06.Stoich and Percent Rev Ans

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Stoich and % Yield Problems

1.

How many grams of chlorine gas are needed in the production of 200.0 grams of bromine gas from sodium bromide?

Cl

2

+

2 NaBr

®

2 NaCl

+

Br

2

200.0

= 1.2515 mol Br

2

= 1.2515 mol Cl

2

159.808

1.2515 (70.906) = 88.74 g Cl

2

2.

Calculate the percent yield of a reaction that consumes 900.0 grams of potassium chlorate in the preparation of 90.0 grams of oxygen?

2 KClO

3

®

2 KClO

2

+

O

2

900.0

122.548

= 7.344 mol KClO

3

1 O

2

= 3.672 mol O

2

2 KClO

3

3.672 (31.998) = 117.49 g of O

2

(TY)

90.0

(100)

= 76.6% yield

117.49

3.

In the reaction of 84.0 g of copper (II) oxide with hydrogen gas in a reaction with a 92.4% yield, Determine the mass of copper produced?

CuO

+

H

2

®

Cu

+

H

2

O

84.0

= 1.056 mol CuO = 1.056 mol Cu (TY)

79.545

1.056 (63.546) = 67.1 g Cu (TY)

AY

(100) = 92.4 %

67.4

4.

How many grams of sodium hydroxide will react with 1.50 x 10 -3 g of phosphoric acid?

3 NaOH

+

H

3

PO

4

®

3 H

2

AY = 62.0 g of Cu

O

+

Na

3

PO

4

0.00150

97.9937

= 1.53 x 10 -5 mol H

3

PO

4

3 NaOH

PO

4

= 4.59 x 10 -5 mol NaOH

1 H

3

4.59 x 10 -5 (39.9969) = 1.84 x 10 -3 g of NaOH

5.

If 320.0 grams of sodium carbonate react with calcium hydroxide in a 74.67% efficient reaction, how many grams of sodium hydroxide are formed?

Na

2

CO

3

+

Ca ( OH )

2

®

2 NaOH

+

CaCO

3

320.0

105.988

= 3.019 mol Na

2

CO

3

2 NaOH

CO

3

= 6.038 mol NaOH

1 Na

2

6.038 (39.9969) = 241.5 g NaOH (TY)

AY

241.5

(100)

= 74.67% AY = 180.3 g of NaOH

6.

How many grams of sodium iodide are produced by the decomposition of 60.0 g of sodium iodate if the reaction is 89.4% effective?

_ 2 _ NaIO

3

®

_ 2 _ NaI

+

_ 3_ O

2

60.0

= 0.3032 mol NaIO

3

= 0.3032 mol NaI

197.887

0.3032 (149.89) = 45.4466 g NaI (TY)

AY

(100)

=

89.4%

AY = 40.6 g NaI

45.4466

7.

If 10.0 g of aluminum sulfide are produced by the 94.2% effective reaction of aluminum and sulfur, how many grams of sulfur were needed?

_ 2 _ Al

+

_ 3_ S

®

___ Al

2

S

3

Don’t worry about this guy if you can’t figure it out

10.0

(100)

=

94.2%

TY

10.6

TY = 10.6 g Al

= 0.07059 mol Al

2

S

3

2

S

3

150.159

0.07059

3 S

S

3

0.211775 mol S

Al

2

0.211775 (32.065) = 6.79 g of S

8.

If 2.50 g of cupric sulfide is produced by decomposing cupric sulfate upon heating, how many grams of cupric sulfate was necessary if the reaction is

90.00% efficient?

___ CuSO

4

®

___ CuS

+

_ 2 _ O

Don’t worry about this guy if you can’t figure it out

2

2.50

(100)

=

90.00%

TY

TY = 2.7777 g of CuS

2.7777

= 0.0290529 mol CuS = 0.0290529 mol CuSO

4

95.611

0.0290529 (159.607) = 4.64 g of CuSO

4

9.

125.0 g of FeS react to form 167.3 g of FeCl

2

: a.

Determine the % yield of the reaction. b.

Calculate, based on that percent yield, the moles of H

2

S that will be produced.

FeS

(s)

+ 2HCl

(aq)

®

FeCl

2(aq)

+ H

2

S

(g)

125.0

= 1.4219 mol FeS = 1.4219 mol FeCl

2

87.910

1.4219 (126.751) = 180.227 g FeCl

2

(TY)

167.3

180.227

(100) = 92.83% yield

10.

If 1.487 moles of lithium oxide react with water through a 79.4% effective reaction, determine the mass of lithium hydroxide produced.

Li

2

O

(s)

+ H

2

O

(l)

®

2LiOH

(aq)

1.487

2 LiOH

1 Li

2

O

= 2.974 mol LiOH

2.974 (23.9479) = 71.22 g LiOH (TY)

AY

71.22

(100)

= 79.4 % AY = 56.5 g LiOH

11.

In order to produce 100.0 g of NaCl based on the following 84.3 % efficient reaction, determine the moles of each reactant required.

Na

2

SO

4(aq)

+ CaCl

2(aq)

®

CaSO

4(s)

+ 2NaCl

(aq)

100.0

58.443

= 1.711 mol NaCl (AY)

1.711

(100)

= 84.3%

TY

TY = 2.0297 mol NaCl

2.0297

1 CaCl

2

2 NaCl

= 1.01 mol CaCl

2

2.0297

1 Na

2

SO

4

2 NaCl

= 1.01 mol Na

2

SO

4

12.

0.941 moles of calcium hydroxide react to form 30.55 g of water. Determine the percent yield of the reaction.

Ca(OH)

2(aq)

+ 2HCl

(aq)

®

CaCl

2(aq)

+ 2H

2

O

(l)

0.941

2 H

2

O

1 Ca ( OH )

2

= 1.882 mol H

2

O

1.882 (18.0148) = 33.9038 g H

2

O (TY)

30.55

33.9038

(100) = 90.11 % yield

13.

What mass of ethane must react in order to produce 4.73 moles of carbon dioxide if the following reaction has a 91.8 % yield?

2C

2

H

6

+ 7O

2

®

4CO

2

+ 6H

2

O

4.73

(100) = 91.8 %

TY

5.1525

2 C

2

H

6

4 CO

2

TY = 5.1525 mol CO

2

= 2.57625 mol C

2

H

6

2.57625 (30.0694) = 77.5 g of C

2

H

6

14.

4.84 moles of oxygen react in the following 87.9 % yield reaction. Calculate the mass of each product produced.

2Cu

2

S + 3O

2

®

2Cu

2

O + 2SO

2

4.84

2( Either )

= 3.22666 mol Cu

2

O and SO

2

(TY)

3 O

2

AY

3.22666

(100) = 87.9 % AY = 2.83624 mol of Cu

2

O and SO

2

2.83624 (143.091) = 406 g of Cu

2

O

2.83624 (64.063) = 182 g of SO

2

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