates a bond o ________________________________________________ o Example: ________________________________________________________________________ Unit 5: Chemical Bonds and Reactions 2015 5 Stevens Types of Covalent Bonds Different covalent bond types share a different number of electrons – Draw and label the examples METALLIC BOND o A force of attraction between a positively charged metal ion and the electrons in a metal o ________________________________________________________________________ o Many properties of metals, such as conductivity and malleability, result from the freely moving electrons in the metal RESULTS OF BONDING Molecule Compound _______________________________ _______________________________ _______________________________ _______________________________ _______________________________ _______________________________ _______________________________ _______________________________ _______________________________ _______________________________ Diatomic - molecules consisting of two atoms of the same element bonded together Examples: _______________________________ Examples: H2, F2, O2, N2 • SECTION 2: Key Ideas: • When do chemical reactions take place? • What is the role of energy in chemical reactions? Unit 5: Chemical Bonds and Reactions 2015 6 Stevens • • • • • What is a chemical equation? How do I understand what a chemical equation is telling me? What is photosynthesis? What are the reactants and products? What is cellular respiration? What are the reactants and products? Vocabulary: • Chemical Reactions • Chemical Equation • Reactant • Product • Coefficient • Subscript - Endothermic Rxn - Exothermic Rxn CHEMICAL REACTIONS (RXN): • Chemical Change occurs • ________________________________________________________________________ ________________________________________________________________________ • One or more substances change to produce one or more different substances • ________________________________________________________________________ • Many forms of energy can be used: • ____________________________________ • ____________________________________ • ____________________________________ • ____________________________________ • ________________________________________________________________________ ________________________________________________________________________ Remember!!! ___________________________________________________________________________ ___________________________________________________________________________ Reminder: CHEMICAL CHANGE: • a change in which a substance becomes another substance having different properties • a change that is not reversible using ordinary physical means • Changes that usually cause, heat, sound, light, odor, fizzing/foaming, color changes CHEMICAL EQUATION: • Shorthand form for writing what compounds are used to begin the reaction and what compounds are formed after the reaction occurs • Examples: Unit 5: Chemical Bonds and Reactions 2015 7 Stevens 2H2 + O2 2H2O CH4 + 2O2 CO2 + 2H2O C6H12O6 + 6O2 6CO2 + 6H2O + energy PARTS OF A CHEMICAL EQUATION: Label them all! • ______________________ ____________________ 2H2 + O2 2H2O What does a Coefficient mean? ____________________________________________ ________________________________________________________________________ • What does a subscript mean? _____________________________________________ ________________________________________________________________________ • What does “Yield” mean? _________________________________________________ • Reactants are always on what side of the yield sign? ___________________________ • Products are always on what side of the yield sign? ____________________________ SYMBOLS OF A CHEMICAL EQUATION: Example: Unit 5: Chemical Bonds and Reactions 2015 8 Stevens PRACTICE: • In CO2 (carbon dioxide) how many Carbon atoms are there? How many Oxygen atoms? ________________________________________________________________________ • In 2NH3, (windex) how many Nitrogen atoms are there? How many Hydrogen atoms? ________________________________________________________________________ • In H2SO4 (battery acid) how many of each type of atom is there? ________________________________________________________________________ • In 3CHNaO3 (Alka Seltzer), how many of each type of atom is there? ________________________________________________________________________ • In C9H8O4 (aspirin), how many of each type of atom is there? ________________________________________________________________________ • What kind of bonds do you think these all form? Why? Compound Type of Bond CO2 2NH3 H2SO4 3CHNaO3 C9H8O4 WHAT IS PHOTOSYNTHESIS? • Photosynthesis is: basically how plants make their own food! Why? Unit 5: Chemical Bonds and Reactions 2015 9 Stevens • How does it work? Draw and label diagram. Photosynthesis formula: 1. What are the reactants in photosynthesis? _______________________________________ 2. What are the products? _______________________________________________________ 3. What is the catalyst? _________________________________________________________ WHAT IS CELLULAR RESPIRATION? • How cells in organisms use oxygen and sugar to make energy needed for us to survive • How does it work? Draw and label diagram. Unit 5: Chemical Bonds and Reactions 2015 10 Stevens Cellular Respiration formula: 1. What are the reactants in cellular respiration? _______________________________________ 2. What are the products? _______________________________________________________ HOW ARE PHOTOSYNTHESIS AND CELLULAR RESPIRATION RELATED? ______________________________________________________________________________ ______________________________________________________________________________ ______________________________________________________________________________ Unit 5: Chemical Bonds and Reactions 2015 11 Stevens ENERGY AND CHEMICAL REACTIONS: Exothermic Reaction Endothermic Reaction • A chemical reaction in which energy is released. • A chemical reaction in which energy is absorbed. • The products have greater bond energy than the reactants • The products have lower bond energies than the reactants C6H12O6 + 6O2 6CO2 + 6H2O + energy 6CO2 + 6H2O + energy C6H12O6 + 6O2 __________________________ ________________________ RATES OF CHEMICAL REACTIONS: The rates at which chemical reactions can take place are influenced by the following: • Temperature –a measure of the average kinetic energy of the particles in a sample of matter • • Ex. Increasing the temperature when cooking increases reaction rate Surface area – amount of material that comes into contact with the reactants • Ex. Cutting a potato into smaller pieces when cooking (larger surface area (smaller pieces) increases reaction rate) • Concentration – amount of substance per volume • Ex. Turning the valve on a gas stove to increase the concentration of methane molecules (this will increase the rate of rxn) • • Ex. Too much salt in a glass of water will decrease the rate of rxn Catalysts (enzymes) –___________________________________________________ _____________________________________________________________________ • Inhibitors – ___________________________________________________________ _____________________________________________________________________ SECTION 3: Key Ideas: • What are different types of chemical reactions? • How is a nuclear reaction different than a chemical reaction? Unit 5: Chemical Bonds and Reactions 2015 12 Stevens Vocabulary: • Synthesis Reaction - Nuclear Reaction • Decomposition Reaction - Fission/Fusion • Combustion • Single Replacement Rxn • Double Replacement Rxn TYPES OF CHEMICAL REACTION • 4Types • Synthesis (creating) • Decomposition (separating) • Combustion (burning) • Displacement/Replacement (switching) SYNTHESIS (CREATING) • ________________________________________________________________________ • Ex: Synthesis of Carbon Dioxide 2CO(g) + O2(g) → 2CO2(g) DECOMPOSITION (SEPARATING) • _______________________________________________________________________ • Ex: Electrolysis of water to make hydrogen and oxygen • 2 H2O ---> 2 H2 + O2 Unit 5: Chemical Bonds and Reactions 2015 13 Stevens COMBUSTION (BURNING) • ______________________________________________________________________ • Oxygen reacts with another element or compound to form water (H2O), carbon dioxide (CO2) and heat • _______________________________________________________________________ DISPLACEMENT/REPLACEMENT (SWITCHING) • Two types: Single replacement and double replacement • Single replacement (substitution): __________________________________________________________________ __________________________________________________________________ • • Ex: Zn + 2 HCl → ZnCl2 + H2 • Ex: Double Replacement: _______________________________________________ __________________________________________________________________ Unit 5: Chemical Bonds and Reactions 2015 14 Stevens • Ex: AgNO3 + HCl → AgCl + HNO3 • Ex: Fe2O3 + HCl → FeCl3 + H2O CHEMICAL VS NUCLEAR RXN: Chemical Reaction • Atoms are rearranged, and chemical bonds are broken and reformed • New substance is formed Nuclear Reaction • __________________________________ • Involves at least two nuclei, where one has to have all its electrons removed, by bringing it to very high temperatures. Why must the electrons be removed? • A neutron is then “slammed” into another nucleus, causing the nucleus to break apart (fission) or combine to create a new nucleus (fusion) C6H12O6 + 6O2 6CO2 + 6H2O + energy (respiration)