On-line Supporting Material The impact of off-site land use energy intensity (LUEI) on the overall life cycle LUEI for utility-scale solar electricity generation technologies David Murphy, Robert Horner, Corrie Clark Note: These tables provide intermediate values used in the calculation of LUEI for individual elements of the upstream and downstream material flows of a solar power plant. Numbers taken from within the tables may not represent physically existing facilities, but rather may be intermediate calculations to determine a LUEI (e.g., a product solar capacity may be very large because it comes from a very large facility that produces a very large amount of product; the ratio of the product solar capacity to the product land area is what matters for LUEI). Calculations follow Equation 1 explained in Method subsection B of the main document. Table S.I. Upstream LUEI estimates for silicon (Si) PV production stages: Solar module production. Production Stage/Facility Year Product (Unit) Product Quantity Product Solar Capacity (MW/y) Product Land Area (m2) Land Area Allocation Assumed Facility Life (Years) Land Use (m2/MW) Upstream LUEI (m2y/MWh) Upstream LUEI as a Percentage of GenerationSite LUEI Separate Facilities Silica Mine 2010 MG-Si (Metallurgical grade 2010 Poly-Si 2010 Silica (Metric Tons) MG-Si (Metric Tons) Poly-Si (Metric Tons) 1,275,000 318,750 2,977,311 1 30 0.311 0.000197 0.001% 28,500 2,053 296,597.14 1 30 4.815 0.00305 0.020% 19,667 1,601 1,078,644.56 1 30 22.459 0.0142 0.094% 27.586 0.0175 0.12% Separate Facilities Total 1 Table S.I (Cont.) Production Stage/Facility Year Product (Unit) Product Quantity Product Solar Capacity (MW/y) Product Land Area (m2) Land Area Allocation Assumed Facility Life (Years) Land Use (m2/MW) Upstream LUEI (m2y/MWh) Upstream LUEI as a Percentage of GenerationSite LUEI Vertically Integrated Facilities (Poly-Si to Module) Solar World (Oregon Facility) 2011 PV Module (MW) 500 500 2011 Si Wafer (MW) 740 740 2011 Si Cell (MW) 550 550 590 590 REC 2011 PV Module (MW) 298,801.22 385,764.18 1 30 19.920 0.0126 0.083% 0.33 30 5.734 0.00364 0.024% 0.33 30 7.715 0.00489 0.032% 0.33 30 7.192 0.00456 0.030% 20.642 0.0131 0.086% REC Total 2010 Si Powder (Tons) 2010 Solar World (German Facility) 2010 2010 Poly-Si Wafers (MW) Poly-Si Cells (MW) Mono and Poly-Si Modules (MW) 850 69 437,477.57 1 30 210.753 0.134 0.82% 1,000 1,000 128,428.66 1 30 4.281 0.00271 0.015% 300 300 128,428.66 1 30 14.270 0.00905 0.049% 600 600 128,428.66 1 30 7.135 0.00452 0.025% 236.439 0.150 0.99% SolarWorld (German Facility) Total 2 Table S.II. Upstream LUEI estimates for silicon PV production stages: BOS production. Material Year Ala 2010 Ni 2010 Cua 2010 Steela 2010 Si Carbide 2010 Polystyrene 2011 Ethyl Vinyl Acetate (EVA) 2011 Product (Unit) Al (Metric Tons) Ni (Metric Tons) Cu (Metric Tons) Steel (Metric Tons) Si Carbide (Metric Tons) Polystyrene (Metric Tons) EVA (Metric Tons) Product Quantity Product Solar Capacity (MW/y) Product Land Area (m2) Land Area Allocation Assumed Facility Life (Years) Land Use (m2/MW) Upstream LUEI (m2y/MWh) Upstream LUEI as a Percentage of Generation-Site LUEI 175,000 7,599 745,296 1 30 3.269 2.1E-03 0.014% 525 433,125 24,722 1 30 0.002 1.2E-06 0.0000079% 79,500 93,696 321,746 1 30 0.114 7.3E-05 0.0005% 2,400,000 3,128,127 2,586,577 1 30 0.028 1.7E-05 0.000115% 35,000 3,275 717,182 1 30 7.299 4.6E-03 0.030% 748,000 264,382,294 1,430,389 1 30 0.00018 1.1E-07 0.00000075% 240,000 30,462 2,997,946 0.11 30 0.350 2.2E-04 0.001% Total 11.063 7.0E-03 0.046% Land area and production quantity values for aluminum, copper, and steel represent averages of all of the facilities analyzed for each material. See Table S.XIII for individual data. a Table S.III. Downstream LUEI estimates for silicon PV disposition stages. Product Quantitya 2011 Scrap Metal (Metric Tons) 30,239 318.31 20,540 1 30 2.2 0.0014 0.01% 2011 Scrap Metal (Metric Tons) 30,239 318.31 80,490 1 30 8.4 0.0053 0.04% 2011 Scrap Metal (Metric Tons) 30,239 318.31 2,316 1 30 0.2 0.0002 0.00% Average 3.6 0.0023 Product quantity values for aluminum, copper, and steel represent the combined total annual disposition at the three Rifkin facilities divided equally among them. 0.015% Scrap Metal (Al, Ni, Cu, Steel) Scrap Metal (Al, Ni, Cu, Steel) Scrap Metal (Al, Ni, Cu, Steel) a Location Rifkin Scrap Iron and Metal Company Traverse City, MI, USA Saginaw, MI, USA West Branch, MI, USA 3 Land Area Allocation Land Use (m2/MW) Product (Unit) Facility Name Assumed Facility Life (Years) Downstream LUEI as a Percentage of GenerationSite LUEI Year Disposition Stage Product Land Area (m2) Downstream LUEI (m2y/MWh) Product Solar Capacity (MW/y) Table S.IV. Conversion ratios used in the Si-PV pathway. CONVERSION TABLEa a Quantity Unit Conversion Ratio Units Conversion Ratio Units Cells 73.4 pc 2.2 W/pc 2.2E-06 MW/pc Wafers 77.8 p 2.1 W/p 2.1E-06 MW/pc Silica 2.9 Metric Tons 250 w/kg 2.5E-01 MW/metric ton Poly-Si 2.0 kg 81.4 W/kg 0.081 MW/metric ton MG-Si 2.3 kg 72.0 W/kg 0.072 MW/metric ton Aluminum 3.8 kg 43.4 W/kg 0.043 MW/metric ton Copper 0.1 kg 1178.6 W/kg 1.179 MW/metric ton Nickel 0.0002 kg 825000.0 W/kg 825.000 MW/metric ton Steel 0.1266 kg 1303.4 W/kg 1.303 MW/metric ton Silicon Carbide 1.8 kg 93.6 W/kg 0.094 MW/metric ton Polystyrene 0.0005 kg 353452.3 W/kg 353.452 MW/metric ton Ethyl Vinyl Acetate 1.3 kg 126.9 W/kg 0.127 MW/metric ton All values are derived from LCI data reported by de Wild-Scholten et al..1 4 Table S.V. Upstream LUEI estimates for CdTe thin film production stages. Facility Name Location Year Product (Unit) Product Quantity Product Solar Capacity (MW/y) Product Land Area (m2) Land Area Allocation Assumed Facility Life (Years) Land Use (m2/MW) Upstream LUEI (m2y/MWh) Upstream LUEI as a Percentage of Generation-Site LUEI Refinery/ Smelter Teck Cominco Trail, British Columbia, Canada 2003 Cd (Metric Tons) 1,000 5.9E+05 2.6E+06 0.0027 30 0.04 2.5E-05 0.00017% Refinery/ Smelter Ronnskar Sweden 2004 13 7.0E+01 6.3E+06 1.5E-05 30 0.044 2.8E-05 0.00019% Panel Construction First Solar Perrysburg, Ohio 2010 Panels (MW) 248 248 2.9E+05 1 30 39 0.025 0.17% Panel Construction First Solar Kulim, Malaysia 2010 Panels (MW) 1,584 1,584 4.1E+05 1 30 8.7 0.0055 0.038% Panel Construction First Solar Frankfurt Oder, Germany 2010 Panels (MW) 528 528 2.5E+05 1 30 16 0.0101 0.069% 39 0.025 0.17% Production Stage Te (Metric Tons) Totala a All totals are the sum of the Teck Cominco and Ronnskar refinery/smelter data and only the Perrysburg, Ohio, First Solar facility data because all of the First Solar facilities represent the same process stage (i.e., manufacturing). 5 Table S.VI. Downstream LUEI estimates for CdTe thin film disposition stages. Disposition Stage/Facility Hazardous Waste Facilitya Hazardous Waste Facilitya Facility Name Environmental Quality Environmental Quality Year Product (Unit) 2011 Hazardous Glass Dust (Metric Tons) Belleville, MI, USA 2011 Hazardous Glass Dust (Metric Tons) 2011 Glass Attached to EVA (Metric Tons) 2011 Glass Fines (Metric Tons) Location Detroit, MI, USA Incinerator Facility Ross Incineration Service Grafton, OH, USA Landfill BFI-Vienna Junction Erie, MI, USA Product Product Assumed Product Solar Land Area Land Area Facility Life Quantity Capacity Allocation (m2) (Years) (MW/y) Land Use (m2/MW) Downstream Downstream LUEI as a LUEI Percentage of (m2y/MWh) Generation-Site LUEI 0.109 124 1.11E+05 ~0 30 0.0E+00 0.0000 0.000% 0.109 124 8.93E+05 ~0 30 0.0E+00 0.0000 0.000% 185.68 248 3.24E+05 0.096 30 4.2E+00 0.0026 0.018% 185.68 248 5.87E+05 0.00025 30 2.0E-02 0.0000 0.000% 4 0.0026 0.018% Total a Both hazardous waste facilities represent one disposition stage. Product quantity and solar capacity were divided between them so that the LUEI for each site could be added directly with the LUEIs from the other stages (instead of averaging the LUEI of the two sites and then adding the result to the LUEIs of the other stages). 6 Table S.VII. Conversion ratios used in the CdTe pathway. CdTe LCI Conversion Material Cadmium Cadmium Sulfide Cadmium Telluride Powder a -Fthenakis b Quantitya Unit Panel Rating (W/ m2)b Panel Rating (W/g) 0.7 2.6 43.2 g / m2 g / m2 g / m2 124 124 124 172.2 47.5 2.8690 et al.(2006).2 -Personal communications with P. Sinha of First Solar November 2 and 26, 2012.3,4 Table S.VIII. Upstream LUEI estimates for parabolic trough CSP production stages. Year Product (Unit) Product Quantity Product Solar Capacity (MW/y) Product Land Area (m2) Land Area Allocation Assumed Facility Life (Years) Land Use (m2/MW) Upstream LUEI (m2y/MWh) Upstream LUEI as a Percentage of Generation-Site LUEI Aluminuma 2010 Al (Metric Tons) 175,000 451,613 745,296 1 30 0.055 2.5E-05 0.00025% Coppera 2010 Cu (Metric Tons) 14,500 12,211 321,746 1 30 0.88 4.0E-04 0.0040% Steela 2010 Steel (Metric Tons) 2,400,000 12,800 2,586,577 1 30 6.7 3.1E-03 0.031% Concretea 2011 Concrete (Metric Tons) 300,000 1,333.33 95,695 1 30 2.4 1.1E-03 0.011% Glass 2011 Glass (MW) 450 450 90,102 1 30 6.7 3.8E-03 0.031% Production Stage/Material a Total 16.7 0.0076 0.077% Land area and production quantity values for aluminum, copper, steel, and concrete represent averages of all of the facilities analyzed for each material. 7 Table S.IX. Downstream LUEI estimates for parabolic trough CSP disposition stages. Product Quantitya 2011 Scrap Metal (Metric Tons) 30,239 1.65E-04 20,540 0.5 30 4.3 0.002 0.020% 2011 Scrap Metal (Metric Tons) 30,239 1.65E-04 80,490 0.5 30 16.8 0.008 0.077% 2011 Scrap Metal (Metric Tons) 30,239 1.65E-04 2,316 0.5 30 0.5 0.000 0.002% Average 7.2 0.003 Product quantity values for aluminum, copper, and steel represent the combined total annual disposition at the three Rifkin facilities divided equally among them. 0.033% Location Scrap Metal (Al, Cu, Steel) Scrap Metal (Al, Cu, Steel) Scrap Metal (Al, Cu, Steel) Rifkin Scrap Iron and Metal Company Traverse City, MI, USA Saginaw, MI, USA West Branch, MI, USA a Table S.X. Conversion ratios used in the CSP pathway. Conversion Table for Upstream CSPa,b Conversion ITEM QUANTITY UNIT Ratio (MW/ton) Concrete 18,000 Metric Ton 0.0044 Steel 15,000 Metric Ton 0.0053 Copper 95 Metric Ton 0.84 Aluminum 31 Metric Ton 2.6 a -Data in table from Martin,5 as reported in Burkhardt et al.6 b -Data based on the Luz SEGS VIII CSP facility, which is an 80-MW parabolic trough CSP plant with natural gas cofiring. 8 Assumed Facility Life (Years) Land Use (m2/MW) Product (Unit) Facility Name Land Area Allocation Downstream LUEI as a Percentage of Generation-Site LUEI Year Disposition Stage Product Land Area (m2) Downstream LUEI (m2y/MWh) Product Solar Capacity (MW/y) Table S.XI. Additional Upstream Facility Data from Sources Identifying Both Land Area and Production Capacity. Company Facility Location Products Capacity (MW/y) Land Area (m2) SolarWorld Hillsboro, Oregon Solar-Grade Si, Wafers, Cells, Modulesa 500 392,545 Trina Solar Changzhou, China Modules 1,900 5,120,000 First Solar Perrysburg, Ohio Thin Film 248 83,613 First Solar Mesa, Arizona Thin Film 248 497,763 First Solar Kulim, Malaysia Thin Film 1,584 645,109 First Solar Frankfurt Oder, Germany Thin Film 528 190,202 9 Table S.XII. Additional Upstream Facility LUEI Data for Silicon PV: Solar Module Production. Production Stage/Facility Location Company Name Land Area (m2) Product (Unit) Product Quantity Year 701 Boyce Memorial Drive, Ottawa, IL, USA U.S. Silica 5,813,000 Silica (Metric Tons) 2,200,000 2010 5263 Edmund Highway West Columbia, SC, USA U.S. Silica 141,000 Silica (Metric Tons) 350,000 2010 2401 Old Montgomery Rd., Selma, AL, USA Globe Specialty Metals, Inc. 296,000 MG-Si (Metric Tons) 27,000 2010 3807 Highland Ave. Niagara Falls, NY, USA Globe Specialty Metals, Inc. 197,000 MG-Si (Metric Tons) 30,000 2010 12334 Geddes Rd., Hemlock, MI, USA Hemlock Semiconductor Corp. 2,648,000 Poly-Si (Metric Tons) 36,000 2010 1616 S. Pioneer Way Moses Lake, WA, USA REC 8,000 Poly-Si (Metric Tons) 15,000 2010 501 Pearl Drive, St. Peters, MO, USA MEMC Electronic Materials 579,000 Poly-Si (Metric Tons) 8,000 2010 25300 NW Evergreen Rd., Hillsboro, OR, USA SolarWorld (Oregon Facility) 299,000 PV Module (MW) 500 2011 Wafers (MW) 740 2011 Si Cell (MW) 550 2011 PV Module (MW) 590 2011 437,000 Si Powder (Tons) 850 2010 128,000 Poly-Si Wafers (MW) 1,000 2010 Berthelsdorfer Str. 111 A, 09599 Freiberg/Saxony, Germany 128,000 Poly-Si Cells (MW) 300 2010 Ferdinand-Reich Str. 1, 09599 Freiberg/Saxony, Germany 128,000 Mono and Poly-Si Modules (MW) 600 2010 Silica Mine Metal-Grade (MG) Si Poly-Si 20 Tuas South Ave. 14, Singapore 637312, Tuas, Singapore Vertically Integrated Facilities (Poly-Si to Module) REC Alfred-Lange Str. 15, 09599 Freiberg/Saxony, Germany Berthelsdorfer Str. 111 A, 09599 Freiberg/Saxony, Germany SolarWorld (German Facility) 386,000 10 Table S.XIII. Additional Upstream Facility LUEI Data for Silicon PV: BOS Production. Production Stage/Material Location Company Name Land Area (m2) Product (Unit) Product Quantity Year 43840 State Route , Hannibal, OH, USA Ormet Primary Aluminum Corp. 1,850,000 Al (Metric Tons) 265,000 2010 391 St. Jude Industrial Park Hwy New Madrid, MO 63869, USA Noranda Aluminum Holding Corp. 1,050,000 Al (Metric Tons) 250,000 2010 400 East Lincoln Highway Chicago Heights, IL, 60411, USA Aleris International, Inc. 61,000 Al (Metric Tons) 130,000 2010 Birmingham, AL, USA Bermco Aluminum Co. 21,000 Al (Metric Tons) 55,000 2010 1891 E 1st Avenue South, Columbus, MT, USA Stillwater Mining Co. 25,000 Ni (Metric Tons) 525 2010 Bagdad, AZ, USA Freeport-McMoRan Copper & Gold 284,000 Cu (Metric Tons) 92,000 2010 Sierrita, AZ, USA Freeport-McMoRan Copper & Gold 359,000 Cu (Metric Tons) 67,000 2010 13th Street and Braddock Avenue, Edgar Thompson Plant, Braddock, PA, USA US Steel 1,223,000 Steel (Metric Tons) 2,800,000 2010 5700 Valley Road, Fairfield Works, Fairfield, AL, USA US Steel 3,950,000 Steel (Metric Tons) 2,000,000 2010 13230 ESK Street, Hennepin, IL, USA Washington Mills Hennepin, Inc. 717,000 Si Carbide (Metric Tons) 35,000 2010 Polystyrene Hwy 75 & River Rd. 70721 , Carville, LA, USA Carville Styrenics Complex – Polystyrene Plant, Total Petrochemicals USA 1,430,000 Polystyrene (Tons) 748,000 2011 Ethyl Vinyl Acetate Daesan Complex, Daesan, South Korea Samsung Total Petrochemicals 2,998,000 EVA (Metric Tons) Primary Aluminum Secondary Aluminum Nickel Copper Steel Silicon Carbide 11 240,000 2011 Table S.XIV. Additional Upstream Facility LUEI Data for CdTe Thin Film. Production Stage Smelter/Refinery Smelter/Refinery Panel Manufacturing Panel Manufacturing Panel Manufacturing Location Trail, British Columbia, Canada Skelleftehamn, Sweden 28101 Cedar Park Blvd., Perrysburg, OH 43551, USA Hi-Tech Park 09000, Kulim, Kedah Darul Aman, Malaysia Marie - Curie - Str. 3 15236 Frankfurt (Oder), Germany Company Name Teck Cominco, Ltd. Ronnskar Land Area (m2) 2,593,824.66 6,291,377.04 Product (Unit) Product Quantity Year Zn (Metric Tons) 283,100 2003 Pb (Metric Tons) 80,700 2003 Cd (Metric Tons) 1,000 2003 In (Metric Tons) 34 2003 Ag (Metric Tons) 569 2003 Cu (Metric Tons) 224,400 2002 Te (Metric Tons) 13 2002 Se (Metric Tons) 34 2002 Pb (Metric Tons) 17,700 2002 Au (Metric Tons) 15.6 2002 Ag (Metric Tons) 408 2002 Zn Clinker (Metric Tons) Sulfuric Acid (Metric Tons) Liquid SO2 (Metric Tons) 34,400 2002 544,000 2002 54,700 2002 First Solar 288,590.82 Panels (MW) 248 2010 First Solar 414,759.69 Panels (MW) 1,584 2010 First Solar 252,520.89 Panels (MW) 528 2010 12 Table S.XV. Additional Upstream Facility LUEI Data for Parabolic Trough CSP. Production Stage/ Material Primary Aluminum Secondary Aluminum Location Company Name 43840 State Route 7 Hannibal, OH, USA 391 St. Jude Industrial Park Hwy., New Madrid, MO, USA 400 East Lincoln Highway Chicago Heights, IL, USA Ormet Primary Aluminum Corp. Noranda Aluminum Holding Corp. Aleris International, Inc. Birmingham, AL, USA Bermco Aluminum Co. Bagdad, AZ, USA Copper Sierrita, AZ, USA Steel 13th St. and Braddock Ave. Edgar Thompson Plant Braddock, PA, USA 5700 Valley Rd., Fairfield Works Fairfield, AL, USA Freeport-McMoRan Copper & Gold Freeport-McMoRan Copper & Gold Land Area (m2) 1,849,918 1,049,642 60,923 20,699 284,175 359,318 U.S. Steel 1,222,703 U.S. Steel 3,950,450 18825 Old Lagrange Rd. Mokena, IL, USA Ozinga 83,751 12660 S. Laramie Ave. Alsip, IL, USA Ozinga 125,757 400 E. Blaine Street Gary, IN, USA Ozinga 74,258 2255 S. 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