Name_______________________ CHEMISTRY FINAL EXAM REVIEW GUIDE CHAPTERS 8 AND 9 TERMS AND CONCEPTS: Chemical reaction Reactants Products Synthesis reactions Decomposition reactions Single replacement reactions Double replacement reactions Combustion of a hydrocarbon catalyst mole ratio Avogadro’s number molar mass limiting reagent excess reagent actual yield theoretical yield percent yield SKILLS/PROBLEM TYPES: Balance equations Tell the type of reaction Translate word equations Stoichiometry problems from balanced equations Percent yield problems PRACTICE PROBLEMS: Translate, balance, and tell the type of reaction for each please. 1. Sodium phosphate + calcium chloride sodium chloride and calcium phosphate 2. Tricarbon hexahydride + oxygen gas carbon dioxide and water 3. Magnesium chlorate magnesium chloride + oxygen gas 4. Sodium oxide + water sodium hydroxide 5. Calcium iodide + fluorine calcium fluoride + iodine Answer the following questions based on the chemical reaction given below please. K3N + CaCO3 K2CO3 + Ca3N2 6. Balance the equation and tell its type. 7. How many grams of potassium carbonate can be formed from 250 grams of potassium nitride and excess calcium carbonate? 8. How many moles of calcium carbonate are needed to produce 155 g of calcium nitride? 9. How many formula units of calcium carbonate are needed to react with 7.5 moles of potassium nitride? 10. If calculations predict a yield of 215 grams of calcium nitride but only 211 grams are collected in the lab, what is the percent yield? Name_____________________ CHEMISTRY FINAL EXAM REVIEW GUIDE CHAPTERS 10, 11, AND 16 TERMS AND CONCEPTS: Heat Temperature Enthalpy Entropy Heat of reaction Heat of fusion Heat of vaporization Solid Liquid Gas Plasma Condensation Sublimation boiling evaporation freezing melting temperature during a phase change Kinetic molecular theory of gases (basic points) Boyle’s Law Charles’ Law Gay-Lussac’s Law Combined Gas Law STP Ideal Gas Law Standard molar volume SKILLS/PROBLEM TYPES: Specific heat capacity Enthalpy change for a chemical reaction Gas Laws Standard molar volume (at STP) Density at STP PRACTICE PROBLEMS: 1. You need 280.8 J to raise the temperature of 34.0 g of ammonia, NH3 (g), from 23.0 C to 25.0 C. Calculate the specific heat capacity of ammonia. 2. How much heat is needed to melt 5.6 kg of ice if the heat of fusion of water is 80 cal/g? 3. How many grams of water can be vaporized by 15 000 J if the heat of vaporization of water is 2340 J/g? 4. The pressure on a 240.00 mL sample of helium gas is increased from 0.428 atm to 1.55 atm. What is the new volume, assuming constant temperature? 5. A scientist warms 26 mL of gas at 0.0 C until its volume is 32 mL. What is the new temperature in degrees Celsius? 6. A tank of oxygen for welding is at 31 C and 11 atm. What is the pressure, when it is taken to the South Pole, where the temperature is -41 C? 7. How many moles of air are in 1.00 L at -23 C and 101 kPa? 8. A 4.44L container holds 15.4 g of oxygen at 22.55 C. What is the pressure? 9. What is the density of chlorine gas at STP? 10. How many grams are present in a 55.5 L sample of carbon dioxide at STP? Enthalpy change for a reaction: Let’s do #27-29 on pp. 371. You may need to use the chart of heats of formation found within Chapter 10. Name___________________________ CHEMISTRY FINAL EXAM REVIEW GUIDE CHAPTERS 12, 14, and 15 TERMS AND CONCEPTS: Mixture Solution Colloid Suspension Alloy Molarity Molality Parts per million Electrolytes Miscible “like dissolves like” Arrhenius acid/base Bronsted-Lowry acid/base pH pH scale properties of acids properties of bases strong acids strong bases self-ionization of water Kw titration equivalence point buret purpose of a titration indicator SKILLS/PROBLEM TYPES: Molarity Molality Parts per million Naming acids pH/pOH problems PRACTICE PROBLEMS: 1. What is the molarity of a 750 mL solution that contains 59.9 grams of NaCl? 2. How many grams of KNO3 should be added to water to make 650 mL of a 1.5 M KNO3 solution? 3. How many moles of KOH must be added to 500 grams of water to make a 2.5 molal solution? 4. A 500 gram sample of pond water contains 75 mg of lead. What is the concentration of lead in ppm? 5. A 350 gram sample of dirt contains 25 mg of radon. What is the concentration of radon in ppm? 6. Name each acid please: a. HNO4 ________________ b. HI____________________ c. H2SO2_________________ d. H3PO4_________________ e. HBr____________________ 7. Give the formula for each acid please: a. Hypochlorous acid_________________ b. Hydrofluoric acid___________________ c. Persulfuric acid_____________________ d. Carbonous acid_______________________ e. nitric acid___________________________ 8. Give the pH, pOH, hydronium concentration , and hydroxide concentration for each of the following please: a. 0.25 M HNO3 b. 2.3 x 10 -3 M Ca(OH)2 c. 1.5 M H2SO4 d. 2.5 x 10 -5 M KOH Name_______________________ CHEMISTRY FINAL EXAM REVIEW GUIDE CHAPTERS 21 and 22 TERMS AND CONCEPTS: Isotopes Two ways to write isotopes Mass defect Fission Fusion Half-life Beta decay Alpha decay Electron capture Nuclide Nucleons Radioactivity organic compound alkanes alkenes alkynes cyclic hydrocarbons aromatic hydrocarbons functional group isomers prefixes for organic compounds 4 types of organic reactions polymers SKILLS/PROBLEM TYPES: Write and balance nuclear equations --alpha decay, beta decay, and electron capture Half-life problems Name unsubstituted alkanes, alkenes, alkynes, and cyclic hydrocarbons Name substituted alkanes, alkenes, and alkynes Classify compounds by their functional group (alcohols, aldehydes, ketones, and carboxylic acids) PRACTICE PROBLEMS: 1. Write the nuclear reaction for each please: a. Beta decay of hydrogen-3 b. Electron capture by sodium-22 c. Alpha decay of polonium-210 d. Beta decay of sulfur-35 2. The half-life of an isotope is 2.0 years. How many years would it take for a 4.0 mg sample to decay and have only 0.50 mg remain? 3. Selenium—83 has a half life of 25.0 minutes. How many minutes would it take for a 10.0 mg sample to decay and have only 1.25 mg of it remain? 4. Actinium—226 has a half-life of 29 hours. IF 100 mg of actinium—226 disintegrates over a period of 58 hours, how many mg of actinium—226 will remain? 5. Give the missing name or formula for each hydrocarbon please: a. Butane________________ b. Ethyne________________ c. Cyclohexene________________ d. Nonane____________________ e. C3H8 ______________________ f. C5H10_______________________ g. C10H18______________________ 6. Name each hydrocarbon please: We will practice some of these on the board. 7. Draw each hydrocarbon please: a. Cyclopropene b. 3-pentyne c. 3-ethyl-2-hexene d. 2,2-dimethyl propane e. 4-ethyl-2,5-dimethyl heptanes f. 2-methyl-2-butene