Investigation 10: Mixing and Melting PART A - MIXING WATER SAMPLES E QUILIBRIUM Case 1: Mixing Equal amounts of hot water with cold water 1. Place 100 mL of cold water in a small foam cup. Measure its temperature (Tcold) in Celsius and record in the data table. 2. Place 100 mL of hot water in a small foam cup. Measure its temperature (Tcold) in Celsius and record in the data table. Be careful, the hot water is HOT. Glue this side down. 3. Before mixing the two samples together, check the prediction you think best describes what will happen: The final temperature of the mixture will be the temperature Tcold. The final temperature of the mixture will be closer to Tcold than to Thot. The final temperature of the mixture will be approximately halfway between Tcold and Thot. The final temperature of the mixture will be closer to Thot than to Tcold. The final temperature of the mixture will be the temperature Thot. 4. Now try to estimate the final temperature of the mixed water samples: Estimated Tfinal = _____°C 5. Mix the hot and cold samples together, pouring them both into the large foam cup. Gently stir the mixed samples with your thermometer until you are sure the mixture is all at one temperature. This is called the equilibrium temperature of the water mixture. Record this in the data table. CASE 1 DATA TABLE: Temperature of 100 mL of cold water (Tcold) °C Temperature of 100 mL of hot water (Thot) °C Equilibrium Temperature of the mixture (Tfinal) °C 6. Was your prediction correct? _________ Was your estimate close? _________ 13. Before mixing the two samples together, check the prediction you think best describes what will happen. The final temperature of the mixture will be closer to Tcold than to Thot. The final temperature of the mixture will be approximately halfway between Tcold and Thot. The final temperature of the mixture will be closer to Thot than to Tcold. 14. Try to estimate the equilibrium temperature of the mixed water samples, Tfinal =_____°C 7. Which water sample was the heat energy transferred FROM? 8. Which water sample was the heat energy transferred TO? 9. How do you know which sample the heat energy was transferred TO and which sample the heat energy was transferred FROM? 10. Why do you think the equilibrium temperature of the mixture was close to halfway between their starting temperatures? 15. Mix the hot and cool samples together, pouring them both into the large foam up. Gently stir and record the equilibrium temperature. CASE 2 DATA TABLE: Temperature of 100 mL of cold water (Tcold) Temperature of 100 mL of hot water (Thot) °C Equilibrium Temperature of the mixture (Tfinal) °C 16. Was your prediction correct? _______ Was your estimate close? ________ 17. Compare Case 2 with Case 1. Explain our results. Case 2: Mixing hot water with twice as much cool water 11. Place 200 mL of cold water in a small foam cup. Measure its temperature (Tcold) and record in the data table. 12. Place 100 mL of hot water in a small foam cup. Measure its temperature (Tcold) and record in the data table. °C Investigation 10: Mixing and Melting PART B – THE MELTING PROCESS We will be adding hot water to ice. We want to find out if the hot water has the same effect it has on the ice that it had on the cold water. In Case2 of Part A, we adding 100 g of hot water to 200 g of cold water. We will be replacing the 200 g of cold water with 200 g of ice in this experiment so that we can compare it to Case 2. 18. Place 200 g of ice in the large foam cup. Make sure you have only ice cubes, no liquid water. Find its temperature (Tice) in °C and record here: (Tice) = ______°C 19. Place 100 mL of hot water in a small foam cup. Find its temperature (Thot) and record here: (Thot) = ______°C Glue this side down. 20. Can you predict how many milliliters of hot water will be needed to completely melt the ice? (None of our experiments thus far would help you make this prediction, so this is really more of an educated guess.) Circle your best guess. Less than 100mL 100mL 200mL 300mL more than 300mL 21. Add the 100 mL of hot water to the ice. Stir gently until it comes to equilibrium. Record the equilibrium temperature when the temperature stops changing. Equilibrium after adding 100mL hot water: (Tfinal) = ______°C 22. Did all of the ice melt? _____ 23. If ice still remains in the mixture, add another 100mL of hot water. Once again, stir the mixture gently and wait until the mixture reaches thermal equilibrium. Equilibrium after adding 200mL hot water: (Tfinal) = ______°C 24. Did all of the ice melt? _____ 25. If ice still remains in the mixture, add another 100mL of hot water. Once again, stir the mixture gently and wait until the mixture reaches thermal equilibrium. Equilibrium after adding 300mL hot water: (Tfinal) = ______°C 26. The ice and the cold water start at nearly the same temperature. Did the first 100mL of hot water have the same effect when added to the ice as it had when added to the cold water? Explain your answer. SUMMARY OF RESULTS Part A, Case 2 – Adding hot water to liquid water at 0°C When 100mL of hot water at ____°C was added to 200 mL of cold (liquid) water at ____°C, the equilibrium temperature of the mixture was Tfinal = ______°C Part B – Adding hot water to solid water (ice) at 0°C After 100 mL of hot water at ______°C was added to 200 grams/mL of ice at ______°C, the equilibrium temperature of the mixture was Tfinal = ______°C After a second 100 mL of hot water at ______°C was added the ice/water mixture, the equilibrium temperature of the mixture was Tfinal = ______°C After a third 100 mL of hot water at ______°C was added the ice/water mixture, the equilibrium temperature of the mixture was Tfinal = ______°C 27. Think about what is happening to the particles of water in the ice as the ice melts. Are the particles themselves changing? Is their kinetic energy changing? Is the way they are connected to each other (bonded) changing? What would explain why it takes so much hot water to melt the ice?