Mid-Term Review Answers: 1. a. Na2Cl b. HCl c. CCl4 d. P2O5 e. (NH4)4SO4 f. BaCl2 g. Li2S h. K3P i. CoBr2 j. Fe2O3 2. a. beryllium chloride b. sodium sulfide c. copper (I) chloride d. calcium hydroxide e. magnesium nitrate f. sodium phosphate g. iron (II) sulfide h. nickel (II) sulfate i. silver bromide j. silicon tetrachloride k. sulfur hexafluoride 3. Ca2+ O24. Chemical change – bread baking, milk souring, wood burning; Physical change – dry ice subliming, ice melting, water boiling 5. 2.36 mol SO3/1 X 80.06 g SO3/1 mol SO3 = 189 g SO3; 2.36 mol SO3/1 X 6.02 molecules SO3/1 mol SO3 = 1.42 X 1023 molecules SO3 6. 100 degrees C + 273 = 373 K; 303 K – 273 = 30 degrees C 7. 2 Fe + 2 H3PO4 2FePO4 + 3 H2 = single displacement 8. Potassium-39 has 19 protons, 20 neutrons, and 19 electrons 9. Ca, Mg, Be 10. Any 3 in the same column – e.g F, Cl, Br or O, S, Se or N, P, As or Li, Na, K 11. See p. 72-74 in textbook 12. See page 68 in textbook 13. See page 68 in textbook 14. A gain of electrons results in a negative ion (anion) and a loss of electrons results in a positive ion (cation) 15. 40 Ca – an atom of Calcium with 20 protons and 20 neutrons (mass # is 40) 20 16. Mass # = # of protons and # neutrons; protons and neutrons are in the nucleus – similar masses; electrons are outside the nucleus – extremely small 17. Isotopes differ from each other in having different numbers of neutrons. So atoms differ in their mass. Separate by centrifuging. 18. Metal elements are to the left of the stair-step line; nonmetals are to the right of the stair step line; Metalloids are located along the stair step line (e.g. Si, Ge, As, B, Sb, Te) 19. An orbital is an area described by a mathematical function that is a place where electrons of a particular energy may be found. One orbital can hold two electrons. (s – orbital spherical; p – dumbbell shape; f – cloverleaf shape. An s sublevel can hold 2 electrons; p – 3 orbitals – holds 6 electrons; and d – 5 orbitals – holds 10 electrons 20. Sulfur: 1s22s22p63s23p4; Sulfide, S2-: 1s22s22p63s23p6; Potassium: 1s22s22p63s23p64s1; K+:1s22s22p63s23p6 21. See pages 100-103 in textbook 22. H2SO4 + KOH KHSO4 + H2O – double displacement 23. One mole of H2SO4 would yield one mole of H2O 24. 3 Cl2 + 2 Al 2AlCl3 - 75.0g AlCl3/1 X 1 mol AlCl3/133.33g AlCl3 X 3 mol Cl2/2 mol AlCl3 = 0.844 mol Cl2 ; 0.844mol Cl2/1 X 22.4L Cl2/1 mol@STP = 18.9 L Cl2 @STP 25. Assume 100 g sample: 38.7 g C/12.01 g C/mol C = 3.22 mol C, 9.7gH/1.008g/molH = 9.62 mol H, 51.6g O/16.00g/mol = 3.22 mol O – divide by smallest # which is 3.22 and you get 1 C, 3 H, 1 O, The empirical formula is CH3O – the molar mass of this formula is 31 g/mol; The molar mass of the molecular formula given is 62.1 g/mol. 31 X 2 = 62 so the molecular formula = 2x empirical formula = C2H6O2